ISSN:
0006-3525
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The electrostatic potential of an infinitely long cylinder with a periodic, discrete charge density was calculated, assuming the cylinder was immersed in a simple 1 : 1 electrolyte solution. The charge density of the simple electrolyte was taken to be the linearized Debye-Hückel charge density. It was also assumed that the discrete charge density, was within the cylinder (rather than on its surface), and that the interior of the cylinder had a unique dielectric constant Dh, which was treated as a parameter. Although this model (except for the Debye-Hückel assumption) more realistically represents DNA than previous models, the calculated potential was found to be ambiguous, depending on the value chosen for the depth of the discrete charge below the cylinder surface. However it was also found that the dependence of the potential on the simple electrolyte concentration was well-defined and was identical to that of a continuously charged cylinder. It was concluded that the continuously charged cylinder model adequately describes differential salt effects.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/bip.1973.360120309
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