ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Three preparative-scale gel permeation chromatography columns were constructed and filled with Corning porous-glass packing materials. Each column was packed with a different pore-size materials, CPG 10-2000, CPG 10-350, CPG 10-120, all of which had been treated with hexamethyldisilazane. An additional preparative-scale column packed with Styragel, nominal porosity 5 × 104 Å, was added to complete the column bank. Polystyrene standards were used to investigate the effects of molecular weight and sample concentration upon elution volume. A commerical polystyrene sample was fractionated using this system to study the effects of sample concentration and flow rate on fractionation efficiency. These fractions were analyzed by high-resolution analyticalscale gel permeation chromatography. Where possible, the results have been compared with similar studies that used Porasil (Spherosil) and Styragel columns.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1975.070190210
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