ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The product of the reaction of (π-C5 H5)Ru(PPh3)2 Cl and CuC2Ph has been characterized by single-crystal x-ray diffraction techniques and shown to have stoichiometry (π-C5 H5)Ru(PPh3)2Cu(C2Ph)Cl-(CH3)2CO(I). The compound contains a phenylethynyl group σ-bonded to the ruthenium atom and simultaneously π-bonded to a terminal Cu-Cl bond. Crystals of this compound from acetone are monoclinic,P21/c, witha = 12.914, = 22.111,c = 16.534 Å, β = 110.77 °, andZ — 4. Full-matrix least-squares refinement constraining the phenyl rings of the triphenylphosphines, the cyclopentadienyl ring, and the solvent of crystallization (acetone) as rigid groups yieldedR and weightedR values of 0.084 and 0.075, respectively.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01275645
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