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  • AERODYNAMICS  (152)
  • EARTH RESOURCES AND REMOTE SENSING  (145)
  • Physics  (129)
  • 1980-1984  (300)
  • 1970-1974  (126)
  • 1980  (300)
  • 1972  (126)
Collection
Keywords
Publisher
Years
  • 1980-1984  (300)
  • 1970-1974  (126)
Year
  • 1
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    Thermal mapping, geothermal source location, natural effluents and plant stress in the Mediterranean coast of Spain (1980)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: Although no significant results were achieved during the report period, research continues. A sample of imagery showing thermal inertia and temperature differences over the northeastern United States and Europe was received. The project coordinator attended a TELLUS Project meeting in Ispra, Italy at which general guidelines for the future were established and the quality of the data received was discussed.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: E81-10119 , NASA-CR-164113 , PR-3
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 2
    Electronic Resource
    Electronic Resource
    Copolymerization of styrene and diethyl fumarate with zinc bromide. III. Electroinitiation at low current densities (1972)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 10 (1972), S. 3267-3277 
    Details
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electroinitiated preparation of equimolar copolymers of styrene and diethyl fumarate is described. The reaction medium consisted of these monomers dissolved in a methanol-zinc bromide solution. Rates of polymerization increased with increasing applied current and the copolymer yield increased linearly with the total number of Faradays transferred. The copolymer composition is 1:1 and is essentially invariant with the degree of conversion (〈15%), electroinitiation rate, and monomer feed ratios. A reaction mechanism involving donor-acceptor complexes and electroinitiated excitation of these complexes at the electrode is postulated.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1972.170101113
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  • 3
    Electronic Resource
    Electronic Resource
    Copolymerization of styrene and diethyl fumarate with ZnBr2. IV. Comparison between photoinitiation and electroinitiation (1972)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 10 (1972), S. 3253-3265 
    Details
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A comparative analysis of photoinitiation and electroinitiation can help elucidate initiation processes in donor-acceptor charge-transfer copolymerization. The technique has been applied to the zinc bromide-catalyzed copolymerization of styrene and diethyl fumarate in methanol. The photocopolymer product was analyzed by GPC, NMR, and elemental analysis. The results showed that 1:1 copolymers were formed initially, but changes occurred in both the kinetics and products after the early stages of the reaction. Significant correlations found between the two initiation methods included the initial kinetic order with respect to the initiating process and the effect on product yield of equivalent increases in total initiation energy. The limiting value of zinc bromide for both initiation methods was found to be the same. The data obtained support the contention that the copolymerization proceeds through a donor-acceptor process and that photoactivation of the preformed complex, inducing electron transfer, is a likely initiation process.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1972.170101112
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  • 4
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    A computational and experimental study of high Reynolds number viscous/inviscid interaction about a cone at high angle of attack (1980)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: The flow over a 5 deg semi-angle cone at incidence in supersonic flow is studied as a model problem for the flow over aircraft forebodies. A computational method utilizing the conically symmetric Navier-Stokes equations is used to obtain theoretical flow results which are compared with experimental data from the Ames Research Center 6- by 6-Foot Wind Tunnel and with results from a cone model sting mounted on an F-15 aircraft. The computed results agree well with the wind-tunnel data but less well with the flight data. Modification of the algebraic turbulence model was necessary to reflect an apparent lower turbulence level in flight than was present in the wind tunnel.
    Keywords: AERODYNAMICS
    Type: AIAA PAPER 80-1422 , Fluid and Plasma Dynamics Conference; Jul 14, 1980 - Jul 16, 1980; Snowmass, CO
    Format: text
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    NASA TECHNICAL REPORTS
  • 5
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    Studies of high latitude current systems using Magsat vector data (1980)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: Disturbance fields caused by global external current systems are analyzed in order to gain an improved understanding of the phydical processes which control high latitude current systems and to increase the confidence level in the identification of internal field levels. The basic approach is to: (1) categorize the vector data by those physical parameters important for investigation of external current systems; (2) map the disturbances for appropriate conditions; (3) model the currents which might cause the mapped disturbances; and (4) correlate results with data from other sources. It is concluded that the Magsat data set appears to have remarkably high precision and quality and should permit major advances to be made in modeling current distribution at high latitudes in the ionosphere and magnetosphere.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: E81-10085 , NASA-CR-163785 , PR-1
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 6
    Electronic Resource
    Electronic Resource
    Crystallization of poly(ethylene oxide) fractions: Crystallization isotherms (1972)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 10 (1972), S. 1555-1564 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The crystallization kinetics of a range of fractions of poly(ethylene oxide) are presented and analyzed. It is concluded that deviations from the Avrami equation with exponent of 3 are mainly due to rejection of low molecular weight molecules for the low molecular weight fractions (M̄n 〈 6,000) and to a process of crystal perfecting for the high molecular weight fractions (M̄n 〉 6,000).
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1972.160100812
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  • 7
    Electronic Resource
    Electronic Resource
    Crystallization of polyethylene at high pressure: A kinetic view (1972)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 10 (1972), S. 1811-1836 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A model for the crystallization kinetics of polymers is outlined and is used to interpret observations of the crystallization of polyethylene at high pressures. This model introduces a distinction between σe the lamellar surface energy which controls the lamellar thickness, and σe′, the surface nucleus surface energy which controls the growth rate. Differential scanning calorimetry and electron microscopy data for several polyethylenes crystallized at pressures of up to 8 kb are presented. From the dependence of lamellar thickness on the crystallization undercooling at 5 kb, it is found that σe increases markedly with pressure leading to the formation of very thick crystals at high pressures. The magnitude of the increase in σe is in agreement with σe values calculated from the dependence of melting temperatures on pressure. The nucleus surface energy σe′ is not expected to vary significantly with pressure, and estimates of growth rates of 5 kb which indicate that the growth rate does not vary significantly with pressure at constant under-cooling confirm this. Fractionation effects and the differences in behavior between different polyethylenes are also discussed.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1972.160100916
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  • 8
    Electronic Resource
    Electronic Resource
    Structure analysis of chain-folded lamellar polyamide crystals from X-ray diffraction (1972)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 10 (1972), S. 863-875 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Folded-chain crystals of certain polyamides present some novel diffraction effects due to the small number of repeat units within the lamellar thickness. X-ray diffraction evidence is available in the complete range from low to wide angles. This information is interpreted in terms of the structure factor of an individual lamella together with the lattice factor appropriate for the stacking of lamellae. When due account is taken of the lattice factor, whose effect can be detected even at large angles, three features of the lamellar structure can be deduced. First, the evidence is in favor of the straight-chain stems traversing almost the total thickness of each lamella, implying sharp folds at the lamellar surfaces. Some consequences of this result on the interpretation of data obtained from annealed mats are mentioned. Second, the detailed determination of the stem structure demands that the majority of the folds in nylon 66 lie in the acid group. Third, there are regions of depleted electron density at the lamellar surfaces, though features of the crystal structure are still retained. This indicates the presence of some folds deeper in the crystal than the majority.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1972.160100508
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  • 9
    Electronic Resource
    Electronic Resource
    Plasma polymerization. III. An ESCA investigation of polymers synthesized by excitation of inductively coupled RF plasmas in perfluorocyclohexa-1,3- and 1,4-dienes, and in perfluorocyclohexeneThis is Part XXVIII of the series “ESCA Applied to Polymers.” (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 407-425 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The plasma polymers prepared from perfluorocyclohexa-1,3-diene, perfluorocyclohexa-1,4-diene, and perfluorocyclohexene have been investigated by ESCA. The carbon-to-fluorine stoichiometries of the diene-derived polymers are similar and close to that of the starting material. The polymer prepared from perfluorocyclohexene is depleted in fluorine compared to the fluorine content of the “monomer.” The polymers prepared in nonglow regions are also studied and shown to be high in CF2 derived species. The results are compared with those for perfluorobenzene and perfluorocyclohexane, and the polymerization rates are in the order C6F6 〉 C6F8 1,3 ∼ 1,4 〉 C6F10 ∼ C6F12. The variations in composition of the plasma polymer as revealed by ESCA as a function of the polymerization conditions are discussed.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.170180202
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  • 10
    Electronic Resource
    Electronic Resource
    Photoreactions of radicals during polyolefin photooxidationIssued as NRCC No. 18168. (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 3245-3251 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polypropylene (PP) and polyethylene (PE) peroxy radicals undergo photoreactions, but under commonly encountered photodegradation conditions these reaction rates are much lower than those of conventional radical reactions; for example, for PP peroxy radicals in noon summer sunlight at 25°C their rate of photolysis to alkyl radicals is less than one-tenth of their rate of hydrogen abstraction from the polymer. At lower temperatures( 〈 -10°C) or when more intense radiation is used, however, peroxy radical photolysis becomes a proportionately more important source of alkyl radicals. In addition, occurrence of photoinduced radical combination is confirmed but is shown to be important only when photolysis generates an alkyl radical sufficiently close to a peroxy radical that termination can occur before oxygen reconverts the alkyl radical to a peroxy radical. This termination mechanism therefore becomes more important for radicals generated at lower temperatures when the average separation of a radical pair is lower.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.170181110
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