ISSN:
0570-0833
Keywords:
Carbonylation
;
Alkenes
;
Palladium
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
During a search for catalysts that allow carbonylation reactions on olefins to proceed below 100 °C, complex palladium(II) compounds having the formula LmPdXn were found to be catalytically active. L denotes a ligand such as a phosphine, nitrile, amine, or olefin, X is an acid residue, and m+n is 3 or 4. The catalysts permit the carbonylation of heat-sensitive compounds, as well as selective carbonylation of polyunsaturated olefins. The new process can also be carried out on the industrial scale, as is shown by the carbonylation of cyclododecatriene
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196803291
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