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  • Chemistry  (292)
  • Analytical Chemistry and Spectroscopy  (50)
  • Wiley-Blackwell  (292)
  • 1970-1974  (292)
  • 1973  (292)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 415-416 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 1339-1360 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Free-radical polymerization in a flow reactor represented by the tanks-in-series model with backflow was considered. Conversions and molecular weight distributions were computed as functions of the backflow parameter, and the results were compared with the conversion and molecular weight distribution from a CSTR and those from a plug-flow reactor. Backflow was found to be undesirable for the polymerization mechanism under investigation. Values of the degree of segregation for the tanks-in-series model were calculated by using Zwietering's approach as a function of backflow.
    Additional Material: 11 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 15 (1973), S. 1101-1121 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamic behavior of a laboratory-scale activated sludge biological waste treatment process with recycle and wasting of sludge was investigated by subjecting the system to step changes in the influent waste concentration, the recycle flow rate, or the sludge wasting rate. The dynamic behavior of the system was examined by measuring adenosine triphosphate (ATP) in addition to dissolved chemical oxygen demand (COD) and cell dry weight in the aeration tank. Cell dry weight of the recyle flow and effluent COD were also measured.Analysis of the results and estimation of time constants assuming first order responses showed that the time constants characterizing the dynamic responses of the sludge were directly related to the sludge mean residence time. The time constants estimated from dissolved COD measurements were of the same order of magnitude as the fluid residence time in the aeration tank. The ATP transient response was frequently different from that of the cell dry weight in the aeration tank.
    Additional Material: 13 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 1239-1243 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The method of stochastic (Monte Carlo) simulation is employed to determine variable process performance of a 545 Mg/d ammonia plant. Operating conditions and equipment reliability are varied in a flow sheet simulation model of the process. Probability distributions of the plant production capability and failure times are generated. These data agree closely with the operating experience of an actual ammonia plant.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 12 (1973), S. 2161-2176 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The frequencies and intensities of the laser Raman spectra of poly-L-lysine (PLL) have been observed in the following studies: (1) the thermally induced α-to-β transition which occurs with increasing temperature at high pH; (2) the ionized form to α transition at 10°C by increasing pH; and (3) the ionized form to α transition by ionic strength at low pH.The frequency-dependent bands which have been observed are the amide I (in H2O), amide I′ (in D2O), amide III, and C-C stretch. It has been found possible to assign an unique set of frequencies and intensities to each conformation of PLL of α, β, and ionized form. In this way the nature of the conformations intermediate in the transitions can be determined. The frequencies of the amide III and amide III′ are very weak in the α-helix and somewhat higher than usual in the β form. Hence it appears the amide III and amide III′ bands may differ from one type of polypeptide to another with the same backbone conformation.
    Additional Material: 11 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 455-461 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Pronounced effects of thermal treatment on the properties of graphite fiber/polycarbonate and glass fiber/polycarbonate composites have been demonstrated and explained. At 20 volume percent loading of random-in-a-plane, discontinuous fibers, both specimen strength and modulus in both fiber systems were found to increase dramatically upon molding above 260-265°C, whereas only the graphite system was further improved by subsequent annealing. In the latter case, property improvement is due to generation of a crystalline innerlayer at the interface, which apparently transfers the stresses more effectively from fiber to fiber. Regardless of the type of fiber, molding at 275°C (slightly above 260-265°C, the melting point of crystalline polycarbonate) results in improved properties due to better wetting of the fibers by the resin. Hot forming of graphite reinforced polycarbonate composites between the molding and annealing steps takes advantage of the higher processability of the unannealed material in addition to providing increased modulus and strength in the final molded article.
    Additional Material: 8 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 280-286 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The physical structure of a number of styrene-butadiene copolymers were investigated via dynamic mechanical and swelling studies on uncrosslinked and gamma-radiation cross-linked films that had initially been solvent cast from toluene or methyl ethyl ketone. The mechanical behavior of these films before and after crosslinking was found to depend on the material history as well as the chemical structure of the copolymer, in agreement with observations made by other experimental techniques. A simple morphological interpretation was given to the dynamic mechanical spectra as a function of radiation dosage and a limited discussion of the swelling behavior is included.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 469-469 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 194-201 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow pattern of a polyethylene melt in the working gap of a disc-type extruder has been visualized. It is shown that there is complex circulating flow in the working gap of the extruder. The flow lines are spirals of Archimedes. An investigation into the qualitative picture of the flow of a polyethylene melt in rotational devices of the “plate-plate” and “cone-plate” type showed that in such devices a complex circulating flow is also realized and the flow lines are spirals of Archimedes.
    Additional Material: 10 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 3127-3141 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of chaln transfer, diffusion control, and temperature on the optimal design and selection of polymerization reactors was investigated. Chain transfer to the monomer was examined and a parametric study of the corresponding rate constant was carried out. The Trommsdorff effect was included in the model by using a diffusion-controlled termination process. An optimum temperature sequence was determined for this modified model by incorporating the effect of temperature on the rate constants and on the amount and rate of heat removal. Furthermore, the concept of dividing the plug flow reactor into several constant temperature zones was considered, and the effect of “zoning” on the system performance was determined.
    Additional Material: 1 Ill.
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