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  • AERODYNAMICS  (152)
  • Analytical Chemistry and Spectroscopy  (130)
  • Chemical Engineering  (117)
  • 1980-1984  (252)
  • 1970-1974  (147)
  • 1980  (252)
  • 1972  (147)
Collection
Keywords
Publisher
Years
  • 1980-1984  (252)
  • 1970-1974  (147)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Gas chromatography mass spectrometry computer analysis of volatile halogenated hydrocarbons in man and his environment - a multimedia environmental study (1980)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 7 (1980), S. 139-147 
    Details
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As part of a study to make a comparative analysis of selected halogenated compounds in man and the environmental media, a quantitative gas chromatographic mass spectrometric analysis of the levels of the halogenated compounds found in the breath, blood and urine of an exposed population (Old Love Canal area, Niagara, New York) and their immediate environment (air and water) was undertaken. In addition, levels of halogenated hydrocarbons in air samples taken in the general Buffalo, Niagara Falls area were determined.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bms.1200070402
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Vibrational spectra and normal coordinate analysis of CF3OF and CF3OCl (1980)
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 9 (1980), S. 230-238 
    Details
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The IR spectra (1400 cm-1 to 160 cm-1) of the gases at ambient temperature and the Raman spectra (below 1400 cm-1) of the liquids near -196°C are reported for CF3OF and CF3OCl. All fundamentals are assigned under Cs symmetry and the results of a normal coordinate analysis are presented. The assignments of Smardzewski and Fox are adopted with one exception for both CF3OF and CF3OCl: the CF3 rock of A″ symmetry is assigned near 430 cm-1 and the two bands between 200 cm-1 and 300 cm-1 are assigned to an A′ fundamental, involving CF3 rocking and COX bending and a Δν=2 transition in the CF3 torsion. An extra band at 548 cm-1 in the Raman spectrum of liquid CF3 COl near -196°C is assigned to a CF3OCl⃛Cl2 complex. The values of the force constants d(OX) for CF3OX molecules are suggested to be near those for X2O molecules. More than half the normal modes of A′ symmetry show extensive mixing of symmetry coordinates. In some of these cases the symmetry coordinate for which the normal mode is named is the largest but not the dominant contributor to the potential energy distribution, while in others this symmetry coordinate is not even the largest contributor to the potential energy distribution. No normal modes of A′ symmetry are present in which ν(CO), δs(CF3), δ(COX), or δ(CF3) symmetry coordinates are dominant, and the mode conventionally labeled as v(CO) should be labeled as νs(CF3). For the remaining A′ normal modes and all the A″ normal modes, the symmetry coordinate for which the normal mode is named is dominant in the potential energy distribution.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jrs.1250090406
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  • 3
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    A computational and experimental study of high Reynolds number viscous/inviscid interaction about a cone at high angle of attack (1980)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: The flow over a 5 deg semi-angle cone at incidence in supersonic flow is studied as a model problem for the flow over aircraft forebodies. A computational method utilizing the conically symmetric Navier-Stokes equations is used to obtain theoretical flow results which are compared with experimental data from the Ames Research Center 6- by 6-Foot Wind Tunnel and with results from a cone model sting mounted on an F-15 aircraft. The computed results agree well with the wind-tunnel data but less well with the flight data. Modification of the algebraic turbulence model was necessary to reflect an apparent lower turbulence level in flight than was present in the wind tunnel.
    Keywords: AERODYNAMICS
    Type: AIAA PAPER 80-1422 , Fluid and Plasma Dynamics Conference; Jul 14, 1980 - Jul 16, 1980; Snowmass, CO
    Format: text
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    NASA TECHNICAL REPORTS
  • 4
    Electronic Resource
    Electronic Resource
    The use of chromatographic profiles for the identification of yeast genera (1980)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 3 (1980), S. 528-530 
    Details
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Two-phase derivatization technique ; Yeast ; Splitless injection ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240031011
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  • 5
    Electronic Resource
    Electronic Resource
    Stability of time-delay systems (1972)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 380-384 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A direct method is presented for determining both local and regional stability of systems described by nonlinear differential-difference equations. Prediction of stability is with respect to a general class of initial curves. The practical as well as the conservative nature of the procedure is demonstrated by a numerical example.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690180221
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  • 6
    Electronic Resource
    Electronic Resource
    The mixing of Granular solids in a rotary cylinder (1980)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 928-934 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is derived for solids mixing and material transport in a continucus flow rotary dryer or reactor. Detailed analysis of the particle motions in the turnover process provides an opportunity to apply well-known reactor models to several subregions and to relate the overall results to different design geometries and operating conditions. The essential parameters of the model are the number of stages, the volume fractions of mixed flow and plug flow in each stage, the recycle ratio and the bypass ratio.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690260607
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  • 7
    Electronic Resource
    Electronic Resource
    Nucleation kinetics of the potassium sulfate-water system (1972)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 798-807 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Secondary nucleation in the potassium sulfate-water system occurs by micro-attrition processes over the entire 1.3-26 μ size range of this study. Experimental nucleation rates were correlated with power-law kinetics expressions in terms of supersaturation, the fourth moment of the parent seed-crystal distribution, and stirring rate. Such kinetics expressions are similar to those used to correlate MSMPR data; however, the secondary nucleation rates of this paper are two orders of magnitude greater than those reported in previous MSMPR studies of the same system. An upper bound on growth rate of these nuclei was calculated based on a population balance analysis; maximum growth rates of these nuclei was markedly size-dependent in the 1.3-26 micron size range of measurement, decreasing with decreasing size. The apparent descrepancy between these nucleation rates and MSMPR values can be explained by nuclei washout during the low growth rate period. Anomalous MSMPR kinetics (low or even negative supersaturation power-law dependence) can be explained by this growth phenomenon.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690180423
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  • 8
    Electronic Resource
    Electronic Resource
    Hydrodesulfurization of benzo[b]naphtho[2,3-d]thiophene catalyzed by sulfided CoO-MoO3/γ-Al2O3: The reaction network (1980)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 690-694 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690260426
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  • 9
    Electronic Resource
    Electronic Resource
    Interfacial instability and spontaneous formation of microemulsions (1972)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 1116-1120 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microemulsions, which are optically transparent oil-water dispersions, were spontaneously produced upon mixing hexadecane, hexanol, potassium oleate, and water in specific proportions. The drop-volume measurements of hexadecane-water interface in the presence of hexanol or potassium oleate revealed that these surfactants decrease the interracial tension of the hexadecane/water interface. It is proposed that the interaction between these two emulsifiers at the oil-water interface causes spontaneous negative interfaical tension resulting in interfacial instability and the formation of microemulsions.As the amount of water is increased, the microemulsion exhibits a clear to turbid to clear transition. Unlike the clear regions, the turbid region possesses birefringence. The development of birefringence is also accompanied by a sharp decrease in electrical resistance. High-resolution (220 Mc) nuclear magnetic resonance data suggest that water exists in two distinct environments or structures in the birefringent region. The electrical, birefringence, and nuclear magnetic resonance data agree with the proposed mechanism of phase-inversion of microemulsions, which can be described as water spheres to water cylinders to water lamellae to a continuous water phase. The spontaneous formation of such structures (for example, water cylinders and lamellae) presumably depends upon the phase-volume ratio and the interfacial tension at the oil-water interface.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690180605
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  • 10
    Electronic Resource
    Electronic Resource
    A random pore model for fluid-solid reactions: I. Isothermal, kinetic control (1980)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 379-386 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For fluid-solid reactions, a random pore model is developed which allows for arbitrary pore size distributions in the reacting solid. The model can represent the behavior of a system that shows a maximum in reaction rate as well as one that does not, and it identifies an optimal pore structure for either of such systems. It is demonstrated that the new model subsumes several earlier treatments as special cases. By comparison with the grain model, a relationship is derived between the effective grain shape factor and a pore structure parameter defined here. When the variance of the pore size distribution is effectively zero, the new results approach those predicted by the Petersen (1957) model over a large range of conversions. The char gasification data of Hashimoto et al. (1979) are shown to produce correlations consistent with the expectations of the new model.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690260308
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