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  • GEOPHYSICS  (222)
  • AERODYNAMICS  (172)
  • Physics  (118)
  • ASTRONOMY  (106)
  • ENERGY PRODUCTION AND CONVERSION  (105)
  • 1980-1984
  • 1975-1979  (723)
  • 1970-1974
  • 1977  (387)
  • 1975  (336)
Collection
Keywords
Publisher
Years
  • 1980-1984
  • 1975-1979  (723)
  • 1970-1974
Year
  • 1
    Electronic Resource
    Electronic Resource
    D2-m-carborane-siloxanes. III. Preparation and properties of trifluoropropyl-modified polymers (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 973-981 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Linear D2-m-carborane-siloxanes with one, two, and three trifluoropropyl moieties per repeat unit were prepared by the condensation reaction between bisureidosilanes and carborane disilanol. Molecular weights between 100,000 and 220,000 were obtained. Compared to fluorosilicones, the trifluoropropyl-modified carborane-siloxanes exhibited greater thermal and oxidative stability and in certain cases comparable solvent resistance. The swelling index for carborane-siloxane elastomers decreased with increasing trifluoropropyl content, although this fluorocarbon moiety did compromise the thermal stability of the carborane system.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150418
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Photoinitiation and electroinitiation in the polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 2673-2684 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The zinc chloride-catalyzed polymerization of 2-vinylnaphthalene (VN) with both photoinitiation and electronitiation methods was examined. Good yields were obtained with both methods, the electroinitiated process being somewhat faster. The mechanism for polymerization initiation was investigated through a detailed comparison of the kinetics. Both initiation methods show a similar response to increasing input energy and to change in salt to monomer mole ratio. Both methods indicate formation of a ZnCl2-(2-VN)2 complex as intermediate with the formation of the species being rate-determining. These results, together with other similar investigations, are then used to deduce a mechanism that involves the formation of an electronically excited donor-acceptor complex. It is argued that in certain salt-stabilized, electron-delocalized, aromatic systems, such excitation is possible in electroinitiation.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170151112
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  • 3
    Electronic Resource
    Electronic Resource
    Electroinitiated polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1563-1571 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As part of a program to extend the range of donor-acceptor-initiated polymerization processes, the electroinitiation of 2-vinylnaphthalene in a zinc chloride-sulfolane solution has been studied. Good conversion yields of well-characterized (NMR, IR, GPC, elemental analysis) poly(vinylnaphthalene) were obtained with the process showing several mechanistic similarities to other donor-acceptor salt electropolymerization systems.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150704
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  • 4
    Electronic Resource
    Electronic Resource
    Electrochemically initiated polymerization of styrene with tetraalkyl and -aryl group VA halide support electrolytes (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1555-1562 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electrochemically initiated polymerization of styrene in methylene chloride solvent with the use of platinum electrodes and tetraalkyl and -aryl group VA halides (i.e., quaternary ammonium, phosphonium, and arsonium compounds) as electrolyte has been investigated. The order of reactivity of the electrolytes with respect to polymerization rate and initiation efficiency was found to be: arsonium 〉 phosphonium 〉 ammonium. Mechanisms involving the electroreduction of the group VA quaternary halides to species capable of electroinitiating polymerization are postulated. The observed losses in solution conductivities during polymerization with the quaternary phosphonium and arsonium electrolytes indicate possible interaction between the initiating radical-ionic species and the supporting electrolyte. In an attempt to further elucidate the mechanism of initiation in these systems, a separate series of experiments, employing the nonpolymerizing monomer, 1,1-diphenylethylene, has been carried out.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150703
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  • 5
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    National geodetic satellite program, part 1 (1977)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: Equipment and techniques were evaluated operationally, by the Department of Defense, during the National Geodetic Satellite Program (NGSP). The theory, instrumentation, and data reduction methods used are described. Results obtained during the NGSP are given.
    Keywords: GEOPHYSICS
    Type: NASA, Washington Natl. Geodetic Satellite Program, Pt. 1; p 139-245
    Format: text
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  • 6
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    Spectral observations of Eta Carinae at 4 microns (1977)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: Spectral observations of the central region of the Eta Carinae nebula at 4 microns have measured the Brackett-alpha hydrogen recombination-line intensity. The bulk of the line and continuum radiation arises in a small central source which is slightly narrower in the line radiation and is barely resolved by the employed beamwidth of 3.4 arcsec. The continuum radiation is well-fitted by an exponential relation to a distance of 10 arcsec from the central source. The line intensity requires a central source which emits 10 to the 49th power ionizing photons per sec into a region of electron density greater than 1 million per cu cm.
    Keywords: ASTRONOMY
    Type: Astrophysical Journal; vol. 217
    Format: text
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  • 7
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    Gamma-ray astronomy in the medium energy (10-50 MeV) range (1977)
    In:  Other Sources
    Details
    Publication Date: 2011-08-17
    Description: To observe the medium energy component of the intense galactic center gamma-ray emission, two balloon flights of a medium energy gamma-ray spark chamber telescope were flown in Brazil in 1975. The results indicate the emission is higher than previously thought and above the predictions of a theoretical model proposed.
    Keywords: ASTRONOMY
    Type: ESA Recent Advan. in Gamma-Ray Astronomy; p 117-124
    Format: text
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  • 8
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    An investigation of several numerical procedures for time-asymptotic compressible Navier-Stokes solutions (1975)
    In:  CASI
    Details
    Publication Date: 2016-06-07
    Description: The status of an investigation of four numerical techniques for the time-dependent compressible Navier-Stokes equations is presented. Results for free shear layer calculations in the Reynolds number range from 1000 to 81000 indicate that a sequential alternating-direction implicit (ADI) finite-difference procedure requires longer computing times to reach steady state than a low-storage hopscotch finite-difference procedure. A finite-element method with cubic approximating functions was found to require excessive computer storage and computation times. A fourth method, an alternating-direction cubic spline technique which is still being tested, is also described.
    Keywords: AERODYNAMICS
    Type: Aerodynamic Analyses Requiring Advanced Computers, Pt. 1; p 437-468
    Format: application/pdf
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  • 9
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    Periodic variations in stratospheric meridional wind from 20 to 65 km - 80 N to 70 S (1975)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: Long-term periodic features in the meridional wind between 20 and 65 km attitude are analyzed. No appreciable periodic waves are found in the tropics. The quasi-biennial oscillation, annual wave, and four-month wave have maximum amplitudes of about 10, 20, and 10 m/s respectively in the arctic near 45 km. The phase of the annual wave changes by nearly 180 deg in a narrow zone near 45 deg N. The semiannual wave has an amplitude of 10 m/s near 50 deg N above 50 km with equinoctial phase dates in the region of maximum amplitude. The location of this polar semiannual wave corresponds closely to that previously found in the zonal wind.
    Keywords: GEOPHYSICS
    Type: Royal Meteorological Society; vol. 101
    Format: text
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  • 10
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    Description and review of global measurements of atmospheric species from GASP (1977)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: A large volume of atmospheric constituent data is being collected in the global airlanes by specially equipped B-747 aircraft. This NASA program also obtains data from the similarly equipped NASA CV-990 aircraft during dedicated flights such as a recent near pole-to-pole latitude survey mission. Aerosol composition data are also collected with a NASA F-106 aircraft. Present measurements include ozone, carbon monoxide, water vapor, aerosol and condensation nuclei number densities, sulphates, nitrates, and the chlorofluoromethanes. Meteorological and flight parameters are also recorded for use in data analysis. The present aircraft operations obtain data between 6 and 13.5 km from 65 deg N between Europe and the North Pacific, and from 23 deg S over South America and 42 deg S over New Zealand. Typical constituent data from the aircraft operations during the first one and a half years are presented. Instrumentation is discussed.
    Keywords: GEOPHYSICS
    Type: Conference on Air Quality Meteorology and Atmospheric Ozone; Jul 31, 1977 - Aug 06, 1977; Boulder, CO; US
    Format: text
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