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  • LUNAR AND PLANETARY EXPLORATION  (191)
  • Physics  (70)
  • SOLAR PHYSICS  (55)
  • Humans
  • 1980-1984
  • 1975-1979  (316)
  • 1965-1969
  • 1977  (316)
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Schlagwörter
Verlag/Herausgeber
Erscheinungszeitraum
  • 1980-1984
  • 1975-1979  (316)
  • 1965-1969
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    D2-m-carborane-siloxanes. III. Preparation and properties of trifluoropropyl-modified polymers (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 973-981 
    Details
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Linear D2-m-carborane-siloxanes with one, two, and three trifluoropropyl moieties per repeat unit were prepared by the condensation reaction between bisureidosilanes and carborane disilanol. Molecular weights between 100,000 and 220,000 were obtained. Compared to fluorosilicones, the trifluoropropyl-modified carborane-siloxanes exhibited greater thermal and oxidative stability and in certain cases comparable solvent resistance. The swelling index for carborane-siloxane elastomers decreased with increasing trifluoropropyl content, although this fluorocarbon moiety did compromise the thermal stability of the carborane system.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1977.170150418
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  • 2
    Digitale Medien
    Digitale Medien
    Photoinitiation and electroinitiation in the polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 2673-2684 
    Details
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The zinc chloride-catalyzed polymerization of 2-vinylnaphthalene (VN) with both photoinitiation and electronitiation methods was examined. Good yields were obtained with both methods, the electroinitiated process being somewhat faster. The mechanism for polymerization initiation was investigated through a detailed comparison of the kinetics. Both initiation methods show a similar response to increasing input energy and to change in salt to monomer mole ratio. Both methods indicate formation of a ZnCl2-(2-VN)2 complex as intermediate with the formation of the species being rate-determining. These results, together with other similar investigations, are then used to deduce a mechanism that involves the formation of an electronically excited donor-acceptor complex. It is argued that in certain salt-stabilized, electron-delocalized, aromatic systems, such excitation is possible in electroinitiation.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1977.170151112
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  • 3
    Digitale Medien
    Digitale Medien
    Electroinitiated polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1563-1571 
    Details
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: As part of a program to extend the range of donor-acceptor-initiated polymerization processes, the electroinitiation of 2-vinylnaphthalene in a zinc chloride-sulfolane solution has been studied. Good conversion yields of well-characterized (NMR, IR, GPC, elemental analysis) poly(vinylnaphthalene) were obtained with the process showing several mechanistic similarities to other donor-acceptor salt electropolymerization systems.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1977.170150704
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  • 4
    Digitale Medien
    Digitale Medien
    Electrochemically initiated polymerization of styrene with tetraalkyl and -aryl group VA halide support electrolytes (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1555-1562 
    Details
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The electrochemically initiated polymerization of styrene in methylene chloride solvent with the use of platinum electrodes and tetraalkyl and -aryl group VA halides (i.e., quaternary ammonium, phosphonium, and arsonium compounds) as electrolyte has been investigated. The order of reactivity of the electrolytes with respect to polymerization rate and initiation efficiency was found to be: arsonium 〉 phosphonium 〉 ammonium. Mechanisms involving the electroreduction of the group VA quaternary halides to species capable of electroinitiating polymerization are postulated. The observed losses in solution conductivities during polymerization with the quaternary phosphonium and arsonium electrolytes indicate possible interaction between the initiating radical-ionic species and the supporting electrolyte. In an attempt to further elucidate the mechanism of initiation in these systems, a separate series of experiments, employing the nonpolymerizing monomer, 1,1-diphenylethylene, has been carried out.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pol.1977.170150703
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  • 5
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    Spectrophotometric and color estimates of the Viking lander sites (1977)
    In:  Other Sources
    Details
    Publikationsdatum: 2011-08-17
    Beschreibung: The spectral radiance and color of the Martian sky and soil and the spectral reflectance of soil features are estimated from six-channel (0.4-1.0 micron) spectral data obtained with the Viking lander cameras. Images taken near local noon from the two landers reveal a sky that is brighter near the horizon than the soil but with a similar spectral radiance shape and color. The scenes are predominantly moderate yellowish brown in color with only subtle variations except for some dark grey rocks. Most spectral reflectance estimates are similar: they rise rapidly with increasing wavelength between 0.4 and 0.8 micron and with only a few exceptions exhibit a pronounced minimum centered about 0.93 micron. These characteristics are consistent with an abundance of Fe(3+)-rich weathering products, notably nontronite. However, the delineation of the number and abundances of total mineral phases requires further analyses and laboratory comparisons. Reflectance estimates for rocks have not been repeatable, probably because most rocks have irregular pitted surfaces that introduce significant shadowing components.
    Schlagwort(e): LUNAR AND PLANETARY EXPLORATION
    Materialart: Journal of Geophysical Research; 82; Sept. 30
    Format: text
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    NASA TECHNICAL REPORTS
  • 6
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    The search for organic substances and inorganic volatile compounds in the surface of Mars (1977)
    In:  Other Sources
    Details
    Publikationsdatum: 2019-06-27
    Beschreibung: A total of four Martian samples, one surface and one subsurface sample at each of the two Viking landing sites, Chryse Planitia and Utopia Planitia, have been analyzed for organic compounds by a gas chromatograph-mass spectrometer. In none of these experiments could organic material of Martian origin be detected at detection limits generally of the order of parts per billion and for a few substances closer to parts per million. The evolution of water and carbon dioxide, but not of other inorganic gases, was observed upon heating the sample to temperatures of up to 500 C. The absence of organic compounds seems to preclude their production on the planet at rates that exceed the rate of their destruction. It also makes it unlikely that living systems that behave in a manner similar to terrestrial biota exist, at least at the two Viking landing sites.
    Schlagwort(e): LUNAR AND PLANETARY EXPLORATION
    Materialart: Journal of Geophysical Research; 82; Sept. 30
    Format: text
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    NASA TECHNICAL REPORTS
  • 7
    facet.materialart.
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    Mars: Water Vapor Observations from the Viking Orbiters (1977)
    In:  Other Sources
    Details
    Publikationsdatum: 2019-06-28
    Beschreibung: The global distribution of the water vapor has been mapped at low resolution throughout the period from the northern summer solstice to the following equinox. During this seasonal period the water vapor underwent a gradual redistribution, the latitude of maximum column abundance moving from the northern polar area to the equatorial latitudes. The total global vapor content remained approximately constant at the equivalent of about 1.3 cu km of ice. The various data obtained indicate that the residual polar caps are composed of water ice.
    Schlagwort(e): LUNAR AND PLANETARY EXPLORATION
    Materialart: Journal of Geophysical Research; 82; 28; 4225-4248
    Format: text
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    NASA TECHNICAL REPORTS
  • 8
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    Behavior of volatiles in Mars' polar areas - A model incorporating new experimental data (1977)
    In:  Other Sources
    Details
    Publikationsdatum: 2019-06-27
    Beschreibung: A model has been developed to explain the north polar water vapor results obtained by the Viking orbiter Mars atmospheric water detector; it has also been used to compute the thickness of seasonally deposited CO2 frost, the variation of the total atmospheric pressure, and wind velocities due to mass motions associated with CO2 condensation. A north polar water ice thickness in excess of 1 m and an ice albedo a of 0.34(+0.06,-0.03) are inferred from a comparison of the model and experimental data. The model results confirm an earlier conclusion that the atmosphere over the ice is saturated. It is suggested that concentration of the atmospheric inert gases in the polar region, combined with local topography and arctic circulation patterns, could be responsible for the south remnant cap not being at the south pole
    Schlagwort(e): LUNAR AND PLANETARY EXPLORATION
    Materialart: Journal of Geophysical Research; 82; Sept. 10
    Format: text
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    NASA TECHNICAL REPORTS
  • 9
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    Applications of a new logical search on the lunar data base for use in pattern recognition classification of Apollo 15 mare basalts (1977)
    In:  Other Sources
    Details
    Publikationsdatum: 2019-07-13
    Schlagwort(e): LUNAR AND PLANETARY EXPLORATION
    Materialart: Lunar Science Conference; Mar 14, 1977 - Mar 18, 1977; Houston, TX
    Format: text
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    NASA TECHNICAL REPORTS
  • 10
    facet.materialart.
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    Geology orbiter comparison study (1977)
    In:  CASI
    Details
    Publikationsdatum: 2019-06-27
    Beschreibung: Instrument requirements of planetary geology orbiters were examined with the objective of determining the feasibility of applying standard instrument designs to a host of terrestrial targets. Within the basic discipline area of geochemistry, gamma-ray, X-ray fluorescence, and atomic spectroscopy remote sensing techniques were considered. Within the discipline area of geophysics, the complementary techniques of gravimetry and radar were studied. Experiments using these techniques were analyzed for comparison at the Moon, Mercury, Mars and the Galilean satellites. On the basis of these comparative assessments, the adaptability of each sensing technique was judged as a basic technique for many targets, as a single instrument applied to many targets, as a single instrument used in different mission modes, and as an instrument capability for nongeoscience objectives.
    Schlagwort(e): LUNAR AND PLANETARY EXPLORATION
    Materialart: NASA-CR-155056 , SAI-1-120-399-S1
    Format: application/pdf
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