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  • Chemistry  (6)
  • 550 - Earth sciences
  • Life and Medical Sciences
  • 1985-1989
  • 1970-1974  (6)
  • 1965-1969
  • 1971  (6)
Collection
Keywords
Publisher
Years
  • 1985-1989
  • 1970-1974  (6)
  • 1965-1969
Year
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 2 (1971), S. 345-355 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Sintering processes in carbide-cobalt-alloys containing 0,2 to 15% Co. The sintering processes in alloys consisting of 0,2, 0,5, 3, 6 and 15% cobalt, the remainder being either WC, TiC, WC/TiC or WC/TiC/TaC, were observed after annealing at 400°C to 1500°C by measuring the bending strength at rupture, the magnetic saturation, the specific electrical resistance and the coercive force at room temperature. As early as the grinding stage the WC-Co-compounds can be clearly distinguished from all other blendings. Thin, not necessarily coherent layers of Co form on the tungsten carbides, a fact which is indicated by the higher coercive force and bending strength at rupture of the WC-Co-green compacts.The actual sintering processes can be divided in to four temperature ranges:(I)T ≤ 400°C(II)400°C 〈 T ≤ 800°C(III)800°C 〈 T 〈 liquid Phase(IV)T ≥ liquid PhaseThe sintering process within these ranges are disscussed in detail and should greatly contribute to an understanding of the structural composition of carbide metals.
    Notes: Die Sintervorgänge in Legierungen mit 0,2, 0,5, 3, 6 und 15% Kobalt, Rest jeweils WC, TiC, WC/TiC oder WC/TiC/TaC wurden nach Glühungen bei 400°C bis 1500°C durch Messung von Biegebruchfestigkeit, Sättigungsmagnetisierung, spezifischem elektrischem Widerstand und Koerzitivkraft verfolgt. Die Ermittlung der Meßwerte erfolgte bei Raumtemperatur. Bereits beim Mahlen unterscheiden sich die WC-Co-Mischungen von allen übrigen Ansätzen. Auf den Wolframkarbiden bilden sich dünne, nicht unbedingt zusammenhängende Co-Schichten aus, worauf die höheren Koerzitivkraft- und Biegebruchfestigkeitswerte der WC-Co-Grünlinge hinweisen.Die Sintervorgänge selbst lassen sich in vier Temperaturbereiche einteilen:(I)T ≤ 400°C(II)400°C 〈 T ≤ 800°C(III)800°C 〈 T 〈 flüssige Phase(IV)T ≥ flüssige PhaseDie in diesen Intervallen ablaufenden Sinterprozesse werden ausführlich besprochen und dürften wesentlich zum Verständnis des Gefügeaufbaues der Hartmetalle beitragen.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 83 (1971), S. 435-437 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 15 (1971), S. 2059-2061 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 54 (1971), S. 1599-1605 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The pyrrolidide group is, in contrast to the carboxy- and ester groups, capable of inducing strong electron impact fragmentation at the b̃- and γ-bonds in complicated alicyclic and aliphatic compounds. The fragments so formed allow certain conclusions concerning the structure in the neighbourhood of the functional group.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 381 (1971), S. 226-234 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The electrochemical reduction of dialkylthallium(III) cations in aqueus buffer solutions and dimethylformamide yields by the first electron transfer the instable intermediate {R2Tl}, which in dependence of the reaction conditions is electrochemical reduced to Tl° or disproportionates to R3Tl and Tl°. Phenyl-substituted organothallium compounds are reduced to Tl° and (C6H5)2Hg in one step.
    Notes: Die elektrochemische Reduktion von Dialkylthallium(III)-Kationen in wäßrigen Puffersystemen und Dimethylformamid führt im Primärschritt zu {R2Tl}, das in Abhängigkeit von den Reaktionsbedingungen entweder elektrochemisch zu Tl° reduziert werden kann oder zu R3Tl und Tl° disproportioniert. Phenyl-substituierte Organothalliumverbindungen werden in DMF in einer Stufe zu Tl° und Diphenylquecksilber reduziert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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