ISSN:
0098-1273
Schlagwort(e):
Physics
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
The change in standard chemical potential of a number of alkanes on PDMS going from dilute solution to the perfect vapor ΔḠov was measured by gas chromatography over a large range of temperatures. The change in standard chemical potential of the alkane going from the pure liquid to the perfect vapor ΔḠov was calculated from fugacity data. These data were fitted separately to three Taylor's series expansions wherein the (partial) heat capacity of vaporization is zero, constant, and linearly dependent on temperature, respectively. On the basis of statistical and physical arguments it was concluded that the partial excess functions determined by gas chromatography should be described with a temperature-independent partial excess heat capacity.
Zusätzliches Material:
2 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pol.1974.180121008
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