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  • Chemical Engineering  (41)
  • ASTROPHYSICS
  • SPACE VEHICLES
  • Wiley-Blackwell  (41)
  • 1970-1974  (41)
  • 1970  (41)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 293-299 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The laminar, isothermal entrance region flow of the Bingham fluid in a circular pipe is studied at first by using the momentum integral method and the boundary-layer equation for the Bingham fluid. In addition to the velocity boundary layer, the existence of the shear stress boundary layer is considered. The solution is valid only near the entry because of limitation of the boundary-layer model. The Campbell-Slattery method originally devised for the Newtonian fluid is also used to analyze the Bingham entrance region flow. The results are compared with those obtained through the use of the momentum integral method and those obtained through the use of the variational method by other investigators. While the results obtained in this work appear to be generally reasonable and valid, the results by the other investigators have been found to be somewhat erroneous.
    Additional Material: 12 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 293-299 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dynamic elastic moduli were measured on macroscopic models simulating two-phase microstructures where the second phase was present as a continuous, isotropic network. Using open-pore polymer foams with higher-moduli, infiltrating matrices, the composite moduli were found to be linear with volume fraction of the network phase. Variations of network cell size or surface area indicated that the moduli increased with increasing interfacial area, but only when interphase wetting was present and matrix contraction upon solidification occurred. Metallic foams with a lower moduli matrix produced moduli that were compatible with existing bounding theories for composites.
    Additional Material: 9 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 154-158 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In injection molding certain polymers, fracture of the polymer stream sometimes occurs at the mold surface. This phenomenon has been found to be a tearing apart of the polymer surface layer accompanied by downstream slip of the flowing melt at the polymer/mold interface. Fracture occurs early in mold filling and is initiated usually at the gate to the mold cavity. Analysis of the fracture mechanism indicates that fracture is caused by: (1) high shearing stress in the melt as it fills the mold; (2) poor polymer/mold adhesion; and (3) low polymer surface cohesive strength.
    Additional Material: 15 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 193-203 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The capillary flow instability resulting in extrudate distortion has been studied for ethylene polymer melts using a molecular structure approach. It is found that the instability initiates at a critical value of elastic strain energy independent of (average) molecular weight for linear polyethylene. Once the flow breaks down, a slip interface within the melt is formed near the capillary wall, causing an abrupt increase in volumetric throughput. The velocity gradient within the melt remains continuous through the instability, however. Low molecular weight species present in the molecular weight distribution of linear polyethylene tend to suppress slip. Blends of linear and branched polyethylene exhibit instability behavior characteristic of both components throughout the entire range of composition. Results are discussed in terms of specific molecular mechanisms.
    Additional Material: 14 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 340-344 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The cross-linked, ladderlike structure of cured pyrrones is not susceptible to forming at ordinary temperatures and pressures. At unusually high processing temperatures, of the order of 500°C, these intractable materials are observed to undergo transient flow sufficient to allow molding of the material. This observation, supported by analytical information, suggests that the flow occurs because of the breakage of covalent organic bonds and subsequent structural rearrangement of the cross-linked polymer network. This is in accord with a number of isolated reports of the pyrolytic behavior of several polymers.
    Additional Material: 10 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 24-31 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Flow at the entrance of a tube or channel is of interest in many polymer processes. Except for mathematical treatments at high Reynolds numbers and in creeping Newtonian flow, one must turn to empirical correlating equations and qualitative observations. These are discussed in two parts, one on pressure drop and the other on flow patterns. The discussion of pressure drop is largely a review, dealing with inertial, viscous, and elastic contributions to the pressure drop in tapered and sharp-edged entrances; also presented are new data for a viscoelastic polymer solution in tapered cone entrances. In the section on flow patterns, stress birefringent data for a very elastic solution flowing into a channel entrance show an unusual effect: stress discontinuities, not unlike “shock waves,” upstream and downstream of the entrances. This is in contrast to Newtonian and less elastic materials in which the stress patterns change gradually between the developed flow region and the entrance region.
    Additional Material: 9 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 832-837 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ternary diffusion coefficients at 25°C. of the system 0.5 g./cc. d-tartaric acid - 0.5 g./cc. l-tartaric acid-water are reported. The results allow experimental verification of the theory for the diffusion of two indistinguishable solutes and clearly illustrate the difference between mutual and tracer diffusion. Moreover, the results allow calculation of ternary mass transfer coefficients and ternary tray efficiencies for the case of two similar species dissolved in a third.
    Additional Material: 1 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1010-1015 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Laminar flow in helically coiled tubes is treated numerically. Fully developed axial and secondary velocities are calculated for both circular and elliptical cross sections. Only closely wrapped helices, that is, helices with modest pitch, are considered. Ten solutions with Deans numbers up to 200 have good accuracy. Two additional solutions with Deans numbers up to 280 are approximate.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 369-374 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The classical emulsion is made up of drops of one liquid dispersed in a containing liquid. Under certain circumstances, however, some of the containing phase may form drops within the drops of the dispersed liquid, giving rise to a structure known as a double-multiple emulsion. This study was an investigation of the hydrodynamic formation of these structures.Double-multiple emulsions were produced by using both transient and steady state liquid injection, with a cylindrical jet configuration. Analysis of the spray was by means of high-speed photography.The distribution of the large drops and that of the included drops were both found to be represented satisfactorily by a log-normal probability function. A simplified model based on the use of nozzle parameters satisfactorily correlated percent included area and volume as a function of Reynolds number and Weber number. Large dispersed phase drops contained proportionally many more inclusions than did the smaller sizes.The mechanism of inclusion formation was found to involve the drawing out of a ligament or sheet from the flowing jet, followed by the recoalescence of the free end of this ligament or sheet with the main jet body, entraining in the process a portion of the containing phase. Thus, the inclusions predate the formation of the drops of the dispersed phase from the jet disruption.
    Additional Material: 13 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 464-471 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer coefficients were measured for glass particles at the same wall surface of a fluidized bed for which glass particle residence times were measured in a previous study. The data compared well with theoretical predictions of the dependence of heat transfer coefficients on particle residence times. Heat transfer coefficients for metal particle systems, for which direct measurements of residence times were not available, were predicted with fair accuracy by estimating residence times from a dimensionless correlation proposed in a previous study. The ability of the particle surface renewal models to accurately predict heat transfer coefficients is strong evidence of their physical validity.
    Additional Material: 5 Ill.
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