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  • Chemical Engineering  (117)
  • ASTROPHYSICS
  • STRUCTURAL MECHANICS
  • Wiley-Blackwell  (117)
  • 1980-1984  (76)
  • 1970-1974
  • 1960-1964  (41)
  • 1983  (76)
  • 1963  (41)
Collection
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  • Wiley-Blackwell  (117)
Years
  • 1980-1984  (76)
  • 1970-1974
  • 1960-1964  (41)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 289-297 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Catalyst deactivation in an isothermal fixed-bed reactor under pore-mouth poisoning conditions is investigated theoretically using a discrete mixing cell model. Two fundamental relationships which characterize the poisoning process in the reactor are identified and incorporated into the model to develop a simple graphical procedure for a quick, general insight into the problem. This graphical method is extended to design pellet impregnation profiles along the reactor which would give nondeteriorating reactor performance up to a given time. The effects of various system parameters on the lifetime and conversion performance of the reactor are also examined analytically, graphically and numerically.
    Additional Material: 12 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 876-878 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 338-342 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 196-202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When two liquid phases are contacted in a stirred tank reactor, dispersed phase mixing can affect average reaction rate and product selectivity in nonfirst order or mass transfer controlled reactions, as shown theoretically in Part I. This work is concerned with experimental measurement of the dispersed phase mixing rate. Various organic phase dispersions in water were studied in stirred tanks with a dye transfer light transmission technique. Batch experiments were performed in 0.30, 5.5, and 86-gal. vessels. The variables studied were power input per unit volume, phase fraction, impeller type, and vessel scale. Dispersed phase mixing rates were found to be in the range where they can have significant effects on chemical reactions. A typical value of the mixing rate is 10 volumes of dispersed phase/min. at a power input of 10 hp./1,000 gal. The information given here and in Part I shows for the first time the importance of these effects in reactor design.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 303-306 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Existing theories on the effect of mass transport on the rate (uniformity) of chemical reaction within a porous solid assume that the reaction is of integer order. However the carbon-carbon-dioxide reaction has the kinetic rate form, rate = k1pCO2/(1 + k2pCO + k3pCO2). For conditions where the retarding effect of carbon monoxide is very pronounced, the buildup of small concentrations of carbon monoxide within the porous graphite can lead to appreciable nonuniformity of gasification. Thus the criteria normally used to predict uniformity of gasification break down. A numerical integration of the combined differential equation of mass transport and chemical reaction has been performed, with rate constants for the carbon-carbon dioxide reaction taken from the literature. The results indicate that extreme nonuniformity of reaction can exist even when the change in carbon dioxide concentration from the exterior of the sample to the interior is small. The results are similar to experimental determinations of non-uniformity of gasification, obtained by determining the porosity of reacted graphite samples as a function of depth from the reacting face. Experimentally nonuniformity of reaction was observed for gasification rates a hundredfold lower than the usual Thiele criteria would predict, probably because of carbon monoxide inhibition.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 681-688 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 4 (1983), S. 64-72 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In the study of complex short-fiber-reinforced plastics behavior, it is helpful to begin with a well-aligned short-fiber system. This study isolates the effects of fiber-aspect ratio and orientation distributions on the tensile stress- strain behavior and failure mechanisms for a system containing 50 vol% E-glass fiber bundles in a ductileepoxy matrix. Using a system wherein the fiber orientation distribution was well-characterized, it is shown that the fibers reinforced as bundles rather than as individual fibers. As the bundle-aspect ratio varied from 185 to 557 for samples tasted in the longitudinal majoralignment direction, the modulus rose from 85 to 99 percent of the value for a continuous fiber system, while the strength rose only to about 60 percent of the continuous-fiber system. The ductility of the matrix had no effect on the modulus or the longitudinal strengths, but the off-axis strengths were significantly higher than has been reported for a comparable brittle-matrix system. The effects of fiber orientation on modulus and strength were successfully fit with the Leknitskii and Azzi-Tsai equations, respectively. SCanning electron micros-copy showed excellent adhesion and no fiber brekage, except at the highest bundle-aspect ratio. Even at off-axis angles below 15°, a mixed mode failure mechanism occurs because of the fiber orientation distribution.
    Additional Material: 16 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 4 (1983), S. 126-134 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: We have studied the phenomenon of acoustic cavitation under the action of volume ultrasonic oscillations on polymer melts and filled compositions. This phenomenon and the stress state of the material have been studied by means of a device for the visualization of flow in polarized light. It has been shown that the process of cavity formation in high-viscosity systems has a certain threshold and that the critical amplitude of oscillations depends on the duration of ultrasonics action. The effect of acoustic field on the melts of commercial polymers and filled compositions results in structural changes. In addition, a sharp increase of the melt flow is observed. Model experiments have shown that the size of particles and filler distribution can also be changed by utrasonic oscillation.
    Additional Material: 15 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 109-115 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Single drops supported on hypodermic tubing have been studied in a wind tunnel to determine the effect of drop oscillation on mass transfer. The systems studied for the case where internal resistance controls consisted of absorption of sulfur dioxide gas by drops of glycerine, propylene glycol, and ethylene glycol. The results may be expressed in terms of effective diffusivity.No significant effect was noted in glycerine, whereas the glycols gave effective diffusivity values two to eight times greater than theoretically calculated values of molecular diffusivities.Frequencies, amplitudes, and internal circulation velocities in the drops were studied by cinematography.The effect of oscillation on external mass transfer coefficients was studied by sublimation of naphthalene spheres in air. In the cases where the vibrational velocity was less than the stream velocity, no effect was noted; this is in agreement with heat transfer studies.A technique has been developed for studying the effect of internal circulation on effective diffusivity by the use of forced circulation through a drop suspended on hypodermic tubing. A pseudofilm thickness is determined as a function of circulation velocity and presents a means of predicting effective diffusivities for the systems studied. This technique has been demonstrated, giving results in fair agreement with the correlation of Garner and Lane.
    Additional Material: 12 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 154-160 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of the fluctuations in the mass transfer rate to small circular electrodes mounted flush with a pipe wall are used to study the unsteady nature of the viscous sublayer. These fluctuations in the mass transfer rate reflect flow fluctuations at y+ ca 0.5. From these measurements it is concluded that the flow disturbances are elongated in the direction of flow and are characterized by a time scale equal to the diameter of the pipe divided by the bulk average velocity. An attempt is made to relate the mass transfer fluctuations to the fluctuation in velocity gradient at the wall. It is concluded that the ratio of the root-mean-square fluctuating velocity gradient at the wall to the average velocity gradient at the wall is at least 0.11.
    Additional Material: 11 Ill.
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