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  • 1
    Publication Date: 2016-09-02
    Description: Oxygen electrochemistry plays a key role in renewable energy technologies such as fuel cells and electrolyzers, but the slow kinetics of the oxygen evolution reaction (OER) limit the performance and commercialization of such devices. Here we report an iridium oxide/strontium iridium oxide (IrO x /SrIrO 3 ) catalyst formed during electrochemical testing by strontium leaching from surface layers of thin films of SrIrO 3 . This catalyst has demonstrated specific activity at 10 milliamps per square centimeter of oxide catalyst (OER current normalized to catalyst surface area), with only 270 to 290 millivolts of overpotential for 30 hours of continuous testing in acidic electrolyte. Density functional theory calculations suggest the formation of highly active surface layers during strontium leaching with IrO 3 or anatase IrO 2 motifs. The IrO x /SrIrO 3 catalyst outperforms known IrO x and ruthenium oxide (RuO x ) systems, the only other OER catalysts that have reasonable activity in acidic electrolyte.
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 136-142 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The pressure-drop characteristics associated with one liquid and one gaseous phase flowing concurrently in a pipe or tube have yet to be understood. The operation of evaporators, boilers, and condensers has long stimulated interest in the pressure drop of steamwater mixtures, and more recently this specialized case of one-component, two-phase flow has received even greater attention from the applications in cooling nuclear reactors. The two-phase-flow problems have not been amenable to through theoretical analyses, and therefore empirical and semiempirical correlations have attained unusual prominence in practical applications. The present investigation employs a new research tool for the study of two-phase-flow structure.A variety of geometric flow patterns is possible. Bergelin, Alves, and others have classified these patterns according to visual appearance; whereas the Martinelli classifications were based upon whether the flow in each phase was termed viscous or turbulent. The distinction between viscous and turbulent flow in either phase is rather arbitrary, and if the Reynolds number for one phase, calculated on the basis of the total tube diameter, is greater than 2,000, the flow in the phase is called turbulent. This investigation is confined to the study of annular flow, in which most of the liquid is found in an annular ring surrounding the central vapor core and the flow in each phase is turbulent.Boiling or flashing occurs when superheated water rises in an insulated vertical tube at atmospheric pressure. For a separated two-phase flow geometry, the mean linear steam velocity may exceed that of the water. The fraction of the tube occupied by the steam (void fraction) at a given cross section cannot be obtained directly from a determination of the thermodynamic quality. Void fractions, however, must be known for the estimation of the pressure drops due to head and momentum changes.Void fractions and pressure drops for steam-water flows were measured in an 0.872-in. I.D. vertical tube at atmospheric pressure over a quality range of 0 to 4%. The test section was the hot leg of a natural-circulation loop, and the inlet liquid flow rate ranged from 1 to 3 ft./sec. A new technique for measuring void fractions was used, and the method utilizes the difference between the gamma-ray absorption coefficients of water and steam.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 462-466 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A kinetic study of the catalytic vapor-phase hydrogenation of three aldehydes (acetaldehyde, propionaldehyde, and n-butyraldehyde) was made at low conversions with a commercial supported nickel catalyst. A simple initial rate equation was determined and found to agree with a mechanism suggested by the ideal kinetics of Hougen and known experimental evidence. By means of this equation the relative reactivities of the aldehydes were compared and found to agree with the predictions of organic theory. An improved reactor designed to ensure isothermal operation is described.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 90 (1957), S. 1287-1289 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 5′-Nitro-2′-hydroxy-chalkone wurden durch Kondensation von 5-Nitro-2-hydroxy-acetophenon mit Benzaldehyd, Anisaldehyd und Piperonal dar-gestellt und in die entsprechenden 6-Nitro-flavon-Derivate übergeführt.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 5 (1957), S. 101-104 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: With a view to prepare titanium tetra-acetate, the reaction between titanium tetrachloride and a mixture of acetic acid and acetic anhydride has been investigated in detail. It has been shown that the reaction in cold yielded pure crystalline dichloride di-acetate of titanium. On refluxing the reaction mixture, decomposition reactions occurred, yielding basic titanium derivatives of the type .
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The capacity of cells containing solutions of 5% cellulose acetate in dioxane was measured from 50 cycles to as high as 5 megacycles by a bridge method. A dispersion region was found between zero and approximately 40 kc. The frequency where the dielectric dispersion was 0.50 was taken as the critical frequency which was found to be related to the viscosity determined degree of polymerization. An empirical correlation enabled the calculation of degrees of polymerization from dielectric dispersion which could be readily duplicated and which agreed reasonably well with those found by the viscosity method. It is suggested that this procedure may develop into a very convenient and rapid method for molecular weights pending the accumulation of further experimental evidence.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Two viscometric methods have been developed for detecting the “critical concentration” (the concentration at which individual polymer molecules interfere with each other) of a dilute solution of a high polymer, B. In the first of these, the intrinsic viscosity, [η], of another polymer, A, is measured in a series of mixed solvents, each consisting of a solution of Polymer B in the solvent S, and each differing from the others only in the concentration of B (CB). For a number of polymer-polymer-solvent systems, data are presented which show that [η] is essentially independent of CB, except over a small range where its value changes fairly abruptly. This change marks the critical concentration. The second method is much faster but probably less reliable than the first. Nevertheless, the two gave values in good agreement. A method of calculating the critical concentration, based on the Flory-Fox theory of intrinsic viscosity, is described. Critical concentrations calculated for the several systems investigated agreed well with those obtained experimentally. The critical concentration was shown to be inversely proportional to the intrinsic viscosity of the Polymer B in experiments in which [η]B was varied by changing the molecular weight of the polymer and by changing the solvent. The effects observed are explained as resulting from interactions of the two polymer species in the solutions.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 290 (1957), S. 95-100 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction of titanium ethoxide and isopropoxide with excess of acetic anhydride results in the formation of a compound with the formula . No tetra-acetate of titanium could be prepared by the above reaction. The reaction of titanium isopropoxide with acetic anhydride (one, two and three moles) was further tried. It has been shown that the reaction upto two moles is facile and the compounds, Ti(OPr1)3 (OAc) and Ti(OPr1)2 (OAc)2, have been prepared for the first time. Further reaction of the diacetate with acetic anhydride becomes slow and the tri-acetate formed reacts with the remaining diacetate resulting finally in a product which corresponds in analysis to . This product also on treatment with excess acetic anhydride has been found to yield .
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 290 (1957), S. 87-94 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: With a view to prepare the tetra-soaps of titanium, the reaction between titanium alkoxides and excess of various fatty acids has been studied in refluxing benzene. The alcohol produced was removed azeotropically with the solvent. However, all the four alkoxy groups per titanium atom could not be replaced in any of the experiments. Even on carrying out the reaction in a higher boiling solvent like toluene, similar results were obtained and only 3 moles of alcohol per mole of the alkoxide could be azeotropically distilled out. It has been shown that the fourth alkoxy group is held in such a manner that it cannot be displaced even on refluxing the reaction product with higher alcohols or water. On heating the product to about 200° under reduced pressure, the excess fatty acid which distilled out has been shown to be mixed with some ester and the residue was found to be a decomposed titanium soap of the type TiOx(OOCR)4-2x with the value of ‘x’ nearly 0.5. These observations have been explained either by the steric hindrance to the entry of the fourth acid group or by the occurrence of other side reactions with the formation of organic ester.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 291 (1957), S. 97-102 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A. detailed study has been made of the reactions between titanium alkoxides and fatty acids. The reaction of titanium ethoxide and isopropoxide with excess fatty acids results in a product which after acetone treatment corresponds to a mixture of TiO(R′COO)2 (I) and O (II). The relative proportion of (I) increases in the product with the increasing number of carbon atoms in the fatty acid. Further it has been shown that the reaction is straight-forward upto the formation of titanium dialkoxy-di-acylates. Diethoxy- and di-isopropoxy-palmitates of titanium have thus been prepared. The above derivatives interchange their alkoxy-content readily with butanol and yield titanium dibutoxy-dipalmitate. When the dialkoxy-palmitates are treated with one mole of the fatty acid, a complex reaction occurs with the elimination of alkyl-palmitate and formation of decomposed titanium derivatives. These observations throw fresh light on the mechanism of titanium alkoxide-excess fatty acid reactions which have been described in an earlier publication.
    Type of Medium: Electronic Resource
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