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  • unknown  (21)
  • Chemical Engineering  (20)
  • Organic Chemistry  (12)
  • AERODYNAMICS  (2)
  • GENERAL  (2)
  • 1955-1959  (57)
  • 1958  (57)
Collection
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  • 1955-1959  (57)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 439-444 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: That phase equilibrium exists at the gas-liquid interface during gas absorption is usually assumed in the analysis and design of absorption equipment, but the validity of this assumption has been in doubt since Higbie's pioneering gas-absorption studies. Accurate measurements are reported herein of the absorption rates at 25°C. of carbon dioxide into short water jets in which the liquid was in laminar flow. The jets issued from circular nozzles of about 1.5-mm. diam., flowed intact downward through an atmosphere of carbon dioxide at average velocities of from 75 to 550 cm./sec. over distances of 1 to 15 cm., and were collected in a receiver slightly larger in diameter than the nozzles. The measured absorption rates are in excellent agreement with predictions based on unsteady state diffusion theory, when one assumes interfacial equilibrium. It is concluded from these results and those of other investigators that equilibrium prevails at a freshly formed, relatively clean, carbon dioxide-water interface and that the same statement probably applies to the absorption of other slightly soluble gases in water.Evidence is discussed which indicates that an accumulation of minute quantitities of surface-active materials may seriously reduce the rate of gas absorption, either by affecting the hydrodynamic characteristics of the system or perhaps by offering resistance to the transfer of solute molecules across the interface.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 382 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 3
    Publication Date: 2005-01-20
    Keywords: unknown
    Type: NACA CONF. ON HIGH-SPEED AERODYN. 1958; P 357-371
    Format: text
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 43-48 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data are reported for condensing Freon-114 (tetrafluorodichloroethane) and steam at several pressures. The condition of the vapors ranged from saturation to 180°F. of superheat. The condensing tube containing embedded thermocouples was 3/4 in. in diameter and 3 ft. long. Visual observation showed that steam condensed by dropwise condensation in part. Increase of superheat in the vapor at constant pressure caused a lowering of the tube-wall temperature, which was indicative of a lowering of the surface temperature of the condensate. The lowering of the condensate-surface temperature below the saturation temperature was computed from the experimental tube-wall temperatures, the heat flux, and Nusselt's equation for the condensate-film resistance. The lowering of the condensate-surface temperature is correlated with degree of superheat. An interfacial coefficient of heat transfer between the superheated vapor and the condensate surface is reported based on the computed surface temperatures. Schrage's analysis and equations for relating mass and heat transfer with conditions at an interface were simplified and used to correlated the experimental condensing load with the degree of superheat.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 223-230 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rate of absorption of chlorine from chlorine-nitrogen mixtures into solutions of ferrous chloride in 0.203 N aqueous hydrochloric acid was studied in a short wetted-wall column. Dimensional analysis and the film and penetration theories were used to infer, from the absorption rate data, that the chemical reaction between chlorine and the ferrous ion is second order. The absorption-rate results for experiments with a dilute gas phase agreed with theoretical predictions for absorption accompanied by a second order reaction with a reaction rate constant of 188 liters/(g. mole) (sec.). The results for experiments with pure chlorine gas deviated from the rest of the results, and they did not agree with the theoretical equations. It was shown that the assumption of a three-step mechanism for the chemical reaction, including the formation of a complex ion and the decompositon of this complex ion, explains, at least qualitatively, the deviations observed for the pure chlorine gas runs.
    Additional Material: 12 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 266-268 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The correlation of Kolodzie and Van Winkle (3) for predicting dry plate orifice coefficients through perforated plates originally covering a Reynolds number range of 2000 to 20,000 has been extended to apply to Reynolds numbers as low as 400. The correlation applies to column diameters ranging from 3 to 15 in.
    Additional Material: 9 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 97-101 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 460-464 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The radial variation of void fraction in randomly packed beds of spheres, cylinders, Raschig rings, and Berl saddles was investigated. After packing, the beds were filled with paraffin, which was then allowed to solidify. Slabs were cut from the bed, and annular rings were removed by two different experimental techniques. An analysis of experimental error revealed that reproducibility, for the sample size used, between different parts of the same bed and different beds was quite good.For highly irregular shapes such as Berl saddles results indicate that the void fraction decreases regularly from one at the wall to the average porosity at about 1 particle radius from the wall. This is in agreement with work of other investigators using irregularly shaped packings; most commercial packings would probably fit in this category.For regularly shaped particles results are quite different. For spheres and cylinders cycling was observed for more than 2 particle diam. into the bed, the amplitude decreasing as distance from the wall was increased. The maxima and minima were observed at integral multiples of the particle radius. For Raschig rings a hump was observed at about 1/2 particle radius from the wall. The void fraction then decreased to its average value at 1 particle radius and then remained constant.
    Additional Material: 7 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 498-498 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 319-323 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A solution to the problem of heat transfer with simultaneous heat generation in viscous tubular flow is presented. The temperature profiles and heat transfer coefficients which are obtained apply to compressible as well as incompressible Newtonian and power-law non-Newtonian fluids with constant physical properties and to systems in which the heat generation is an arbitrary function of radius. An example of heat transfer with frictional heat generation in a non-Newtonian fluid is also presented, and the solution to the problem in which a fluid enters a tube in laminar flow with an arbitrary temperature profile is given, with a consideration of a first approximation to the case of heat transfer in a turbulent fluid in which heat is being generated.
    Additional Material: 4 Ill.
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