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  • Analytical Chemistry and Spectroscopy  (68)
  • Physics  (61)
  • Chemical Engineering  (50)
  • Cell & Developmental Biology
  • GENERAL
  • 1970-1974  (229)
  • 1955-1959
  • 1950-1954
  • 1974  (229)
Collection
Keywords
Publisher
Years
  • 1970-1974  (229)
  • 1955-1959
  • 1950-1954
Year
  • 1
    Electronic Resource
    Electronic Resource
    Normal coordinate analysis of cis-1,4-polybutadiene (1974)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 12 (1974), S. 445-454 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The fundamental vibrational frequencies of an isolated chain of cis-1,4-polybutadiene have been calculated. Infrared and polarized Raman data are used in the force constant refinement routine. The assignments of the vibrational frequencies are discussed in terms of the potential energy distribution.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1974.180120301
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  • 2
    Electronic Resource
    Electronic Resource
    Cationic starch-polyacrylonitrile graft copolymer latexesPresented at the 8th Great Lakes Regional Meeting, American Chemical Society, West Lafayette, Indiana, June 3-5, 1974. (1974)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 12 (1974), S. 2683-2692 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Acrylonitrile (AN) was graft-polymerized onto gelatinized cationic starch (CS) possessing diethylaminoethyl ether groups by cerium (IV) initiation to give stable latexlike copolymer dispersions. Dispersions of the latex copolymers, having up to 50% grafted polyacrylonitrile (PAN), air- and heat-dry on glass to clear, adhesive films. Sonification of up to 8% dispersions at 20 Khz reduced their viscosities from 1500-3000 cP to 15-40 cP. Scanning electron microscopy revealed that both nonsonified and sonified dispersions consist of ball-like particles measuring about 0.05-0.15 μ in diameter when dry. The films are formed by coalescence of these particles. The degree to which AN grafts onto CS at ambient temperature is related to the nitrogen content of CS, gelatinization time of CS at 95°C, sequence of AN and cerium(IV) addition, concentration of cerium (IV), concentration of AN, and severity of reaction agitation. Number-average molecular weight values of PAN were about 106 when grafting was conducted under stirring and about 5 × 105 when conducted under shaking action.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1974.170121122
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  • 3
    Electronic Resource
    Electronic Resource
    Influence of crystal size on the rate of contact nucleation in stirred-tank crystallizers (1974)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 653-659 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The purpose of this study was to investigate the influence of seed crystal size on the rate of nucleation in batch stirred-tank crystallizers. Experimental results confirm the existence of such an effect. Nucleation rate data are correlated with a second-order polynomial in seed crystal size; coefficients of the correlation are functions of the solute-solvent system, crystallizer geometry, and mixing conditions. The empirical correlation is incorporated into a population balance model for determining the nucleation rate in multi-seed crystallizers. The observed results are explained in terms of variations in impact energy, circulation frequency, and target efficiency.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690200404
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  • 4
    Electronic Resource
    Electronic Resource
    A quantitative method of sample loading for field desorption mass spectrometry (1974)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 1 (1974), S. 358-362 
    Details
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A quantitative method for loading nanogram samples onto field desorption emitter wires is described. Sample consumption is reduced and problems with emitter wettability are overcome by freezing microliter droplets onto the emitters. Using this technique, good spectral data are obtained from 10 to 50 ng of material. Field desorption sensitivity measurements are reported for neomycin B, adenosine and cholesterol. Evaluation of the nonquantitative dipping technique previously employed reveals poor and nonreproducible sample loading efficiency.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bms.1200010513
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  • 5
    Electronic Resource
    Electronic Resource
    Editorial (1974)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 14 (1974), S. 161-161 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760140302
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  • 6
    Electronic Resource
    Electronic Resource
    The influence of additives on the flow behavior of ABS (1974)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 14 (1974), S. 806-809 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow and processing behavior of commercial plastics is determined not only by the characteristics of the base resin but also by the presence of additives of various kinds. In this study the influence of a number of additives on the rheological behavior of molten ABS was investigated using a capillary extrusion rheometer and a Weissenberg rheogoniometer. The additives studied included molding lubricants, rubber impact modifiers, flame-retardant additives, and residual unreacted components remaining from the polymerization process. The mechanisms by which these species affect flow characteristics are described.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760141113
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  • 7
    Electronic Resource
    Electronic Resource
    Glycolytic enzyme activity in developing red and white muscle (1974)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Cellular Physiology 83 (1974), S. 251-257 
    Details
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The activities of the constant proportion enzymes of the Embden-Meyerhof chain (triose phosphate isomerase (TIM), glyceraldehyde-3-phosphate dehydrogenase (GAPDH), phosphoglycerate kinase (PGK), phosphoglycerate mutase (PGM) and enolase (ENOL)), and the activity of lactic dehydrogenase (LDH) were studied in developing red (trapezius) and white (longissimus) muscles of the pig from a fetal stage to 24 weeks postnatal. Both muscles were differentiated by two weeks postnatal in the sense that they had reached the adult level of enzyme activity. Enzyme activities were two- to three-fold greater in the longissimus than in the trapezius. Enzyme activity ratios based on GAPDH were not consistent in the fetal and day 1 samples but were consistent during later stages of growth. Ratios of enzyme activity based on activity at 105 days gestation revealed that TIM, PGK and PGM are grouped and follow the same pattern, but GAPDH and ENOL are quite different from each other and from the pattern shown by TIM, PGK and PGM. The constant proportion concept in developing muscle is therefore questioned.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jcp.1040830211
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  • 8
    Electronic Resource
    Electronic Resource
    Cell cycle dependent modulations of the surface membrane of normal and SV40 virus transformed 3T3 cells (1974)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Cellular Physiology 84 (1974), S. 343-348 
    Details
    ISSN: 0021-9541
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Agglutinability with Concanavalin was studied as function of cell cycle transition in normal and SV40 virus transformed 3T3 cells. In synchronized cultures of normal cells, agglutinbility was high during mitosis and disappeared rapidly. Agglutinability of transformed cells remained high in G1 phase but diminished gradually upon entering S phase and reached minimum in G1 phase. Decreased agglutinability a the end of the cell cycle was also observed in synchronous SV3T3 cultures by a combined technique of haemadsorption and density gradient centrifugation. In normal 3T3 cells, similar variations in agglutin ability during interphase could not be observed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jcp.1040840303
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  • 9
    Electronic Resource
    Electronic Resource
    A search for the mosaic block structure in polyethylene single crystals (1974)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 12 (1974), S. 1015-1022 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A diffraction contrast study with the aid of an image intensifier was undertaken to obtain direct evidence for the existence of a mosaic block structure in polyethylene single crystals grown by self seeding under isothermal conditions. Dark-field microscopy indicates that the crystals do not contain a mosaic block structure. High-resolution electron diffraction confirms that the crystal is coherent (i.e., mosaic block-free) over regions of several thousands of Angstroms. It is concluded that a mosaic structure on the scale of ∼300 Å does not exist in polyethylene single crystals grown under carefully controlled conditions from dilute solutions. Possible reasons for previous results that indicate the presence of a ∼300 Å mosaic block structure are discussed.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1974.180120512
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  • 10
    Electronic Resource
    Electronic Resource
    Precipitation chromatography. III. Optimization of the experimental conditions and determination of the polydispersity of fractions (1974)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 12 (1974), S. 239-254 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of the solvent-nonsolvent gradient and the temperature gradient on the efficiency of the precipitation chromatography is investigated with radically and anionically prepared polystyrene samples. Only a combination of both gradients gives optimal effectiveness of the column. The separating power of the column was determined by using mixtures of well defined samples. From the elution curves of the mixtures the nonuniformity Ufr of fractions can be estimated. For fractions of anionically prepared polystyrenes Ufr is on the average 0.001; this value is of the same order of magnitude as the statistical error. These results show that with this chromatographic method it is possible to determine the narrow molecular weight distributions of anionically prepared polystyrenes (or other polymers) with an accuracy sufficient for kinetic studies.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1974.180120202
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