ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Mass spectrometric studies have been made of the [(C7H8)Cr]+ ions generated from (η6-PhCH3)Cr(CO)3 and (η6-c-C7H8)Cr(CO)3. Fragmentation behaviour and appearance potential measurements have been used to show that the ions from the two precursors do not achieve a common structure. [(C8H10)Cr]+ generated from (η6-PhEt)Cr(CO)3 and (η6-c-C7H7Me)Cr(CO)3 behave similarly. A study of the α-d3 toluene complex suggests the structure [CH3C6H4-CrH]+ is appropriate for [C7H8Cr]+ ions generated from (η6-PhMe)Cr(CO)3 and decomposing to [CrH]+.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210130913
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