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  • 1990-1994
  • 1955-1959  (19)
  • 1959  (8)
  • 1957  (11)
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  • 1990-1994
  • 1955-1959  (19)
Year
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 49 (1957), S. 583-589 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 49 (1957), S. 894-903 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 49 (1957), S. 986-992 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 51 (1959), S. 472-480 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 183 (1959), S. 542-543 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Table 1. DOSES OF D.F. 596 REQUIRED TO PRODUCE PARALYSIS IN DIFFERENT SPECIES Species Test Intravenous dose mgm./kgm. with limits of error (P = 0-05) D.F. 596 (2-Tubocurarine chloride Mouse Rat Dose causing 50 per cent of animals to fall from an almost vertical wire mesh screen within 1 min. ...
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 361-366 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The reaction rate of gaseous acetylene and hydrogen chloride was studied experimentally on a mercuric chloride-activated carbon catalyst at pressures from 1 to 4 atm. and temperatures of 167°, 212°, and 257°F. The measurements were made in a differential reactor packed with mercuric chloride impregnated on activated carbon, the data being taken to obtain the separate effect of the partial pressure of each of the components on the rate.The results indicated that hydrogen chloride was strongly adsorbed on the catalyst and that vinyl chloride was also adsorbed to a significant extent. A rate equation, which well represented the data, was developed from the following postulates: (a) acetylene is adsorbed on the catalyst on one type of site, (b) hydrogen chloride and vinyl chloride are adsorbed on a different kind of site, (c) the formation of vinyl chloride occurs by reaction of adsorbed acetylene and adsorbed hydrogen chloride, and (d) the rates of adsorption and desorption are fast compared with the formation rate of vinyl chloride.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 49-55 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer coefficients were measured experimentally for carbon dioxide in turbulent flow in an 0.18-in. I.D. pipe. The pressure was 1,200 lb./sq. in. abs. and the bulk temperature varied from 70° to 120°F. In this critical region the coefficients between fluid and tube wall ranged from 300 to 2,600 B.t.u./(hr.)(sq. ft./°F.) over a Reynolds number interval of 30,000 to 300,000.Existing empirical and semitheoretical correlations were found inadequate in this region, where the thermal conductivity, viscosity, density, and specific heat are all varying rapidly and nonuniformly with temperature. A method of integrating the heat and momentum transfer equations with variable physical properties, recently proposed by Deissler, was applied to the experimental data and found to fit well. The application required extensive calculations, which were carried out with an Electrodata digital computer.A simplified procedure was proposed for estimating heat transfer coefficients in the critical region by using a semitheoretical equation developed for zero heat flow. Simple rules were suggested for estimating the temperature at which to evaluate the physical properties when this equation is applied to the realt case of finite heat transfer. The method worked well when compared with the computed heat transfer coefficients of Deissler for supercritical wate but showed about 30% deviation when compared with the carbon dioxide results. This discrepancy is believed due to the fact that the carbon dioxide was very close to the critical point (reduced pressure = 1.1) but the water was somewhat further removed (reduced pressure = 1.6).
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 147-152 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data are presented for the heats of mixing of liquids at 25°C. and 1 atm. pressure for ten binary and five ternary systems. For nonpolar binary systems a two-constant equation has been developed which correlates the data within experimental accuracy. Several equations which have been proposed for the calculation of ternary heats of mixing from binary data are tested for the systems studied. The method of Jost and Röck (4) for determining the constants in power-series functions from experimental data is considered.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 453-457 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A differential type of flow reactor, 0.25-in. I.D., was used to study the kinetics of the hydrogenation of ethylene on an alumina-supported nickel catalyst. This is apparently the first investigation made above atmospheric pressures. Data were obtained from 14.7 to 70 1b./sq. in. abs. and feed compositions from 40 to 90 mole % hydrogen. Measurements at temperatures from 30° to 80°C. indicated an apparent activation energy of 11,600 cal./g.-mole.It was found that the activity of the catalytic surface was reduced by exposure to ethylene, or mixtures containing an excess of ethylene, owing to the formation of acetylene residues. Pretreatment of the catalyst at temperatures of 170°C. with mixtures of ethylene and hydrogen stabilized the catalyst so that reliable rate data could be obtained.The rate measurements at 70°C. were correlated by an equation. While the mechanism of the reaction cannot be determined from the data, the rate expression and other kinetic studies suggest a process in which hydrogen is adsorbed on the small fraction of the surface not occupied by acetylenic residues and the reaction takes place between this adsorbed hydrogen and ethylene in the gas phase.
    Additional Material: 7 Ill.
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  • 10
    Publication Date: 1957-03-01
    Print ISSN: 0019-7866
    Electronic ISSN: 1541-5724
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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