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  • 1
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Das Spiroorthocarbonat, 8,10,19,20-Tetraoxatrispiro[5.2.2.5.2.2]heneicosan (1), welches zwei Cyclohexylgruppen enthält, wurde dargestellt. Das Monomere wurde mittels eines kationischen Katalysators wie Bortrifluoridätherat oder Zinn(IV)-chlorid polymerisiert. Die Struktur des Polymeren wurde mit Hilfe der IR und NMR Spektren bestimmt; es sind Copolymere mit alternierenden Äther- und Carbonatverknüpfungen. Das Monomere 1 expandiert bei der Polymerisation.
    Notes: A spiro orthocarbonate containing two cyclohexyl groups, 8,10,19,20-tetraoxatrispiro[5.2.2.5.2.2]heneicosane (1), was prepared. The monomer was polymerized with Lewis acids such as boron trifluoride etherate or stannic chloride as catalysts. The IR and NMR spectra indicated that the polymer was an alternating copolymer with ether and carbonate linkages. This monomer underwent expansion on polymerization.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 20 (1978), S. 1249-1265 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model has been employed to examine the interplay of reaction and mass transfer in immobilized enzyme systems involving reaction-generated enzyme poisons. Deactivation rates can be significantly reduced in some cases by catalyzing a purification reaction in which the poison is transformed into an innocuous substance. This conclusion is illustrated experimentally for reaction-generated H2O2 in a continuous-flow stirred slurry reactor containing glucose oxidase immobilized on activated carbon.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 20 (1978), S. 1817-1831 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Immobilization of an enzyme within an insoluble material permeable to substrate can change the apparent behavior of the enzyme. In particular, external mass transfer and intraparticle diffusion effects can significantly influence the dependence of observed reaction rate on operating parameters such as temperature and pH. This analysis shows that, under very general conditions, the influence of diffusion alone is to diminish the sensitivity of the observed rate to any parameter that is uniform throughout the catalyst particle. However, the optimal value of the parameter is not changed because of intrapellet diffusional effects.
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 20 (1978), S. 1651-1665 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Apparent kinetics and pH-activity relationships have been determined for glucoamylase and glucose oxidase immobilized on activated carbon using a diimide method. Reaction rate expressions of Michaelis-Menten form adequately approximate the observed kinetics for both enzyme preparations over the ranges of substrate concentrations considered. Influences of external mass transfer as well as substrate and product adsorption on interpretation of the experimental data have been examined. Immobilization of a glucose oxidase-gluconolactonase enzyme mixture has been found to increase substantially the ratio of gluconolactonase to glucose oxidase activities compared to the corresponding activity ratio for these enzymes in solution.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 570-577 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Commercial microbiological processes frequently contain dispersed microorganisms which are heterogeneous in their age, size, and composition. Relative protein and nucleic acid contents of individual bacteria in Bacillus subtilis submerged cultures have been measured experimentally using laser flow microfluorometry. Marginal and joint population composition density data and their complex patterns of evolution during batch growth provide an impetus and emerging basis for a new generation of potentially robust mathematical models of microbial systems.
    Additional Material: 9 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 16 (1976), S. 507-509 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In a previous paper, results of morphological studies using electron microscopy and X-ray diffraction were reported concerning random and non-random olefin copolymers of ethylene. As comonomers, relatively low concentrations of n-alpha alkenes and 5-methyl norbornene-2 were used. It was tentatively concluded that one possibility for morphological changes observed in the n-alpha alkene copolymers was a change in direction of chain folding. These studies have been continued with copolymers of ethylene and acenaphthylene. The intent was to pursue effects of vicinal substitution; however, the result was to produce ethylene copolymers of quite high comonomer content which were crystalline and showed no evidence of an independent beta mechanical transition. Further, definite evidence was found to indicate a change in the direction of chain folding in the polymer crystals.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 16 (1976), S. 510-511 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyolefins are generally known either as partially crystalline thermoplastics or as elastomers. With the finding in the ethylene-acenaphthylene copolymer system of the unusual properties of high crystallinity, high modulus, and no independent beta thermomechanical transition at high comonomer contents, it appeared that it might be possible to prepare a block polymer system which would retain the desirable low temperature transition near -110°C and “hard” acenaphthylene copolymer segments as well. Attempts were made, and the resulting terpolymer is described. An intermediate crystallinity polymer of apparently broad composition distribution was obtained with the modulus of high density polyethylene but the elongational characteristics of low density polyethylene.
    Additional Material: 1 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 16 (1976), S. 734-734 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 48 (1976), S. 50-50 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 16 (1978), S. 507-513 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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