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  • Physics  (2)
  • Wiley-Blackwell  (2)
  • 1965-1969  (2)
  • 1969  (2)
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  • Wiley-Blackwell  (2)
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  • 1965-1969  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 7 (1969), S. 583-595 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3-Methacrylyloxymethyl-5,7,8-trimethylchroman-6-01 (MMC) was prepared, polymerized, and copolymerized. Poly-MMC, a reduced redox polymer, is stable to air and is oxidized readily. The redox behaviors of poly-MMC and copolymers with vinyl acetate were compared with that of 3-propionyloxymethyl-5,7,8-trimethylchroman-6-o1 (PMC), the model monomer. The titration curves of the polymers were flat as is usual with redox polymers, and showed higher midpoint potentials than the model monomer. One factor in this “polymer effect” was found to be adsorption of oxidized polymer on the electrode. But there seem still to be present other factors yet to be clarified.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 7 (1969), S. 1269-1274 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Redox polyurethanes, polyesters, and alternate copolyurethanes and copolycarbonates from two kinds of benzoquinonyl glycol were prepared based on 2-(duroquinonyl)-propan-1,3-diol. The oxidized polymer is stable. When the fully reduced polymer in solution is exposed to air the durohydroquinonyl residues are oxidized to the quinone form while the less substituted hydroquinonyl glycol residues remain stable in the reduced form. There is thus prepared polymer with oxidized and reduced groups alternating along the chain.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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