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  • GEOPHYSICS  (121)
  • ASTROPHYSICS  (97)
  • Physics  (70)
  • ENERGY PRODUCTION AND CONVERSION  (67)
  • Biochemistry and Biotechnology
  • 1995-1999
  • 1980-1984
  • 1975-1979  (377)
  • 1977  (377)
Collection
Keywords
Publisher
Years
  • 1995-1999
  • 1980-1984
  • 1975-1979  (377)
Year
  • 1
    Electronic Resource
    Electronic Resource
    D2-m-carborane-siloxanes. III. Preparation and properties of trifluoropropyl-modified polymers (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 973-981 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Linear D2-m-carborane-siloxanes with one, two, and three trifluoropropyl moieties per repeat unit were prepared by the condensation reaction between bisureidosilanes and carborane disilanol. Molecular weights between 100,000 and 220,000 were obtained. Compared to fluorosilicones, the trifluoropropyl-modified carborane-siloxanes exhibited greater thermal and oxidative stability and in certain cases comparable solvent resistance. The swelling index for carborane-siloxane elastomers decreased with increasing trifluoropropyl content, although this fluorocarbon moiety did compromise the thermal stability of the carborane system.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150418
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    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Photoinitiation and electroinitiation in the polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 2673-2684 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The zinc chloride-catalyzed polymerization of 2-vinylnaphthalene (VN) with both photoinitiation and electronitiation methods was examined. Good yields were obtained with both methods, the electroinitiated process being somewhat faster. The mechanism for polymerization initiation was investigated through a detailed comparison of the kinetics. Both initiation methods show a similar response to increasing input energy and to change in salt to monomer mole ratio. Both methods indicate formation of a ZnCl2-(2-VN)2 complex as intermediate with the formation of the species being rate-determining. These results, together with other similar investigations, are then used to deduce a mechanism that involves the formation of an electronically excited donor-acceptor complex. It is argued that in certain salt-stabilized, electron-delocalized, aromatic systems, such excitation is possible in electroinitiation.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170151112
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Electroinitiated polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1563-1571 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As part of a program to extend the range of donor-acceptor-initiated polymerization processes, the electroinitiation of 2-vinylnaphthalene in a zinc chloride-sulfolane solution has been studied. Good conversion yields of well-characterized (NMR, IR, GPC, elemental analysis) poly(vinylnaphthalene) were obtained with the process showing several mechanistic similarities to other donor-acceptor salt electropolymerization systems.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150704
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Electrochemically initiated polymerization of styrene with tetraalkyl and -aryl group VA halide support electrolytes (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1555-1562 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electrochemically initiated polymerization of styrene in methylene chloride solvent with the use of platinum electrodes and tetraalkyl and -aryl group VA halides (i.e., quaternary ammonium, phosphonium, and arsonium compounds) as electrolyte has been investigated. The order of reactivity of the electrolytes with respect to polymerization rate and initiation efficiency was found to be: arsonium 〉 phosphonium 〉 ammonium. Mechanisms involving the electroreduction of the group VA quaternary halides to species capable of electroinitiating polymerization are postulated. The observed losses in solution conductivities during polymerization with the quaternary phosphonium and arsonium electrolytes indicate possible interaction between the initiating radical-ionic species and the supporting electrolyte. In an attempt to further elucidate the mechanism of initiation in these systems, a separate series of experiments, employing the nonpolymerizing monomer, 1,1-diphenylethylene, has been carried out.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150703
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    Paper (German National Licenses)
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  • 5
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    National geodetic satellite program, part 1 (1977)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: Equipment and techniques were evaluated operationally, by the Department of Defense, during the National Geodetic Satellite Program (NGSP). The theory, instrumentation, and data reduction methods used are described. Results obtained during the NGSP are given.
    Keywords: GEOPHYSICS
    Type: NASA, Washington Natl. Geodetic Satellite Program, Pt. 1; p 139-245
    Format: text
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    NASA TECHNICAL REPORTS
  • 6
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    Spectrum of the Kleinmann-Low nebula from 29 to 125 micrometers (1977)
    In:  Other Sources
    Details
    Publication Date: 2011-08-17
    Description: The infrared spectrum of the Kleinmann-Low nebula in M42 has been measured from 80 to 350 kaysers (approximately 29 to 125 microns) with a Michelson interferometer aboard the NASA Kuiper Airborne Observatory. The frequency spectrum peaks at about 185 kaysers. A simple model of the emission implies that the temperature is in the range 70-95 K and that the optical depth is at least 0.2 at the peak frequency. A possible absorption is seen at about 176 kaysers. Thermal emission by dust at a temperature of 71 K, with the absorption cross section proportional to frequency, provides a good fit to the data. Other thermal-emission models can also fit the spectrum. The data are compared with previous broad-band measurements. Upper limits are placed on expected line emission from the surrounding H II region at the position of the nebula.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal; vol. 212
    Format: text
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  • 7
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    The micrometeoroid complex and evolution of the lunar regolith (1977)
    In:  CASI
    Details
    Publication Date: 2016-06-07
    Description: Monte Carlo-based computer calculations, as well as analytical approaches utilizing probabilistic arguments, were applied to gain insight into the principal regolith impact processes and their resulting kinetics. Craters 10 to 1500 m in diameter are largely responsible for the overall growth of the regolith. As a consequence the regolith has to be envisioned as a complex sequence of discrete ejecta blankets. Such blankets constitute first-order discontinuities in the evolving debris layer. The micrometeoroid complex then operates intensely on these fresh ejecta blankets and accomplishes only in an uppermost layer of approximately 1-mm thickness. The absolute flux of micrometeoroids based on lunar rock analyses averaged over the past few 10 to the 6th power years is approximately an order of magnitude lower than presentday satellite fluxes; however, there is indication that the flux increased in the past 10 to the 4th power years to become compatible with the satellite data. Furthermore, there is detailed evidence that the micrometeoroid complex existed throughout geologic time.
    Keywords: ASTROPHYSICS
    Type: The Soviet-Am. Conf. on Cosmochem. of the Moon and Planets, Pt. 2; p 605-635
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 8
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    Description and review of global measurements of atmospheric species from GASP (1977)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: A large volume of atmospheric constituent data is being collected in the global airlanes by specially equipped B-747 aircraft. This NASA program also obtains data from the similarly equipped NASA CV-990 aircraft during dedicated flights such as a recent near pole-to-pole latitude survey mission. Aerosol composition data are also collected with a NASA F-106 aircraft. Present measurements include ozone, carbon monoxide, water vapor, aerosol and condensation nuclei number densities, sulphates, nitrates, and the chlorofluoromethanes. Meteorological and flight parameters are also recorded for use in data analysis. The present aircraft operations obtain data between 6 and 13.5 km from 65 deg N between Europe and the North Pacific, and from 23 deg S over South America and 42 deg S over New Zealand. Typical constituent data from the aircraft operations during the first one and a half years are presented. Instrumentation is discussed.
    Keywords: GEOPHYSICS
    Type: Conference on Air Quality Meteorology and Atmospheric Ozone; Jul 31, 1977 - Aug 06, 1977; Boulder, CO; US
    Format: text
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    NASA TECHNICAL REPORTS
  • 9
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    Dip-coating process: Silicon sheet growth development for the large-area silicon sheet task of the low-cost silicon solar array project (1977)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: The objective of this research program is to investigate the technical and economic feasibility of producing solar-cell-quality sheet silicon by coating one surface of carbonized ceramic substrates with a thin layer of large-grain polycrystalline silicon from the melt. The past quarter demonstrated significant progress in several areas. Seeded growth of silicon-on-ceramic (SOC) with an EFG ribbon seed was demonstrated. Different types of mullite were successfully coated with silicon. A new method of deriving minority carrier diffusion length, L sub n from spectral response measurements was evaluated. ECOMOD cost projections were found to be in good agreement with the interim SAMIS method proposed by JPL. On the less positive side, there was a decrease in cell performance which we believe to be due to an unidentified source of impurities.
    Keywords: ENERGY PRODUCTION AND CONVERSION
    Type: NASA-CR-157072 , ERDA/JPL-954356-77/4 , HONEYWELL-QR-7
    Format: application/pdf
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  • 10
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    Silicon on ceramic process. Silicon sheet growth development for the large-area silicon sheet task of the low-cost silicon solar array project (1977)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: The technical and economic feasibility of producing solar-cell-quality sheet silicon was investigated. The sheets were made by coating one surface of carbonized ceramic substrates with a thin layer of large-grain polycrystalline silicon from the melt. Significant progress was made in all areas of the program.
    Keywords: ENERGY PRODUCTION AND CONVERSION
    Type: NASA-CR-155613 , ERDA/JPL-954356-77/3 , AR-2
    Format: application/pdf
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