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  • Analytical Chemistry and Spectroscopy  (256)
  • Chemical Engineering  (196)
  • 1980-1984  (169)
  • 1970-1974  (283)
  • 1950-1954
  • 1982  (169)
  • 1974  (124)
  • 1972  (78)
  • 1970  (81)
Collection
Keywords
Publisher
Years
  • 1980-1984  (169)
  • 1970-1974  (283)
  • 1950-1954
Year
  • 1
    Electronic Resource
    Electronic Resource
    Optimization of binary solvents in thin layer chromatographyThis work was reported in part at the 16th Symposium on Advances in Chromatography, Barcelona, Spain The work was supported by a grant from Research Corporation. (1982)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 5 (1982), S. 373-376 
    Details
    ISSN: 0935-6304
    Keywords: Thin-layer chromatography, TLC ; Binary solvent mixtures ; New solvent polarity ranking ; Optimization ; Window diagram ; Cluster center ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ΔRf, the separation between a pair of compounds on a thin layer chromatographic plate, can be predicted as a function of solvent composition for certain binary systems. This allows the prediction of optimum solvent composition for separating a mixture of compounds by thin layer chromatography. A new solvent polarity ranking, based on calculation of ΔRf is described.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240050708
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  • 2
    Electronic Resource
    Electronic Resource
    Simple fabrication of a “Grob” injector (1982)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 5 (1982), S. 52-53 
    Details
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Instrumentation in gas chromatography ; Capillary Injector ; Injector ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240050111
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  • 3
    Electronic Resource
    Electronic Resource
    Stability of time-delay systems (1972)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 380-384 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A direct method is presented for determining both local and regional stability of systems described by nonlinear differential-difference equations. Prediction of stability is with respect to a general class of initial curves. The practical as well as the conservative nature of the procedure is demonstrated by a numerical example.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690180221
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  • 4
    Electronic Resource
    Electronic Resource
    Turbulent drag reduction in fiber-polymer systems: Specificity considerations (1974)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 1218-1219 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690200626
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  • 5
    Electronic Resource
    Electronic Resource
    Explicit approximations to the solution of Colebrook's friction factor equation (1982)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 514-515 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690280323
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  • 6
    Electronic Resource
    Electronic Resource
    Numerical solution of liquid-phase multicomponent adsorption in fixed beds (1982)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 765-772 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized mathematical model is developed to describe the process of multicomponent adsorption on activated carbon in fixed beds. Numerical, finite difference, solutions for the adsorption of binary, and ternary organic mixtures are shown to satisfactorily match previously published experimental data.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690280510
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  • 7
    Electronic Resource
    Electronic Resource
    Kinetics of coal drying-decomposition (1982)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 199-207 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A series of seven coals of different ranks and from various locations were heated in an inert atmosphere under relatively mild conditions to measure the rates of gas evaporation. Samples crushed to various fractions in the particle size range -6+50 U.S. mesh were studied at temperatures in the range of 150 to 300°C. The results show that: (1) most water is released at 100°C, evidently an evaporation process, (2) CO2 is evolved at 150°C and above, and (3) CO is evolved at 250°C and above. An interpretive model was developed to fit the CO2 production rate and kinetic constants were obtained. Gas evolution rates are independent of particle size for the most porous coals, but vary among coals, depending on both chemical composition and physical structure. A 15% loss in heating value was incurred during drying and subsequent oxidation when the pretreatment temperature was increased from 150 to 225°C.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690280206
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  • 8
    Electronic Resource
    Electronic Resource
    Nucleation kinetics of the potassium sulfate-water system (1972)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 798-807 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Secondary nucleation in the potassium sulfate-water system occurs by micro-attrition processes over the entire 1.3-26 μ size range of this study. Experimental nucleation rates were correlated with power-law kinetics expressions in terms of supersaturation, the fourth moment of the parent seed-crystal distribution, and stirring rate. Such kinetics expressions are similar to those used to correlate MSMPR data; however, the secondary nucleation rates of this paper are two orders of magnitude greater than those reported in previous MSMPR studies of the same system. An upper bound on growth rate of these nuclei was calculated based on a population balance analysis; maximum growth rates of these nuclei was markedly size-dependent in the 1.3-26 micron size range of measurement, decreasing with decreasing size. The apparent descrepancy between these nucleation rates and MSMPR values can be explained by nuclei washout during the low growth rate period. Anomalous MSMPR kinetics (low or even negative supersaturation power-law dependence) can be explained by this growth phenomenon.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690180423
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  • 9
    Electronic Resource
    Electronic Resource
    Effect of phase-volume ratio and phase-inversion on viscosity of microemulsions and liquid crystals (1974)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 510-514 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microemulsions, which are optically transparent oil-water dispersions, were spontaneously produced upon mixing hexadecane, hexanol, potassium oleate, and water in specific proportions. The viscosity of the microemulsions was measured for several water/oil ratios including the phase-inversion region. The striking optical and viscosity changes observed at specific water/oil ratios were in agreement with the proposed mechanism of phase-inversion, namely, water spheres → water cylinders → water lammellae → continuous water phase, for this system. In the phase-inversion region, the dispersion exhibited birefringence and rheopectic properties. An extremely high viscosity (〉 100,000 cps) exhibited by the dispersions between water/oil ratios of 2.0 and 3.5 were explained in terms of ion-dipole association between oleate and hexanol molecules on adjacent droplets.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690200311
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  • 10
    Electronic Resource
    Electronic Resource
    Thermodynamic properties of the system N2O4⇌2NO2⇌2NO + O2 (1970)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 420-425 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Thermodynamic properties of the chemically reactive system N2O4 ⇌ 2NO2 ⇌ 2NO + O2 have been evaluated over a pressure range of 0.005 to 200.0 atm. and a temperature range of 200° to 900°K. by making use of Lennard-Jones potential. In these calculations, the dissociation of nitrogen tetroxide to nitrogen dioxide, nitric oxide and oxygen, and the effect of pressure on the equilibrium constants for the system of reactions N2O4 ⇌ 2NO2 and 2NO2 ⇌ 2NO + O2 have been taken into account.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690160319
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