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Die Kristallstruktur von TlFeSe2 und TlFeS2 (1979)

Klepp, Kurt ; Boller, Herbert

Springer

Monatshefte für Chemie 110 (1979), S. 1045-1055

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ISSN: 1434-4475

Keywords: Chalcogenides ; Crystal structure ; Raguinite ; TlFeS2 ; TlFeSe2

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract TlFeSe2 is monoclinic, space groupC2/m−C 2h 3 ,a=11.973 Å,b=5.490 Å,c=7.110 Å, β=118.2°,Z=4. TlFeS2 is isotypic witha=11.636 Å,b=5.304 Å,c=6.799 Å, β=116.7°. The crystal structure of TlFeSe2 has been determined from single crystal diffractometer data. Isotypy of the sulfide has been confirmed from powder diffraction data. The crystal structure containing infinite linear chains of edgesharing FeX 4-tetrahedra, and its relationship to the thio- and selenoferrates of the alkali metals are discussed. The mineral raguinite is very probably isotypic to synthetic TlFeS2.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00910952

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