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  • Chemical Engineering  (47)
  • 1960-1964  (47)
  • 1962  (47)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 542-549 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 14 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 708-710 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 103-108 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Results from an investigation of the fully developed turbulent wake of a circular cylinder are presented. The study was conducted in the liquid phase, in the controlled flow field of a water tunnel. A technique was developed for measuring the intensity of turbulence in water. The decay of turbulence intensity downstream from a series of fine-mesh wire screens was measured and compared with aerodynamic decay laws. Profiles of the turbulence intensity in the cylinder wake were also obtained. This paper is Part I of a study of liquid phase turbulent mass transfer in the wake of a cylinder. The mass transfer results are reported in Part II.
    Additional Material: 10 Ill.
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  • 4
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Turbulent mass-transfer coefficients were calculated from concentration profiles obtained in the wake of a hollow cylinder having a porous wall through which a solution of electrolyte was flowing. These coefficients are presented as functions of the turbulence intensity and the width of the transport region. This paper is a continuation of the previous report on this subject and utilizes the results presented earlier.
    Additional Material: 7 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 136-136 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 154-160 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple temperature dependent equation τ = K [Ṡ exp(ΔH
    Additional Material: 11 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 2 (1962), S. 294-297 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polymerization of the monomer was investigated in organic solvents such as nitro-compounds, amines, amides, nitriles, ethers, esters, ketones, aldehydes, acids, anhydrides, and some heterocyclic compounds. Crystalline polyvinylchloride was produced in aliphatic aldehyde media at temperatures ranging from 0° to 60°C and highly crystalline polyvinylchloride was synthesized in the presence of preliminarily oxidized butyric aldehyde. The electron diffraction picture of the non-oriented specimen of the polymer exhibited 19 distinct reflexes.
    Additional Material: 1 Tab.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 79-86 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study forms part of a project aimed at obtaining a better understanding of the behavior of nonideal permselective membranes. The object here was to determine the applicability of the Nernst-Planck equations for studying the behavior of ions in aqueous solutions surrounding such a membrane during electrodialysis.Attention was confined to stagnant and laminar flow systems. The processes studied were transfer of hydrogen ions, silver ions, and mixtures of the two through the cation exchanging membrane Nepton CR-61. The bulk solution concentrations on either side of the membrane varied from 0.01 to 0.20 N, and in all cases the only anions present were nitrate ions. Limiting currents for solutions of silver nitrate were predictable within 15%, with much of the uncertainty resulting from the difficulty in defining the limiting current. For mixtures of silver nitrate and nitric acid the limiting currents were predictable within the range of experimental accuracy but were found to be quite sensitive to small changes in the operating conditions. This sensitivity results from the very high relative mobility of the hydrogen ions. The relative transport of the two cations was primarily a function of relative concentration, relative diffusivities, current density, and ion exchange equilibria and was predictable with an accuracy limited only by the uncertainty of the ionic diffusivities and the ion exchange equilibria.The diffusivities of the cations in the membrane relative to the diffusivity of nitrate ion were estimated to be about ten times lower than in solution. This was explained by assuming that the cations tended to concentrate about the anionic fixed charges of the membrane thereby portially screening their effectiveness and reducing the mobility of the cations. In mixtures, the membrane diffusivity of the silver ions relative to the hydrogen ions was lower (by a factor of 1.4 to 3.6) than the relative diffusivity in solution. This indicated that silver ions were more easily concentrated about the fixed charges and thereby screened them from both the anions and hydrogen ions.
    Additional Material: 10 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 346-350 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diffusivities in slurries and in non-Newtonian solutions are predicted by means of an extension of the general Eyring rate theory. The fluid is considered as consisting of a number of discrete regions, each with its own contribution to the overall diffusion process. This model overcomes the unrealistic effects of fluid viscosity predicted by the conventional (empirical) equations. Whereas diffusivities predicted by means of prior art correlations were as much as 230 times lower than the experimental values in the systems, the maximum error in diffusivities predicted with the equations developed in this work was about 40%.Experimental data are provided on two kinds of fluids: slurries and a polymer solution. Both were highly non-Newtonian (flow behavior indexes as low at 0.15). Benzoic acid and β napthol were employed as the diffusing solutes. The principal limitation of the experimental data is that only aqueous systems were investigated.Much further experimental work will be required to provide a truly adequate test of the theory and to evaluate the several unknown parameters in sufficient detail to enable highly accurate predictions. Additionally the model used suggests a possible mechanism for increasing diffusion rates in these systems which is worthy of exploration. It may also be applied to an analysis and prediction of diffusion rates in viscous Newtonian fluids, for which no adequate method is presently available.
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 421-422 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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