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  • Physics  (53)
  • Cell & Developmental Biology
  • Chemical Engineering
  • 1980-1984
  • 1970-1974  (109)
  • 1950-1954  (10)
  • 1970  (109)
  • 1952  (10)
Collection
Publisher
Years
  • 1980-1984
  • 1970-1974  (109)
  • 1950-1954  (10)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 420-425 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Thermodynamic properties of the chemically reactive system N2O4 ⇌ 2NO2 ⇌ 2NO + O2 have been evaluated over a pressure range of 0.005 to 200.0 atm. and a temperature range of 200° to 900°K. by making use of Lennard-Jones potential. In these calculations, the dissociation of nitrogen tetroxide to nitrogen dioxide, nitric oxide and oxygen, and the effect of pressure on the equilibrium constants for the system of reactions N2O4 ⇌ 2NO2 and 2NO2 ⇌ 2NO + O2 have been taken into account.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 86-93 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Boron fiber reinforced composites have been extensively evaluated in epoxy resin matrix materials, which are satisfactory for applications in comparatively moderate environments, and are usually inapplicable at temperatures in excess of 400°F. For use in high temperature environments in excess of this figure, it is necessary to use more thermally stable resins. A modified phenolic resin was selected for this application because of the versatility of the material and the successful performance of phenolics in glass fiber reinforced structures. The modifications increased the viscosity and tack of the formulation so that consolidation could not be readily accomplished by a combination of tension and heat during the winding process, so that a multi-stage winding process with intermediate consolidation steps became necessary. Winding a complex path to make a uniformly thick wall on a frustrum required further modifications to the basic winding process. The successful solution of these problems and the development of structurally sound composites was the primary object of this work.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2-Chloromethylbutadiene has been converted to quaternary ammonium and sulfonium monomers which have been polymerized at room temperature. They show a very great tendency to dimerize on heating in water solution. The aqueous quaternary monomer dimerized 25 times as fast as the aqueous sulfonium monomer and nearly 105 times as fast as neat isoprene at 50°C. The quaternary monomer dimerized with itself in a water solution to which 2-hydroxymethylbutadiene has been added as an example of a nonionic diene. The latter monomer did not dimerize rapidly in water, nor did 2-aminomethylbutadiene. The hydrochlorides of 2-aminomethylbutadiene and 2-dimethylaminomethylbutadiene dimerized at rates comparable to that of the sulfonium monomer. Poly 2-chloromethylbutadiene contains reactive chlorine except for the structure resulting from the minor extent of 1,2 addition. Water-soluble derivatives have been made from it with nucleophilic tertiary amines and sulfides. Cationic polymers are substantive to paper pulp, and the sulfonium polymers can be cured in paper to give improved wet strength.
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 8 (1970), S. 2103-2108 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Irradiation of terephthalophenone in isopropyl alcohol gave a bright yellow-colored intermediate which decayed rather rapidly. The products were complex and depended upon the mode of irradiation. They ranged from a mixed polymer I to a dimer II. I consisted of about 5 terephthalophenone units capped with hydrogen or isopropyl alcohol radicals or terminated by cyclization. II, the dimer, was capped by hydrogen atoms.
    Additional Material: 1 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 8 (1970), S. 2703-2711 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Exposure of poly(ethylene terephthalate) to γ-rays results in the formation of radical I, radical II (tentatively), and to an unassigned radical (III) which is responsible for a central peak in the ESR spectrum. It is believed that completely amorphous samples of polymer contain radicals II and III. On heating, the radicals decay, and the relative proportion of radical III increases. The kinetics of the overall decay process were followed by measuring the decrease in peak height with time. After an initially rapid reaction the decay of the radical population conformed to second order kinetics. An Arrhenius plot of the logarithm of specific rate versus 1/T indicated two lines which intersected at 72°C, which is close to the glass transition temperature. The activation energies were 112 kcal/mole above 72° and roughly 25 kcal/mole below 72°C. Reference to reports in the literature suggests that this decay can be explained by long-range movement of the polymer molecules, even in the glassy solid. The decay of radical I in the crystalline regions of an oriented sample was shown to follow first-order kinetics. As the decay occurs at temperatures as low as 100°C (the melting point is about 260°C), it seems that decay by normal physical movement is unlikely. The results might be explained by invoking the hypothesis of chemical migration of free radical sites by hydrogen atom hopping.
    Additional Material: 6 Ill.
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  • 6
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The structure and polysaccharide constitution of the jelly capsule of the egg of Rana pipiens is described. Microscopic examination of the jelly capsule revealed the presence of five discrete jelly layers that differed clearly in their response to selected cytochemical tests. These layers were classified as M1-through M5 from the inner to the outermost layer. A sixth layer occasionally could be observed between M3 and M4.All layers contain neutral mucopolysaccharides. In addition layers M1 and M3 contain sulphated mucopolysaccharides, M2 and M4 contain non-sulphated acid mucopolysaccharides, and layer M5 contains both sulphated and non-sulphated acid mucopolysaccharides. M2 may also contain a small quantity of sulphated mucopolysaccharides. The layer that occasionally appears between M3 and M4 is probably an area in which free acidic groups are in higher concentration than in adjacent areas rather than being a discrete jelly layer. Neither hyaluronic acid nor sialic acid was localized by the methods employed.The possible significance of some of these constituents is discussed.
    Additional Material: 1 Tab.
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  • 7
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Meiosis is described in virgin females, inseminated females and males of the acarid mite Caloglyphus mycophagus (Megnin). The observed sex determining mechanism is an XO-type with the male having a diploid chromosome number of 15. Oogenesis in mated females is regular. Pachytene is the earliest meiotic stage which is readily identifiable. At metaphase I eight bivalents are observed. Both products of the first maturation division divide at the second maturation division. After the fusion of the pronuclei either 15 or 16 chromosomes are observed in cleaving eggs.Nurse cells are not observed during the growth period of the oocyte. Such oocytes are attached to a central structure of the ovary by a cone-shaped organelle. At this stage the nucleus appears as a germinal vesicle; a nucleolus is present and the diffuse chromatin appears to extend from the nucleolus to the nuclear membrane. Nuclear extrusion bodies can be seen adjacent to the nuclear membrane both within and outside of the nucleus.Virgin females do not oviposit. The aberrant morphology and behavior of bivalents in post diakinetic oocytes which have not been penetrated by a sperm are described. Neither chromatin nor a chorion could be demonstrated in aberrant oocytes situated in the oviduct. It is suggested that oocyte degeneration in virgins is an adaptive feature in an animal order in which parthenogenesis is the more common mode of reproduction.
    Additional Material: 30 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 89-103 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The theoretical justification for using M[η], or a similar quantity, as a universal calibration parameter in GPC is reviewed. The equation based on this parameter is applied to transform the primary calibration curve, obtained by means of polystyrene samples, into calibration curves for poly-α-methylstyrene, polypropylene, and linear polyethylene. The Mark-Houwink equations for these polymers, as they are used in the transformation, are discussed. The resulting GPC calibration curves are compared with molecular weights and peak elution volumes of fractionated poly-α-methylstyrene and polypropylene. The same comparison is made with samples of polypropylene and polyethylene having very broad molecular weight distributions. The agreement lies within experimental error.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 47-59 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A simple method of preparing thin uniform films of high polymers has been examined for growing single crystals from solution. Single crystals of polyethylene, polypropylene, polybutene-1, polyacrylonitrile, and cellulose triacetate have been obtained by this method. Different stages of growth reveal different growth features that are also obtained from solutions of these polymers by changing temperature and concentration.
    Additional Material: 19 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 519-528 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Three transitions are detected dilatometrically when partially isotactic poly(propylene oxide) melts. One transition, the temperature of which is independent of the crystallization temperature over a wide range below 60°C, is ascribed to the melting of lamellar crystallites which are limited in thickness by the average isotactic sequence length alone. The other two transitions, the temperatures of which vary with the crystallization temperature, are ascribed to the melting of lamellar crystallites with thickness determined predominantly by three- and two-dimensional primary nucleation acts. The theory of Flory is adapted and applied quantitatively to the melting points of three crystalline fractions of poly(propylene oxide), obtained from a polymer produced via the zinc diethyl and water catalyst system. This method leads to a thermodynamic melting point of isotactic poly(propylene oxide) near 82°C.
    Additional Material: 3 Ill.
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