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  • Chemistry  (521)
  • STRUCTURAL MECHANICS  (79)
  • BIOSCIENCES  (68)
  • ASTROPHYSICS
  • 1970-1974  (424)
  • 1960-1964  (244)
  • 1971  (424)
  • 1963  (244)
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  • 1970-1974  (424)
  • 1960-1964  (244)
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  • 1
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Removal of the pungent factor, allyl isothiocyanate, will partly determine whether mustard seed can become a commerical source for oil and meal in the United States. In processing studies at the Northern Laboratory, the mustard glucoside was converted enzymatically and the pungent oil was removed. This process has now been extended to pilot-plant scale by using filtration-extraction equipment at the Southern Laboratory. After desolventization and further steam stripping, the extracted meal had a residual content of 2.9% crude fat and 0.004% allyl isothiocyanate.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 10 (1971), S. 89-106 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Raman spectra of poly-γ-benzyl-L-glutamate, poly-L-leucine, poly-L-valine, and poly-L-serine are reported. For the α-helical polymers, the conformationally sensitive amide I, II, and III modes are observed in the Raman as, well as the infrared. For the β form, the Raman effect, supplies the infrared inactive inphase motion which is useful for the determination of a parallel or antiparallel chain alignment. Modes characteristic of the specific polypeptide are also observed which are insensitive to conformation.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 5 (1963), S. 83-85 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The inclusion of ethionine in Streptomyces rimosus fermentation resulted in the production of N-methylethyloxytetracycline. The compound has been isolated, crystallized, and a number of its chemical properties determined.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 379-383 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis is made of diffusion and chemical reaction in an isothermal multicomponent fluid. Transient gas-phase reaction in a one-dimensional nonflow system and steady state gas-phase or surface reaction in a tubular reactor are considered. The equations are linearized around some state away from equilibrium. Multicomponent and binary diffusivity expressions are used and a series of reactions of varying complexity is considered. The possibility of oscillations increases as the complexity of the reactions is increased. These oscillations occur with time in the nonflow system and with space-time in the tubular reactor, and it appears that any reacting mixture which oscillates in one of these two systems will also oscillate in the other.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 689-696 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Interaction of macromixing and micromixing in microbiological flow reactors based on a kinetic model of the Michaelis-Menten type has been treated by considering two general types of flow systems: the system of n continuous stirred-tank reactors in series (n-CSTR's in series) and the series combination of a plug-flow reactor and a continuous stirred-tank reactor. Systematic schemes to describe the micromixing conditions of a reactor system are presented. Additional micromixing states are considered besides those proposed by Kramers and those proposed by Zwietering if the systems are employed as empirical models of a flow system. When the number of stirred-reactor units in the system of n-CSTR's in series is small, micromixing has a significant effect on the growth processes. As the number of reactor units increases, the micromixing effect on the growth processes decreases. The effect of micromixing is also important for a system described by a series combination of a plug-flow reactor and a continuous stirred reactor. In addition, the exit concentrations from the system having the same residence time distribution and the same degree of segregation may be different from each other. Information obtained in this study is pertinent in the design of biological flow reactors and sewage treatment systems.
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 1264-1265 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 1516-1520 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 338-342 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 1394-1401 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The optimal startup policy of a jacketed tubular reactor, in which a first-order, reversible, exothermic reaction takes place, is presented. A distributed maximum principle is presented for determining weak necessary conditions for optimality of a diffusional distributed parameter system. A numerical technique is developed for practical implementation of the distributed maximum principle. This involves the sequential solution of the state and adjoint equations, in conjunction with a functional gradient technique for iteratively improving the control function.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 196-202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When two liquid phases are contacted in a stirred tank reactor, dispersed phase mixing can affect average reaction rate and product selectivity in nonfirst order or mass transfer controlled reactions, as shown theoretically in Part I. This work is concerned with experimental measurement of the dispersed phase mixing rate. Various organic phase dispersions in water were studied in stirred tanks with a dye transfer light transmission technique. Batch experiments were performed in 0.30, 5.5, and 86-gal. vessels. The variables studied were power input per unit volume, phase fraction, impeller type, and vessel scale. Dispersed phase mixing rates were found to be in the range where they can have significant effects on chemical reactions. A typical value of the mixing rate is 10 volumes of dispersed phase/min. at a power input of 10 hp./1,000 gal. The information given here and in Part I shows for the first time the importance of these effects in reactor design.
    Additional Material: 5 Ill.
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