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  • Chemical Engineering  (8)
  • Wiley-Blackwell  (8)
  • American Institute of Physics
  • 1965-1969  (8)
  • 1955-1959
  • 1940-1944
  • 1965  (8)
Collection
Publisher
  • Wiley-Blackwell  (8)
  • American Institute of Physics
Years
  • 1965-1969  (8)
  • 1955-1959
  • 1940-1944
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 526-532 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method has been developed for the calculation of the viscosity of nonpolar gas mixtures at moderate and elevated pressures from the molecular weights and critical constants of the components. By the use of available experimental data and appropriate pseudocritical constant rules, results obtained previously for the viscosity of pure gases have been extended to mixtures. Viscosity values calculated by the method developed in this study for a number of nonpolar gas mixtures were found to reproduce reported values with a high degree of accuracy.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 370-374 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 474-480 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A technique has been developed for finding quantitative regions of asymptotic stability for nonlinear systems by using a known proof of the theorem which substantiates the linearization. In a sense, the method defines a region in which the first-order approximation is dominant from the point of view of stability. While the computations necessary can be somewhat involved, the procedure is essentially identical in all situations, and once established, can easily be used for a vast class of autonomous systems. The practical problems of both reversible and irreversible chemical reactions occuring in a continuous flow stirred vessel have been analyzed. Stability regions were obtained which are sufficiently extensive to be practical from the process viewpoint.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 965-971 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A previous study (3) revealed a discrepancy between the actual shape of a spheroidal filter cake formed on a laterally unconfined circular test leaf, and that predicted from theory. This discrepancy was tentatively attributed to either cake compressibility or filter cloth resistance that was neglected in the mathematical model and not controlled in the original experiments. More extensive and systematic experiments reported in the present paper, employing incompressible cakes and filter media of negligible resistance, display similar behavior. (Cake incompressibility and negligible septum resistance were quantitatively established by conventional one-dimensional experiments.) It is speculated that the observed departure from theory may be due to the inapplicability of Darcy's law, especially in the early stages of cake formation.
    Additional Material: 10 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 158-163 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The present work is concerned with an experimental study of the influence of mass transfer on the holdup of countercurrent liquid-liquid fluidized systems and the effect of solute on droplet coalescence. Of particular importance in the results obtained is the dramatic demonstration that mass transfer greatly influences the holdup when solute is being extracted from the discontinuous phase loading to strong coalescence.
    Additional Material: 5 Ill.
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  • 6
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Peak nucleate boiling fluxes for liquid oxygen near 1 atm, have been measured on a 0.75-in.-diameter flat polished horizontal platinum surface located in a known, variable magnetic-field gradient that produced steady acceleration (which could be maintained indefinitely) on the oxygen acting in opposition to the earth's gravitation, gE. Measurements were made under condition ranging from net negative (directed away from the heated surface) accelerations of -0.03gE acting on the bulk liquid to the normal accelerations, 1.0gE. The results indicate that at zero g conditions for the bulk liquid, the peak nucleate boiling flux is ∼0.55 of the value at 1.0gE. For bulk-liquid accelerations ranging from ∼0.25 to 1gE, the experimental results confirm the ¼ power dependence of peak flux on acceleration as predicted by various correlations. However, below 0.25gE the peak flux becomes insensitive to the acceleration, varying approximately in proportion to the 1/14 power of the net acceleration. At bulk-liquid conditions of zero g (±0.005gE) the peak plux breaks sharply and falls by a factor of 10 between zero g and -0.03gE (for this apparatus).
    Additional Material: 8 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 891-897 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Integral conversion catalytic data have been studied by nonlinear estimation to determine whether the Langmuir-Hinshelwood heterogeneous catalytic models are more valid than the simpler homogeneous noncatalytic forms, and whether it is possible to discriminate among models. The experimental system chosen for this study was the vapor phase dehydration of ethanol. Data for a similar hypothetical catalytic system were also generated and analyzed to highlight the effects arising in the ethanol dehydration case.Nonlinear estimation is shown to be a valuable adjunct in the study of reaction kinetics and mechanism. For the hypothetical system, the correct model was found to provide the best fit to the data. Linear regression, coupled with the usual criterion that models are acceptable if all parameter estimates are positive, did not provide this discrimination. For the experimental system of ethanol dehydration, as corroborated by the hypothetical system, such problems as degeneracy of the heterogeneous rate equations and comparatively large errors in measurement are shown to be obscuring factors in determining the best model. When these effects are involved, it is doubtful that the Langmuir-Hinshelwood equations are more warranted than the simpler homogeneous forms.
    Additional Material: 5 Tab.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 5 (1965), S. 49-58 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The interlaminar shear strength of reinforced plastic composites has long been recognized as a critical property in the structural performance of composites. However, its role in structural performance and the many factors that influence it have not been clearly elucidated. Although much attention has been given to the importance of resin-glass adhesion, little is known regarding the contribution of resin strength and composite quality. In this article it is shown that interlaminar shear strength is a direct function of both resin strength and composite void content. The curves of resin tensile strength vs interlaminar shear strength indicate a limiting value for interlaminar shear above which increases in resin tensile strength do not increase defects.
    Additional Material: 21 Ill.
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