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  • Chemical Engineering  (102)
  • Aircraft Stability and Control
  • GENERAL
  • Wiley-Blackwell  (102)
  • 1980-1984  (87)
  • 1955-1959  (15)
  • 1984  (87)
  • 1955  (15)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 317-328 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is developed that calculates the chemical equilibrium that exists between a flowing electrolyte solution and mineral assemblages. The development computes the mineral and aqueous compositions as a function of time and position in a one-dimensional porous medium. The model considers the dissolution of solids as well as their precipitation. The application of the model to various problems has revealed that characteristic aqueous and solid phase concentration waves develop and propagate through the system in a chromatographic manner. Example calculations are presented that illustrate the widespread applicability of the model. Specifically, a calculation is presented that reproduces the genetic mineralization features that are found in sandstone-type uranium deposits.
    Additional Material: 10 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 30-37 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An integral method including the entrainment hypothesis of Hoult, Fay and Forney (1969) is used to predict the concentration of product formed in a buoyant jet in a crossflow. The analysis is restricted to a slow, irreversible, second-order reaction with premixed reactants. Reliable laboratory data are presented for the oxidation of nitric oxide by the reaction 2NO + O2 → 2NO2 with excess O2 and these results are correlated with the theory. Additional measurements are recorded to provide information on the magnitude of the turbulent parameters necessary for proper closure of the rate expressions.
    Additional Material: 10 Ill.
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  • 3
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Preferential adsorption of organic compounds onto activated carbon from dilute aqueous solutions is studied to develop a comprehensive theoretical basis for predicting the adsorption of structurally different isomers for different homologous series. The fundamental multidimensional approachof the solvophobic (cφ) thermodynamic theory is further refined and used to correlate the extent of adsorption for the comprehensive theory with the overall standard net free energy change (ΔGnet/RT) for the association-adsorption reaction in solution, and for the simplified theory with the cavity surface area of the solute (TSA).Experimental adsorption isotherms of two homologous series (12 aliphatic alcohols and 21 aliphatic ketones) were measured and used to test and compare the cφ theory with seven independent parameters characterizing the sorbates. Several experimental innovations for measuring equilibrium adsorption isotherms are introduced to reduce the possible loss of sorbate during the procedure and to provide reproducible and reliable results.Comparing the coefficients of linear correlation (r), the results for 12 aliphatic alcohols give greater than 99% confidence that the r-values are different for ΔGnet/RT and molecular weight (MW). For the 15 aliphatic ketones, greater than 90% confidence interval is obtained for different r-values for TSA and MW.These results support the contention that simple structural modifications of aliphatic homologous compounds can be used to predict the effect of solute-solvent-sorbent interactions on adsorption. The cφ theory can thus be used to rank-order adsorption intensity of these compounds from the aqueous phase onto activated carbon.
    Additional Material: 9 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 341-345 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 856-858 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 24 (1984), S. 163-168 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dextran-g-poly(acrylamide-co-sodium acrylates) were prepared by partial hydrolysis of dextran-g-poly(acrylamides) with controlled numbers and lengths of grafted chains. This hydrolysis route proved to be more effective than Ce(IV)-induced cografting of acrylamide and sodium acrylate comonomers onto dextran in producing the desired graft-copolymer structures. The resulting copolymers were characterized and the effects of composition, temperature, ionic strength, and shear rate on dilute solution rheological properties were studied.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 24 (1984), S. 1300-1305 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In a series of publications we reported on melt rheology, morphology, and mechanical properties of the poly(ethylene terephthalate)/poly(amide-6,6) blends (PET/PA). The non-oriented samples had poor interphase bonding resulting in low impact and tensile strengths. To improve these properties the ester-amide interchange reaction was carried out in solution and in melt. In the latter case a Brabender Plastograph was used in the mixing chamber or twin-screw extruder configurations with p-toluenesulfonic acid as a catalyst. The interchange reaction was followed by 400 MHz proton and 13C nuclear magnetic resonance spectroscopy.
    Additional Material: 4 Ill.
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  • 8
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental information concerning the molecular transport of the lighter hydrocarbons in the gas phase is limited. For this reason a study was made of the Maxwell diffusion coefficients of n-hexane in the gas phase of the methane-n-hexane, and propane-n-hexane systems.Maxwell diffusion coefficients were determined at steady state for pressures up to 70 lb./sq. in. at temperatures between 70° and 220° F. The effects of interfacial resistance were considered and uncertainties as to the behavior at the end of the transport path were eliminated. Coefficients were reported with partial pressure and with fugacity as the potential. Fick diffusion coefficients were calculated for each component on the assumption that the gas phase was an ideal solution.These data indicated that the Maxwell hypothesis with fugacity as the potential in an ideal solution is a fair description of the transport characteristics of the lighter hydrocarbons in the gas phase at relatively low pressures. A regular decrease in the Maxwell diffusion coefficient with an increase in the molecular weight of the stagnant component was observed.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 99-110 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Solid tracer particles were fed pneumatically through a jet into a fluidized bed to simulate the feeding of solids via a pneumatic transport line into a fluidized-bed reactor operating in the slugging-bed mode. The fluidized bed was defluidized instantaneously at different times after the initiation of the tracer particle injection. The bed was then sampled layer by layer to provide the radial and axial concentration profiles of the tracer. Regular and high-speed movies (1,000 frames per second) were taken to study the operation of the fluidized bed and the phenomena of the gas-solid two-phase jet.Experimental results on solid mixing, jet constriction and slugging frequencies, slugging bed height, slug length, jet penetration, and jet half-angle at three nominal jet velocities of 52, 37, and 25 m/s and corresponding solids loadings are presented. Additional experimental results on jet constriction and slugging frequencies, and slug volume (axial slug size) obtained for a wider range of jet velocities confirm the hydrodynamic trends observed during the tracer particle injection experiments. The results indicate that solids mixing increases, and well-mixed conditions are reached earlier, with an increase in jet injection velocity. The obtained mixing times were correlated successfully in terms of the excess gas velocity. The experimental data on jet penetration and slug motion were satisfactorily correlated by modified versions of existing theoretical relations. The modifications included the effect of the injected solids on jet penetration and jet half-angle and also the effect of our semicircular column geometry and single wall-slug configuration on the observed slug motion.
    Additional Material: 16 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 213-220 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Until now the oxygen transfer in viscous non-Newtonian solutions has been studied only in bubble columns of about 0.14-m diameter. Recently Godbole et al. (1982) reported much smaller gas holdups in Carboxy Methyl Cellulose solutions (CMC) for a large-diameter column. Therefore, the gas holdups, volumetric mass transfer coefficients, and specific gas-liquid interfacial areas are measured in CMC solutions using a bubble column of diameter 0.305 m and height 3.4 m. The transition from churn-turbulent to slug flow regime occured at higher viscosities and the gas holdups and volumetric mass transfer coefficients were lower in both flow regimes than reported for smaller column diameters. Empirical correlations are presented for the gas holdup, volumetric mass transfer coefficient, and specific gas-liquid interfacial area which would be suitable for the design of fermentors.
    Additional Material: 10 Ill.
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