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  • Articles  (181)
  • Chemistry  (181)
  • Industrial Chemistry  (3)
  • Analytical Chemistry and Spectroscopy
  • Atomic, Molecular and Optical Physics
  • Cartilage
  • Diphosphonates
  • Female
  • United States
  • 2005-2009
  • 1970-1974
  • 1965-1969
  • 1955-1959  (181)
  • 1959  (181)
  • Physics  (137)
  • Process Engineering, Biotechnology, Nutrition Technology  (44)
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  • Articles  (181)
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  • 2005-2009
  • 1970-1974
  • 1965-1969
  • 1955-1959  (181)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 36 (1959), S. 295-304 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Chitosan prepared from the pen in the mantle of the squid Loligo was fractionated by precipitation. Two fractions were investigated in aqueous solutions of sodium chloride. Fraction II showed anomalous behavior, which is attributed to molecular association, the extent of which increases with decreasing ionic strength. For fraction I, the intrinsic viscosity appears to increase even more rapidly with the radius of gyration than would be predicted by the free-draining model. The experimental change in the molecular dimensions as a function of ionic strength is much smaller than predicted by polyelectrolyte theories.
    Additional Material: 7 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 35 (1959), S. 113-118 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: By crosslinking natural rubber in benzene, networks are prepared in which the degree of coiling is higher than normal (“supercoiled” networks). On heating, these networsk are converted to normal ones with the same number of crosslinks but a lower degree of equilibrium swelling. The results of the swelling experiments are in quantitative agreement with theoretical predictions. Results of strees relaxation experiments at elevated temperatures support the conclusion reached on the basis of swelling. It follows that great caution is needed when calculating changes in the density of the crosslinks from changes in stress alone as is sometimes done in kinetic studies.
    Additional Material: 2 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Biochemical and Microbiological Technology and Engineering 1 (1959), S. 27-36 
    ISSN: 0368-1467
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Equipment has been developed in which fermentation processes for fastidious, pathogenic micro-organisms can be operated on a pilot-plant scale. Experience has shown the need for the development of concepts, techniques, and equipment meeting more stringent requirements than those ordinarily encountered in the fermentation industry. A system has been developed for the preparation of pure cultures which may be used either for the development of processes or in the preparation of substantial quantities of pure cultures. The equipment includes specially designed valves, fermentors, piping arrangement, and requires special methods of operation in order to maintain pure cultures during growth of the organism. The number of cultures of pathogenic, fastidious micro-organisms contaminated in the systems commonly used in industry is materially greater than the number of contaminated cultures produced in the system described.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Biochemical and Microbiological Technology and Engineering 1 (1959), S. 261-271 
    ISSN: 0368-1467
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: During the biosynthetic production of chlortetracycline on a medium with sucrose, soy meal, corn steep extract, sodium chloride, ammonium sulphate, calcium carbonate and beet molasses, the amount of nucleic acids synthesized by the culture and the maximum respiration of the culture is determined by the amount of inorganic phosphate in the original medium. Chlortetracycline production does not start until all the inorganic phosphate has been consumed. The adverse influence of increased amounts of inorganic phosphate upon production of chlortetracycline is more apparent in flasks on a shaking machine than in agitated and aerated fermentation tanks with higher oxygen transfer numbers.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 76-79 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Studies of the solvent extraction of cobalt and nickel nitrates from aqueous solution would add to the fundamental knowledge of extraction of metal salts. In experiments performed to determine the extractibility of these metals as nitrates from aqueous solutions by organic solvents, normal butanol was found to be the best solvent and gave equilibrium distribution coefficients K for cobalt or nickel nitrate of about 0.3. The presence of nitric acid tended to decrease these at high metal concentrations.In mixtures of the two metals the K value of either metal was found to depend on the total metal concentration. Low separation factors of about 1.3 were obtained. Very high K values of over 5 were obtained for the equilibrium extraction of the nitric acid in the presence of the metal nitrates by the n-butanol an indication of commercial possibilities.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 361-366 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The reaction rate of gaseous acetylene and hydrogen chloride was studied experimentally on a mercuric chloride-activated carbon catalyst at pressures from 1 to 4 atm. and temperatures of 167°, 212°, and 257°F. The measurements were made in a differential reactor packed with mercuric chloride impregnated on activated carbon, the data being taken to obtain the separate effect of the partial pressure of each of the components on the rate.The results indicated that hydrogen chloride was strongly adsorbed on the catalyst and that vinyl chloride was also adsorbed to a significant extent. A rate equation, which well represented the data, was developed from the following postulates: (a) acetylene is adsorbed on the catalyst on one type of site, (b) hydrogen chloride and vinyl chloride are adsorbed on a different kind of site, (c) the formation of vinyl chloride occurs by reaction of adsorbed acetylene and adsorbed hydrogen chloride, and (d) the rates of adsorption and desorption are fast compared with the formation rate of vinyl chloride.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 257-262 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer and fluid dynamics were studied in columns in which hot mercury was sprayed into a rising stream of water. Volumetric and area heat transfer coefficients are presented which were found to be lower than those reported for heat transfer from fixed spheres.It was observed that considerable water bypassed the stream of drops, while some surrounding the drops flowed downward. This behavior resulted in water temperatures at the base of the column which were considerably higher than the inlet water temperatures. Consequently the outlet mercury temperature did not approach the inlet water temperature as a limit. The very unconventional flow pattern of the water was unexpected and is believed to be an important factor in spray-column heat transfer and mass transfer kinetics.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 125-129 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 295-300 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of multicomponent distillation is considered for a column with an arbitrary number of feed streams and an arbitrary number of side-stream withdrawals. The overheads from the side-stream strippers are admitted to the column, introducing the inert stripping medium into the main column. Provisions are made in the calculations for complete heat balancing, inert injection, and internal reflux cooling. The method of computation is that of a previous paper involving the component-by-component technique. Calculations are made on the main column and give first approximations to the side-stream compositions; stripper calculations are then initiated. An alternating procedure is instituted between the main column and the strippers, the successive iterations continuing until a preassigned accuracy in the desired quantities is reached. An extensive numerical problem is worked.
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 2 (1959), S. 216-224 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The force required to peel an aluminum (or nickel) ribbon glued to a rigid glass plate with a polyethylene or polyvinyl acetate was determined. It proved to be smaller than expected (from a theory, partly new) both for adhesives which were almost Hookean solids and for those whose stress-strain curve could approximately be represented as stress = const. (strain)0.5. In the latter group, the difference between the theory and the experiment was due to stress concentrations at the right-hand and the left-hand edges of the adhesive layer; these stress concentrations formed because, when a pull was applied, the adhesive contracted in the directions perpendicular to that of pull. As a consequence of this effect, the peeling force W0 was not proportional to the width w of the ribbon; sometimes, a linear relation W0 = aw + b seemed to be valid. On the other hand, near-Hookean adhesives of a low total elongation required a peeling force proportional to w; the stress concentration dangerous for these materials occurred at the boundary between the adhesive and the bent ribbon at the sharp bend. The damage to the brittle adhesive caused by the ribbon deformation could be reproduced without bending, namely by extension of the ribbon beyond its yield strength.
    Additional Material: 9 Ill.
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