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  • CHEMISTRY  (55)
  • PROPULSION SYSTEMS  (52)
  • ASTROPHYSICS
  • 1970-1974  (107)
  • 1955-1959
  • 1972  (107)
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  • 1970-1974  (107)
  • 1955-1959
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  • 1
    Publication Date: 2019-06-27
    Description: The molecular and atomic mechanisms for the hydrogen-iodine exchange reaction are treated theoretically by means of extensive classical trajectories calculated on a reasonable potential energy surface on which the single adjustable parameter is the iodine-core effective charge. The analysis shows the molecular mechanism to be dynamically forbidden, but gives an over-all rate constant for the atomic mechanism that is in agreement with the experimental values. It is indicated that the formation of a weak H2I complex plays an important dynamical role if the atomic mechanism is limited to reactions with collision complexes involving no more than two hydrogen atoms and two iodine atoms. Excellent agreement with experiment is obtained for the rate constant for the recombination I+I+H2 yields I2+H2 and its negative temperature coefficient.
    Keywords: CHEMISTRY
    Type: Journal of Chemical Physics; 56; June 15
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  • 2
    Publication Date: 2011-08-16
    Description: Measurement of the N2 concentration and temperature, the ion composition and concentrations, and the electron temperature up to 290 km about 30 and 5 min before totality during the Mar. 7, 1970, eclipse. The rockets traveled similar trajectories, thus permitting the purely temporal changes between flights to be resolved. The neutral temperature and N2 concentration changed little, but the electron temperature decreased by as much as 20% in the lower F region. The ion concentration decreased by about 30% in the F region and about 50% in the E region, with little change in relative ion composition. The electron cooling rates decreased by a factor of 6 in the lower F region, approximately in proportion to the change in the visible solar disk. A smaller than expected decrease in the cooling rate below 150 km between the two flights indicates a hardening of the solar spectrum and suggests a significant heat contribution from the solar corona near totality. The ion composition measurements were consistent with solutions of the ion continuity equations. A proper fit required a factor-of-three enhancement of the flux below 200 A, an amount also consistent with the electron heat balance analysis. Reactions involving the minor ions N(+) and N2(+) were found to be important for the ion chemistry of the major ions O2(+) and NO(+), especially at the time of eclipse.-
    Keywords: CHEMISTRY
    Type: Journal of Atmospheric and Terrestrial Physics; 34; Apr. 197
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  • 3
    Publication Date: 2011-08-16
    Keywords: CHEMISTRY
    Type: Biochemistry; 11; 15, 1; 1972
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  • 4
    Publication Date: 2011-08-16
    Description: The observation of 'double quantum' transitions which made it possible to determine the charge state of Ti as 2+ is reported. The EPR spectrum observed at 1.2 K is presented in a graph. The first derivative of the absorption is shown vs the magnetic field. The hyperfine patterns for the Ti-47 and Ti-49 isotopes are identified. Spin-Hamiltonian parameters for Ti(2+) in various cubic hosts are listed.
    Keywords: CHEMISTRY
    Type: Journal of Chemical Physics; 57; Oct. 15
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  • 5
    Publication Date: 2019-06-27
    Description: An experimental study of phase equilibria in the He-CH4 system was carried out over the temperature range 95 to 290 K and at pressures to 10,000 atm. The experimental results consist of equilibrium phase composition for twenty-eight isotherms in the region of coexistence of two fluid phases, together with the pressure-temperature trace of the three-phase boundary at which a CH4-rich solid phase is in equilibrium with the two fluid phases. The system exhibits a fluid-fluid phase separation which persists to temperatures and pressures beyond the range of this experiment. These results, together with those recently obtained for other binary systems, provide information about the form of phase diagrams for binary gas mixtures in the region of pressure induced phase transitions at high pressures. These findings are relevant to problems of deep atmosphere and interior structures in the outer planets.
    Keywords: CHEMISTRY
    Type: Univ. Space Res. Assoc. High Pressure Phys. and Planetary Interiors; p 69-77
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  • 6
    Publication Date: 2019-06-27
    Keywords: CHEMISTRY
    Type: Journal of Electroanalytical Chemistry and Interfacial Electrochemistry; 38; 1972
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  • 7
    Publication Date: 2019-06-27
    Keywords: CHEMISTRY
    Type: Earth and Planetary Science Letters; 17; Dec. 197
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  • 8
    Publication Date: 2019-06-27
    Description: A preliminary mission study of a reusable vehicle from staging to orbit indicates payload advantages for a dual-propulsion system consisting of separate scramjet and rocket engines. In the analysis the scramjet operated continuously and the initiation of rocket operation was varied. For a stage weight of 500,000 lb the payload was 10.4 percent of stage weight or 70 percent greater than that of a comparable all-rocket-powered stage. When compared with a reusable two-state rocket vehicle having 50,000 lb payload, the use of the dual propulsion system for the second stage resulted in significant decreases in lift-off weight and empty weight, indicating possible lower hardware costs.
    Keywords: PROPULSION SYSTEMS
    Type: NASA-TN-D-6762 , E-6555
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  • 9
    Publication Date: 2019-07-13
    Description: The stabilizing influence of acoustic cavities (quarterwave acoustic resonators) on acoustic modes of combustion instability has been studied. The ability to analytically predict cavity damping was improved. Relatively good agreement between predicted damping and measured stability was demonstrated. Full-scale motor firings were made to evaluate the influence of several parameters on stability. Results from these firings showed that stability was changed, but not dramatically, by changes in the engine operating conditions. Variations in the film-coolant flowrate do not significantly affect cavity stabilization. The ability to stabilize an engine with unconventional cavity configurations was demonstrated.
    Keywords: PROPULSION SYSTEMS
    Type: AIAA PAPER 72-1147 , Joint Propulsion Specialist Conference; Nov 29, 1972 - Dec 01, 1972; New Orleans, LA; US
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  • 10
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    In:  CASI
    Publication Date: 2005-11-30
    Description: The selection and design of velocity diagrams for axial flow turbines are considered. Application is treated in two parts which includes: (1) mean-section diagrams, and (2) radial variation of diagrams. In the first part, the velocity diagrams occurring at the mean section are assumed to represent the average conditions encountered by the turbine. The different types of diagrams, their relation to stage efficiency, and their selection when staging is required are discussed. In the second part, it is shown that in certain cases the mean-section diagrams may or may not represent the average flow conditions for the entire blade span. In the case of relatively low hub- to tip-radius ratios, substantial variations in the velocity diagrams are encountered. The radial variations in flow conditions and their effect on the velocity diagrams are considered.
    Keywords: PROPULSION SYSTEMS
    Type: Turbine Design and Appl., Vol. 1; p 69-99
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