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  • Chemical Engineering  (325)
  • Life and Medical Sciences  (210)
  • Biology
  • GENERAL
  • General Chemistry
  • 1975-1979  (530)
  • 1955-1959  (174)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal of Morphology 152 (1977), S. 1-19 
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Records of electrical activity in the tracheal muscles of domestic chickens were obtained for a variety of ad libitum vocalizations. Primary attention was given to an analysis of events during the most complex call, crowing.Three pairs of muscles, Mm. tracheohyoideus, tracheolateralis, and sternotrachealis, can affect the configuration of a chicken's syrinx. The firing patterns of the three muscle pairs are related to their different abilities to affect the tension of the syringeal membranes. The influence of M. tracheohyoideus is most indirect and imprecise, and its role the least clearly defined. It appears to adjust the position of the trachea so that the syrinx is isolated from unpredictable and/or undesirable consequences of nuchal position and tracheal elasticity, and also helps draw the glottis caudad, thereby deepening the pharyngeal chamber. The other two muscles interact to control the tension of the vocal membranes. M. sternotrachealis relaxes the membranes by drawing the drum of the trachea caudad, or, via the syringeal ligament, by rotating the pessulus cranioventrad, or both. M. tracheolateralis tenses the membranes and/or prevents caudal movement of the origin of M. sternotrachealis, a necessity if the syringeal ligament is to rotate the pessulus.Vocalization depends on both syringeal configuration and appropriate air flow. Hence, tracheal muscles, syrinx, air sacs, and ventilatory muscles cooperate to form a vocal system. Cooperation elicits a surprising degree of redundancy. At least one call, a high pitched wail, may be produced by two very different techniques.
    Additional Material: 12 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 289-297 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A flash photomicrographic method and modified dye-light transmittance technique are employed to measure size distributions and mixing frequencies in a turbulently agitated flow vessel. This liquid-liquid dispersion is nearly spatially homogenous. Mixing frequencies are strongly dependent on impeller speed and moderately dependent on holdup fraction.
    Additional Material: 6 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 744-750 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Random search procedures have recently been successfully applied to the optimization of a variety of chemical engineering problems, including optimization of chemical processes by flow sheet simulation. These procedures represent the independent variables as random variables described by probability distributions. The adaptive random search procedure centers the distribution for each variable about the best search point found and examines this region for a better point. Thus, this technique has the ability of continuously moving the search region toward the optimum, which is particularly advantageous in following constraints.This study examines the efficiency of the adaptive random search technique as applied to six different problems, which have been previously solved by various other techniques.
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 851-855 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bench scale packed columns were used to study the kinetic behavior of biological denitrification. After tracer studies were run to determine flow characteristics, steady state nitrate profiles were determined. A first-order rate expression with an Arrhenius temperature dependence is an adequate model of the reaction for nitrate-nitrogen concentrations of 〈 100 mg/l and temperature of 5° to 20°C. The rate constants are proportional to the packing surface area.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 33-36 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental equilibrium vapor and liquid compositions are reported for the hydrogen-methane system at -150°, -200°, and -250°F. and at pressures of 500 to 4,000 lb./sq. in. The ternary system hydrogen-methane-propane was studied at 0°, -100°, and -200°F. at 500 and 1,000 lb./sq. in. Phase compositions were determined for a limited number of similar conditions for the hydrogen-methane-propylene and hydrogen-methane-ethylene-ethane-propylene-propane systems.
    Additional Material: 12 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 439-444 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: That phase equilibrium exists at the gas-liquid interface during gas absorption is usually assumed in the analysis and design of absorption equipment, but the validity of this assumption has been in doubt since Higbie's pioneering gas-absorption studies. Accurate measurements are reported herein of the absorption rates at 25°C. of carbon dioxide into short water jets in which the liquid was in laminar flow. The jets issued from circular nozzles of about 1.5-mm. diam., flowed intact downward through an atmosphere of carbon dioxide at average velocities of from 75 to 550 cm./sec. over distances of 1 to 15 cm., and were collected in a receiver slightly larger in diameter than the nozzles. The measured absorption rates are in excellent agreement with predictions based on unsteady state diffusion theory, when one assumes interfacial equilibrium. It is concluded from these results and those of other investigators that equilibrium prevails at a freshly formed, relatively clean, carbon dioxide-water interface and that the same statement probably applies to the absorption of other slightly soluble gases in water.Evidence is discussed which indicates that an accumulation of minute quantitities of surface-active materials may seriously reduce the rate of gas absorption, either by affecting the hydrodynamic characteristics of the system or perhaps by offering resistance to the transfer of solute molecules across the interface.
    Additional Material: 8 Ill.
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  • 7
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The separation of 4.5 g. of americium from approximately a kilogram of light rare earths (primarily lanthanum) was achieved on a pilot plant scale by chromatographic displacement of the mixture from Dowex-50 resin with 0.1% ammonium citrate at pH 8 into hydrogen-form Dowex-50. The americium collected into a narrow band and was eluted free from lanthanum but contained an equal weight of cerium. A 6- and a 2-in.-diam. column were used in tandem. Use of a final column with a much smaller diameter would have permitted a cleaner separation from cerium, but this was left for a laboratory-scale separation by a different process. Precipitation, which was observed in the columns during the first runs, was later avoided entriely by use of high flow rates both initially and during the transfer between columns. No adverse effects were noted from ∼15 curies of alpha activity.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 397-402 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In connection with a study of the mechanism of gas absorption the problem arose of predicting absorption rates into laminar liquid jets. A solution to the problem is presented in this paper, which provides an example of the application of fluid dynamics to the analysis of mass transfer in a complex flow system.The water jets considered here issued from circular nozzles of about 1.5-mm diameter, flowed intact downward through an atmosphere of solute gas at average velocities of from 75 to 550 cm./sec. over distances of 1 to 15 cm., and were collected in a receiver slightly larger in diameter than the nozzles. Equations describing the liquid flow near the jet surface are deduced from measurements of jet diameter and analogy to related flow situations. When one uses these equations, absorption rates are predicted from unsteady state diffusion theory with the assumption of interfacial equilibrium. The predicted rates for carbon dioxide at 25°C are in close agreement with experimental determinations over the observed range of contact time of the liquid with gas, namely 0.003 to 0.04 sec.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 623-623 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 656-663 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The tearing or decomposition of recycle process networks is extended to include the enumeration of alternate cut sets or tear stream sets. The optimality criterion is the response to convergence acceleration in the quasi-Newton sense and an algorithm is proposed to select the optimum cut set adaptively as the recycle computation proceeds.
    Additional Material: 12 Ill.
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