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  • Chemical Engineering
  • EARTH RESOURCES AND REMOTE SENSING
  • METEOROLOGY AND CLIMATOLOGY
  • 1980-1984
  • 1970-1974  (40)
  • 1970  (40)
Collection
Publisher
Years
  • 1980-1984
  • 1970-1974  (40)
Year
  • 11
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 718-724 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A procedure based on kinetic principles is presented for the development of models for the adsorption of mixtures of gases in any number of layers by solid adsorbents. Equations of state for two-dimensional gas mixtures which are thermodynamically consistent with the adsorption models are also presented. The constants in the adsorption models for mixtures are obtained from the isotherms for the pure components. Good accuracy for the predicted adsorption of mixtures for the data available was obtained by use of a model for the adsorption of mixtures in bimolecular layers.
    Additional Material: 3 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 967-972 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The laminar flow of dilute aqueous polymer solutions was studied in the entrance region of a cylindrical tube. In laminar, fully developed, steady tube flow, elastic and inelastic fluids were indistinguishable. Viscoelastic fluids exhibited much higher entrance pressure losses than did inelastic fluids with comparable viscous properties. A method has been developed for separating the elastic portion of the overall entrance loss and shows that in some cases the elastic contribution represents as much as 80% of the total. An analysis is also presented which allows calculation of the elastic entrance loss in terms of a Hookean shear modulus.
    Additional Material: 7 Ill.
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  • 13
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 991-998 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new modification of the Redlich-Kwong equation of state is presented. The modification follows the procedure suggested by Redlich, Ackerman, et al., in which a deviation function (a function of temperature, pressure, and acentric factor) is added to the compressibility factor from the original equation to improve the agreement with data. The purpose of the present modification was to improve predictions of the Redlich-Kwong equation in the saturated vapor region up to the critical point while retaining a relatively simple form to make analytical relations for derived properties possible. The equation for pressure correction to vapor enthalpy, derived from the compressibility factor by standard thermodynamic procedures, is also presented. Comparisons of predicted vapor compressibility factors and vapor enthalpy pressure corrections with literature data are given, demonstrating the advantages of the proposed modification when the saturated vapor region is of principal interest.
    Additional Material: 3 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 53-57 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An explicit, four-constant model for viscosity and normal stresses in simple shear has been developed by simplifying the integral theory of Bernstein, Kearsley, and Zapas. In essence the procedure involves curve-fitting the linear relaxation spectrum. The four constants appear also in equations for the stress distribution and for pressure drop in accelerative flow between flat plates; flow along rays is assumed. The equations reduce to second-order theory and to Newtonian theory as a Deborah number becomes small. Comparison of the predicted stress distributions with previously published stress birefringent data shows good agreement; because of the low shear rates, however, the check is not demonstrating very strong departures from the second-order asymptote. Certain other theoretical results, including pressure drop predictions, are also noted.
    Additional Material: 5 Ill.
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  • 15
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Acoustic velocity data for various isotherms from 1 to 70 atm. are presented for argon (32°F.), nitrogen (32°F.), methane (32°, 70°F.) tetrafluoromethane (32°, 70° F), dichlorodifluoromethane (240°F., p 〈 30 atm.), and various mixtures (32°F.). Interaction potential force constants for the pure gases are derived from the acoustic data with values for tetrafluoromethane and dichlorodifluoromethane differing significantly from previous literature values. BWR constants are also reported for argon and tetrafluoromethane.
    Additional Material: 7 Ill.
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  • 16
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method was developed for estimating the age density of transporting elements at a transport surface by using the spectral density of the total element counts. Only total counts, and not individual element histories, need be observed. The method was compared with autocorrelation methods used in an earlier work. Residence times were measured for several sizes of particles at a paticular wall surface of a stirred fluidized bed and at various gas velocities using both spectral density and autocorrelation methods. A dimensionless plot brought all data points near a single curve, valid only for this surface in this bed. Checks of these residence times against values obtained by direct observation of individual particles confirmed the methods.
    Additional Material: 7 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 841-848 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The model of the fluctuating viscous sublayer proposed by Einstein and Li was modified by treating some of the objections to the original formulation without greatly altering the essential simplicity of the concept. The applicability of this model to the description of the important features of turbulent flow and heat transfer in ducts and of the Toms phenomenon was evaluated by comparison of predictions of the model with experimental measurements. The mean period for growth and decay of the sublayer and the magnitudes of the wall-pressure fluctuations and wall-temperature fluctuations were compared for the flow of air and liquids. Quantitative spatial features of the periodic sublayer, that is, minimum and maximum sublayer thickness and patch size in the directions normal and parallel to the flow direction, were determined.
    Additional Material: 9 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 867-875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Results of calorimetric determinations are reported for a mixture containing approximately 51 mole % propane in methane. Measurements were made with both isobaric and throttling flow calorimeters in the liquid, critical, gaseous, and two-phase regions in the temperature range from -250° to +300°F. at pressures of between 100 and 2,000 lb./sq. in. abs. Tables of experimental values of heat capacity, Joule-Thomson coefficient, and isothermal throttling coefficient are presented, and the values of Cp and φ are summarized on parametric plots.Experimental values of enthalpy differences within the two-phase region determined under both isobaric and isothermal conditions are also reported together with the experimentally determined phase boundary data. A skeleton enthalpy table is presented which is based almost entirely on experimental data obtained in this investigation. Comparisons are made with other published calorimetric data and with calculations based on PVT data.
    Additional Material: 11 Ill.
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  • 19
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 749-754 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model of a through-circulation packed bed dryer is presented in this paper. The semitheoretical model treats the case of constant rate drying in a deep bed of granular solids under initially uniform drying conditions. Experimental data for drying in superheated steam, mixtures of superheated steam and air, and air alone showed good agreement with predictions of the model.Based on the model, a static optimization method is developed for optimal operation of a continuous through-circulation dryer subject to the inequality constraints of maximum permissible air-horsepower per unit bed area and maximum permissible local final moisture content in the bed. A nonlinear capacity function is defined in terms of the independent drying variables and is maximized under the above nonlinear restraints.
    Additional Material: 5 Ill.
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  • 20
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1100-1102 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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