ISSN:
0749-1581
Schlagwort(e):
Chemistry
;
Analytical Chemistry and Spectroscopy
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Electron paramagnetic resonance spectroscopy has been used to probe the decomposition pathway of neat molten 2,4,6-trinitrotoluene (TNT). The analogs of TNT labelled in the 2-, 2,6-, 4- and 2,4,6-positions with 15N, and labelled in the α-, 3,5- and α,3,5-position with 2H have been studied, and their spectra recorded at 240°C. The results indicate that the earliest observable radical produces a spectrum resulting from coupling with a para-N (aN = 10.8G), five equivalent hydrogens (aH = 2.7G) and two benzylic hydrogens (aH = 10.7G).
Zusätzliches Material:
8 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/mrc.1260240906
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