ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Aquation rates forcis-CoCl(en)2(A)2+ (A = 3,5-lutidine, imidazole, N-methylimidazole, benzimidazole) have been determined by halide release titration in 1.0 M HNO3 at 50-80°C. Kinetic parameters are (in the above order of A) 107k298 (sec-1), 7.4, 5.7, 1.3, 9.7; Ea (kJ/mole), 103, 101, 130, 112; log PZ (sec-1), 11.89, 11.53, 16.04, 13.58; ΔS298
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550080411
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