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  • 1965-1969  (22)
  • 1960-1964
  • 1968  (22)
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 7 (1968), S. 1655-1656 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 33 (1968), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: SUMMARY– The distribution of volatile solutes between two immiscible solvents can be determined by a study of the vapor pressures in the corresponding single solvent systems, since the partition coefficient is related to the Henry's constants: Kp= k2k12. Application of this principle makes possible the gas chromatographic determination of partition coefficients involving nonvolatile solvents. The method was applied to a solvent pair consisting of paraffin oil and aqueous sodium sulfate. An approximate semilogarithmic relationship exists between the partition coefficient and number of carbon atoms within each homologous series of aldehydes, ketones, alcohols and esters. Saturation with sodium sulfate increased the partial pressure of volatiles from 12 to 20 times. The partial heat of vaporization of volatiles in paraffin oil decreased with increasing temperature and was appreciably smaller than that of the pure compound at its boiling point. These observations may be utilized in quantifying food volatiles in operations involving extraction and gas stripping prior to analysis.
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 33 (1968), S. 2986-2988 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 90 (1968), S. 6256-6256 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 24 (1968), S. 680-683 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: An X-ray powder diffraction and single-crystal study of the structures and phase transformations existing in the 50 at.% region of the gold-cadmium system has been carried out. The transformation β1 (cubic) →β′ (orthorhombic) occurring in the range 47–48.5 at.% Cd is confirmed. At higher cadmium content, 49–52 at.%, the cubic β1 phase transforms to a structure possessing hexagonal symmetry rather than the previously suggested tetragonal structure. The X-ray diffraction patterns of this hexagonal structure can be interpreted in terms of a unit cell of 27 atoms, which is structurally similar to the ξ phase of the AgZn system.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 24 (1968), S. 1018-1018 
    ISSN: 1420-9071
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Zusammenfassung Die Endothelschicht von doppelt unterbundenen Abschnitten der A. carotis des Kaninchens wird 3 Tage nach der Unterbindung und Injektion von Intralipid (künstliche Fett-Emulsion) in das Lumen elektronenmikroskopisch untersucht. Die künstliche Hyperlipämie zusammen mit Hypoxie erzeugte eine starke Aufnahme von Fett in Form von intrazellulären Tröpfchen, die viel elektronendichter waren als die ursprünglichen Intralipid-Partikel. Ein morphologischer Hinweis auf den Mechanismus der Fettaufnahme wurde nicht gefunden.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1432-119X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Nucleoside phosphatase activity was localized in rabbit intracranial blood vessels, namely cerebral and basilar arteries and veins, and in the thoracic aorta using the electron microscope. In the intracranial vessels the same ultrastructural localization of reaction product was found when ATP or ADP was used as substrate in a modified Wachstein-Meisel procedure using Mg ions as the enzyme activator. No reaction product was seen when using AMP or β-glycero-phosphate as substrates, or in controls without any substrate. Reaction product was sparsely localized within cell membrane invaginations on all sides of endothelial and, to a lesser extent, of smooth muscle cells. Pinocytotic vesicles occasionally contained reaction product. The greatest amount of lead phosphate (reaction product) precipitate was found in the basement membranes of both endothelial and smooth muscle cells, particularly intense in the former case. A diffuse precipitate of reaction product was observed in the cytoplasm of adventitial fibroblasts. The thoracic aorta demonstrated the same localization with the following exceptions: generally greater concentrations of reaction product were found using ATP as substrate, than in the corresponding intracranial vessels; interendothelial gaps and the cell membrane invaginations of these gaps were completely filled with reaction product; there was no specific localization of reaction product in the basement membranes; and reaction product could also be demonstrated using AMP and glycero-phosphate as substrates. Acid phosphatase activity was localized in lysosomes in endothelial and smooth muscle cells from both types of vessels. The differences in enzyme localization between aorta and intracranial vessels were discussed, particularly in light of the differences in nucleoside phosphatase activity and transport functions between brain and somatic capillaries.
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  • 8
    ISSN: 1432-119X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary A study of the mechanisms involved in silver staining of blood vessels has been performed on the rabbit and rat aorta and vena cava, both in fixed and unfixed states. Pretreatment with cationic detergents, organic solvents, and solutions containing free iodide ions inhibited the silver staining. Anionic or neutral detergents, oxidizing agents, binders of such ions as Ca++, Mg++ and SO 4 - failed to inhibit the staining. Staining of the intercellular gaps between endothelial cells and between smooth muscle cells could also be obtained if vessels were treated with a cationic detergent and bromocresol green, or by a modified Hale's colloidal iron technique. Silver lines could be returned to dechlorinated vessels, if treated with sodium chloride before silver nitrate staining, but not vice versa; by an extended treatment with dilute silver nitrate or with gold chloride following normal silver nitrate staining; and by treatment with heparin prior to silver staining. Dark chamber experiments have demonstrated that a photographic developer can take the place of light in the silver staining procedure and that a photographic fixer has the same effect on vessel silver staining as dechlorination. The obtained results have led to the hypothesis that silver staining of vessels occurs in two stages. In the first silver ions from silver nitrate are bound by polyanions located primarily in the intercellular gaps, and then reduced. This produces a network of reduced silver grains which, however, are still too sparsely aggregated to be visualized. Chloride ions in the tissues also bind and precipitate silver ions preventing their removal in subsequent rinsing procedures. In the second stage light (or a photographic developer) reduces the silver ions in silver chloride, producing a visible accumulation of metallic silver, but only around the silver grains reduced during the first stage, analogous to the photographic process. The possible existence and function of an intercellular cement substance is discussed in light of the evidence for the presence of polyanionic groups in the intercellular gaps.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Medical & biological engineering & computing 6 (1968), S. 387-397 
    ISSN: 1741-0444
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Description / Table of Contents: Sommaire Le but de cet article est d'appliquer une loi physique, telle que les équations de Kirchhoff, à certains aspects de la physiologie rénale et cardiovasculaire. On peut en déduire facilement et systématiquement: les relations bien connues de filtrage, de sécrétion, de réabsorption, ainsi que les expressions mathématiques des débits, qui sont toutes des exemples de la méthode de dilution; en particulier, la circulation du plasma dans le rein, la formule de Fick pour le débit cardiaque et la formule de Kety pour la circulation sanguine du cerveau. La méthode de dérivation exige de réduire le système physiologique à étudier à un diagramme composé de diverses branches et de leurs points d'intersection, qui sont appelés des noeuds. Une fois le ou les noeuds choisis, l'équation de Kirchhoff peut être appliquée à chacun d'entre eux et être résolue pour les variables en question. La méthode, appliquée aux sujets mentionnés ci-dessus, apporte: 1. Une principe de base commun pour tous; 2. Une amélioration de la compréhension générale des sujets; 3. Un ontil qui peut éventuellement aider de nouvelles expériences.
    Abstract: Zusammenfassung Der Zweck dieser Arbeit liegt in der Anwendung eines physikalischen Gesetzes, das in der Knotengleichung gegeben ist, auf gewisse Aspekte der Nieren- und Herzkreislaufphysiologie. Die bekannten Beziehungen für Filtration, Sekretion und Reabsorption, und die mathematischen Ausdrücke für Flußgrößen—alle sind Beispiele der Verdünnungsmethode—wie der renale Plasmafluß, die Ficksche Formel für die Herzleistung und die Ketysche Formel für den zerebralen Blutdurchfluß werden leicht und systematisch abgeleitet. Die Methode der Ableitung erfordert eine Reduzierung des untersuchten physiologischen Systems auf ein Flußdiagramm, welches aus Verzweigungen besteht. Die Punkte, an denen diese zusammentreffen, werden als Knoten bezeichnet. Wenn der oder die geeigneten Knoten gewählt sind, kann die Knotengleichung auf jeden Knoten angewandt werden und für die gesuchten Variablen gelöst werden. Die Behandlung der obengenannten Punkte liefert (1) ein Grundprinzip als gemeinsame Basis; (2) ein besseres Verständnis des Fachgebietes und (3) eine Möglichkeit zur Planung neuer Experimente.
    Notes: Abstract The purpose of this paper is to apply a physical law, described by the node equation, to certain aspects of renal and cardiovascular physiology. The well-known relations for filtration, secretion, and reabsorption, and mathematical expressions for flows, all of them examples of the dilution method, such as renal plasma flow, Fick's formula for cardiac output, and Kety's formula for cerebral blood flow, are easily and systematically derived. The method of derivation requires the reduction of the physiological system under study to a flow diagram composed of branches and the points where they meet, which are called nodes. Once the appropriate node or nodes are chosen, the node equation can be applied to each of them and can be solved for the variable under study. This treatment of the above-mentioned topics provides: 1. a basic principle which represents a common stem for all of them; 2. an improvement to the general understanding of the subjects; 3. a tool which eventually may help in the design of new experiments.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 101 (1968), S. 1215-1222 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Hydrolyse von NSF gibt als erstes Reaktionsprodukt wahrscheinlich HNSO, als dessen Folgeprodukte S(OH)2 und H2NOH nachgewiesen und Trithionat sowie Hexathionat-Ionen als schwerlösliche Tetraphenylphosphoniumsalze gefällt werden. Der mögliche Hydrolysemechanismus ist schematisch aufgeführt. Aus der schwach ammoniakalischen Hydrolyselösung von S4N4 lassen sich ebenfalls Tri- und Hexathionat-Ionen als Phosphoniumsalze fällen, in Gegenwart von S2O32--Ionen jedoch nur Hexathionat-Ionen. Aus der neutralen Hydrolyselösung von S4N4 erhält man nur auf Zusatz von F--oder Cl--Ionen eine Fällung von Tetraphenylphosphoniumtrithionat und -hexathionat, was durch eine intermediäre Bildung von NSF bzw. NSCl erklärt wird. Bei der Reaktion von Na2S2O3-Lösung mit verdünnter Salzsäure konnten neben S und SO2 Hexathionat-Ionen als Tetraphenylphosphoniumhexathionat isoliert werden.
    Additional Material: 3 Tab.
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