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  • Chemical Engineering  (32)
  • Wiley-Blackwell  (32)
  • Blackwell Publishing Ltd
  • National Academy of Sciences
  • 1980-1984
  • 1960-1964  (32)
  • 1945-1949
  • 1961  (21)
  • 1960  (11)
  • 1949
Collection
Publisher
  • Wiley-Blackwell  (32)
  • Blackwell Publishing Ltd
  • National Academy of Sciences
Years
  • 1980-1984
  • 1960-1964  (32)
  • 1945-1949
Year
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 40-46 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The non-Newtonian flow behavior of polyethylene has been investigated with respect to the effects of molecular weight and molecular weight distribution. Effects of die geometry on melt fracture as well as preliminary extrudate orientation studies are discussed.
    Additional Material: 16 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 619-624 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid-liquid extraction of acetic acid from the methyl isobutyl ketone-water system was studied as a function of plate wetting characteristics and other variables in a pulsed perforated-plate extraction column.Various combinations of stainless steel plates and polyethylene plates were used with different directions of solute transfer at a constant throughput of 82.6 lb. total flow/(min.) (sq. ft. column area) and with other operating variables in the following range:Frequency  -  16 to 117.1 c./min.Amplitude  -  0.492 and 0.973 in.W/K flow ratio  -  0.46 to 2.8 lb. water/lb. ketoneThe plate wetting characteristics were found to affect the column extraction efficiency when the solute transfer was from the continuous ketone phase to water. An all polyethylene plate arrangement provided the best efficiency (H. T. U.oc = 4.1 in.) while an all stainless steel plate arrangement was less efficient (H. T. U.oc = 6.1 in.) under the most favorable operating conditions. A combination of these two arrangements in the column produced efficiencies midway between the all-plastic plate arrangement and the all-stainless steel plate arrangement.Within the column flooding limits the extraction efficiency did not seem to be affected by the plate wetting characteristics when the solute transfer was from water to the continuous ketone phase.
    Additional Material: 5 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 631-639 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer and pressure-drop measurements were made with non-Newtonian aqueous thorium oxide suspensions. A comparison of the results of the two different kinds of measurement allowed the general features of non-Newtonian thorium oxide suspension heat transfer to be readily identified, thus leading to a clear understanding of anomalies observed in previous suspension heat transfer studies.Data were obtained at suspension concentrations up to 0.10 volume fraction solids, (1,000 g. of thorium/kg. of water) in systems having tube diameters of 0.318 and 1.030 in. In addition laminar-flow data were taken with a capillary-tube viscometer with a tube diameter of 1/8 in. and an L/D of 1,000. It was shown that laminar flow physical properties determined with the 1/8 in. diameter tube were satisfactory for correlating data taken with tubes up to 1.030 in. in diameter.Until the present study information was not available which would permit a choice between two different viscosities for use in correlating non-Newtonian turbulent heat transfer and flow data. The limiting viscosity at very high shear rates is shown to give a unique correlation of turbulent data for tube diameters from 0.124 to 1.030 in., whereas the use of the effective viscosity (that is the viscosity evaluated at the point value of the wall shear stress corresponding to each given flow condition) gives a pronounced diameter effect in turbulent-flow correlations.The data show that the onset of turbulence for both the pressure-drop and heat transfer measurements occurs at the same Reynolds number and is approximated by the value predicted by the Hedstrom criterion (II). The heat transfer transition region extends to Reynolds numbers a factor of four times greater than the critical, as is also the case with Newtonian materials. Heat transfer to thorium oxide slurries in fully developed turbulent flow is the same as that predicted by the usual correlations for Newtonian fluids to within the precision of the experimental data, provided that the Reynolds and Prandtl numbers are calculated with the limiting viscosity at high rates of shear, η, for this viscosity. An approximate form of Martinelli's momentum heat transfer analogy correlates the experimental results within +17 and -36%.
    Additional Material: 12 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 352-352 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 602-605 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data are presented to show the points of incipient hydrate formation in the methane-propylene-water system. The addition of 1.4% propylene to methane lowered the equilibrium pressure 400 lb./sq. in. at 50°F. The locus of the four-phase equilibrium consisting of hydrate, vapor, water-rich liquid, and hydrocarbon-rich liquid was determined. This was terminated by the appearance of a critical condition at 1,370 lb./sq. in. abs. and 69.3°F., where the vapor phase contained 34.8% propylene on a dry basis. Below this pressure the hydrate, vapor, water-rich liquid equilibrium does not exist for solutions containing more than about 25% propylene. Solid-vapor equilibrium ratios were estimated for propylene hydrates. The significant features of the phase diagrams for the system are discussed in some detail.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 87-90 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented for the measurement of thermal diffusivity of synthetic and natural rock materials at elevated temperatures. The method involves heating of cylindrical test specimens at a constant rate of rise of the edge temperature and measuring the temperature differential between a point just inside the sample edge and the center of the sample. It is shown that for a fixed geometry and a constant heating rate thermal diffusivity is inversely proportional to the temperature differential.A record of the variation of diffusivity with temperature may be obtained through the temperature range of 150 to 1000°C. (except where thermal reactions occur) within a period of less than 2 hr.Measurements are reproducible within ± 10% for a given material. Accuracy of the values obtained is believed to be good; however there are no data available for direct comparison with the materials tested. Use of an approximate equation for calculation of diffusivity from experimental data leads to errors of the order of only 0.5%. Fairly good agreement was obtained between steady state measurements and measurements by the present method.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 34-37 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The influence of the concentration gradient on the density gradient in a thermal-diffusion column is called the forgotten effect. A modification of the theory developed by Furry, Jones, and Onsager is proposed to include the effect of the horizontal concentration gradient. A sample calculation with the system toluene-cyclohexane shows that the equations predict the proper behavior for a forgotten-effect system.
    Additional Material: 1 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 143-147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experiments on the continuous catalytic water-gas shift reaction have been carried out making full use of the principles of statistical design to elucidate the reaction mechanism. Instantaneous reaction rates were determined for sixteen different combinations of the five variables: partial pressures of carbon monoxide, hydrogen, carbon dioxide, and temperature. Nitrogen gas was used as an inert diluent to make up the total pressure to 1 atm. From the analysis of variance of these sixteen runs it can be shown that the Temkin mechanism for the water-gas shift reaction cannot represent the data within the experimental accuracy. A tentative alternative mechanism which is consistent with the data obtained is presented. The work shows that while it is possible to obtain useful empirical kinetic data from small, well-planned experiments, both highly precise experimental data and very careful statistical treatment are required. When these are available, a very marked reduction in the amount of experimental work can be effected.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 231-239 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure drop and liquid saturation accompanying two-phase concurrent flow have been studied in a variety of packings and with gas-liquid systems having a wide range of fluid properties. Two basic flow patterns were observed with nonfoaming systems. Correlations of pressuredrop and liquid-saturation data were obtained in terms of the single-phase friction losses for the liquid and the gas when each flows alone in the bed. Deviations from the correlation with foaming systems are discussed and illustrated with sample data.
    Additional Material: 9 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 357-362 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The investigation was concerned with measuring growth rates of bubbles in an isothermal medium where growth is controlled by mass diffusion. The conditions were met by generating hydrogen bubbles at a platinum cathode during the electrolysis of water. Growth data were obtained by motion picture photography at 800 to 2,400 frames/sec. taken through a microscope to produce an enlargement of 30X on the film.Growth took place in 0.1 normal and 1.0 normal sulfuric acid in water at 77°F. Current densities between 0.1 and 0.2 amp./sq. cm. were used. The observed diameters were all less than 0.006 in., and the growth times were less than 2 sec. Beside growth phenomena interesting features recorded included the coalescence of bubbles, the jumping of bubbles off the solid and then back again, and the slip of the bubble contact at the solid surface.Some bubbles grew with their radii proportional to the square root of time as predicted theoretically by Scriven. For these bubbles the calculated supersaturation of hydrogen in the solution was found to be from eight to twenty-four times the concentration at saturation.
    Additional Material: 9 Ill.
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