ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. (Pyridylamino)dialkylboranesadd to the carbonyl group of aldehydes or ketones to form boron chelates, dialkylboryl-[2-(α-hydroxyalkyl) aminopyridinates]. 2. Reaction of 2-aminopyridine, aldehydes (ketones), and diphenylborinic esters gives diphenylboryl-[2-(α-hydroxyalkyl) aminopyridinates]. 3. We have synthesized a coordination compound of boron, dibutylboryl-[2-(carboxyamino)pyridinate], by reaction of (2-pyridylamino)dibutylborane with CO2. 4. The primary step in the electron-impact fragmentation of the synthetic chelates is loss from the molecular ion of the alkyl (aryl) group attached to boron.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00928528
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