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  • American Institute of Physics  (33)
  • Springer  (30)
  • American Chemical Society (ACS)
  • 1975-1979  (63)
  • 1975  (63)
  • 1
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of triphenylphosphine — (1 — (di(trifluoromethyl) — hydroxymethyl) — cyclopentadienyl) — (1,2 — di(carboxymethyl)ethylene — 1 — yl) — ruthenium (0) has been studied by single-crystal X-ray diffraction techniques. This compound, [C5 H4(CF3)2 COH] Ru(PPh3)C2(CO2Me)2H, crystallizes in the triclinic space groupP¯1 witha =10.131,b= 15.107,c= 10.798 Å, α = 102.14,β = 107.04, γ = 89.64° andZ = 2. The structure was refined by block-diagonal least-squares methods to a finalR value of 0.042, including hydrogen atoms. The compound contains a dicarboxymethylethylene ligand coordinated to ruthenium both through a ketonic oxygen and through a metal-β-carbon σ-bond. An intramolecular hydrogen bond is observed. Details of the structure are reported, and the structures of several Ru(0) complexes are compared.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 4 (1975), S. 399-412 
    ISSN: 1572-8927
    Keywords: Raman ; infrared ; sulfur dioxide ; bisulfite ; pyrosulfite ; sulfite ; water ; deuterium oxide ; interaction ; structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Raman and infrared spectra of gaseous SO2 and SO2 dissolved in H2O and D2O have been recorded. Although the results are in general agreement with previous work, some new infrared data is presented, as well as results on the effect of phase and solvent change on the infrared and Raman spectra. Previous workers have used the technique of vibrational spectroscopy to investigate the structure of the pyrosulfite ion in solution. The present study indicates that it is difficult to make conclusive statements concerning the structure of this ion on the basis of present and previous work. Solutions containing the sulfite ion have also been studied. Spectral differences between previous studies have been investigated, and an earlier study by Bernstein is essentially substantiated, although the present work does indicate, some discrepancy in the 900–1100-cm− region for this ion.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Computers and the humanities 9 (1975), S. 145-150 
    ISSN: 1572-8412
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Media Resources and Communication Sciences, Journalism
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of environmental contamination and toxicology 14 (1975), S. 265-272 
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Summary Soil and dust samples from beneath citrus trees contained relatively high concentrations of paraoxon and parathion for at least 45 days after parathion was applied at normal rates. These data indicate that parathion dripping on dry soil from sprayed crops, or sprayed directly on the soil surface, can persist for long periods and be oxidized to the highly toxic paraoxon. The residue concentrations are much higher on the loose dust particles than in the bulk soil. The data indicate that the soil or grove floor should be considered as a possible contributing source of toxicant along with foliage, or dust on foliage, to workers reentering treated fields. In any event, the data confirmed the high rates of oxidation of parathion to paraoxon on particulate matter, whether on foliage (SPEAR et al., 1974) or at the soil surface. The particulate matter appears to contribute to the accumulation of paraoxon, either by enhancing oxidation of parathion to paraoxon or by decreasing dissipation of paraoxon.
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  • 5
    ISSN: 1573-0832
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract An inhibitor of Aspergillus flavus has been isolated from peanuts and identified as 5,7-dimethoxyisoflavone. Authentic 5,7-dimethoxyisoflavone, synthesized from benzyl-2-hydroxy-4,6 dimethoxyphenyl (3), and the isolated compound display identical ultraviolet spectra in methanol, in methanol+sodium methoxide, and in methanol+AlCl3; similar behavior in solvent extraction, column chromatography, TLC, and fungal inhibition.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Solar physics 43 (1975), S. 107-110 
    ISSN: 1573-093X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We consider a beam driven unstable plasma and estimate the turbulent electric fields which may be excited by this beam. We then estimate the Stark broadening due to such fields.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    The annals of regional science 9 (1975), S. 1-8 
    ISSN: 1432-0592
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geography , Economics
    Notes: Abstract Employment multipliers for the metropolitan economy of Vancouver are derived from both economic base and input-out-put models of the region. The principal shortcomings of the location quotient approach in delineating the economic base of a region are reviewed, and empirical estimates are made of the understatement of exports resulting from this approach in light of survey data. The survey data and the author's judgment are then employed to yield a base employment multiplier of 1.99 for the region. Sectoral input-output employment multipliers are presented and conditions are derived under which an aggregated I-O multiplier is equal to the multiplier associated with the economic base model.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 1 (1975), S. 69-73 
    ISSN: 1432-0495
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Unequivocal identification of irrigation return water through routine chemical analyses does not appear possible in tropical volcanic islands. Several constituents, nevertheless, will suggest an agricultural source if they are present in large concentrations. Nitrate is the most useful indicator; background concentrations are generally less than 2 ppm but return irrigation water will commonly have concentrations of between 5 and 50 ppm. Sulfate appears to be the next most useful indicator. Calcium, silica, and bicarbonate have also been reported to be significant. Where detailed studies have been made of agricultural water balances, regional ground-water flow directions, and deep-well hydraulics, hydrochemistry can provide critical supporting data for the identification of return irrigation water which could be a potential ground-water pollutant.
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  • 9
    ISSN: 1432-0886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract A new method for gene mapping at the chromosome level using in situ hybridization and scanning electron microscopy is described and has been applied to mapping the rRNA genes of Drosophila melanogaster. Biotin is covalently attached to Drosophila rRNA via a cytochrome c bridge at a ratio of one cytochrome-biotin per 130 nucleotides by a chemical procedure. Polymethacrylate spheres with a diameter of ca. 60 nm are prepared by emulsion polymerization and are covalently attached to the protein avidin at a ratio of 5–20 avidins per sphere. The biotin-labeled rRNA is hybridized to denatured DNA in a chromosome squash. Upon incubation with a sphere solution, some of the biotin sites become labeled with spheres because of the strong non-covalent interaction between biotin and avidin. The chromosome squash is examined in the scanning electron microscope (SEM). Polymer spheres, which are visible in the SEM, are observed to label the nucleolus, where the rRNA genes are located.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of comparative physiology 96 (1975), S. 223-236 
    ISSN: 1432-1351
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary 1. A pair of thermoreceptor units was identified in the sensilla coeloconica at the tip of the antennae on the mosquito,Aedes aegypti. 2. One thermoreceptor was warm-sensitive and responded with a phasic-tonic increase in spike frequency to sudden increases in temperature. The second thermoreceptor was coldsensitive, responding with a phasic-tonic increase in spike activity to sudden decreases in temperature. 3. The mean tonic spike activity of both the cold and warm receptors increased with increasing temperature to a peak of 30 imp/sec at 26
    Type of Medium: Electronic Resource
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