ALBERT

Beschreibung: Oxygen and carbon isotopic records have been developed for the Cenozoic carbonate oozes of Sites 752, 754, 756, and 757 based on the analysis of monospecific benthic foraminifers. The intent of this report is to provide a basic isotopic stratigraphy for use in other paleoceanographic studies. The oxygen isotope record displays the enrichments associated with cooling or ice volume buildup at the Eocene/Oligocene boundary, in the middle Miocene, and in the upper Pliocene. The carbon isotopic record contains the Chron 16 enrichment in the lower Miocene and the Chron 6 depletion in the uppermost Miocene.

Beschreibung: The basaltic rocks of Hole 794D drilled during Leg 128 are strongly altered. Microprobe analyses and XRD spectra on small quantities of matter extracted from thin sections show that primary minerals and glassy zones of the groundmass are totally or partially replaced by clay minerals with chlorite/saponite mixed-layer composition whatever the rock sample considered. This mixed-layer was also identified in veins and vesicles where it crystallizes in spheroidal aggregates. The largest veins and vesicles are filled by a zoned deposit: the chlorite/saponite mixed-layer always occupies the central part and is rimmed by pure saponite. Calcite crystallizes in secondary fractures which crosscut the clayey veins and vesicles. Chemographic analysis based on the M+-4Si-3R2+ projection shows that the chemical composition of the saponite component in the mixed-layer is identical to that of the free saponite. This indicates that the clay mineral crystallization was controlled by the chemical composition of the alteration fluids. From petrographic evidence, it is suggested that both chlorite/saponite mixed-layer and free saponite belong to the same hydrothermal event and are produced by a temperature decrease. This is supported by the stable isotopic data. The isotopic data show very little variation: d18O saponite ranges from 13.1 per mil to 13.5 per mil, and dD saponite from -73.6 per mil to -70.0 per mil. d18O calcite varies from +19.7 per mil to +21.9 per mil vs SMOW and d13C from -3.2 per mil to +0.4 per mil vs. PDB. These values are consistent with seawater alteration of the basalt. The formation of saponite took place at 150°-180°C and the formation of calcite at about 65°C.

Beschreibung: We developed an isotope (87Sr/86Sr, delta18O) reference section for the uppermost Oligocene to lower upper Miocene (ca. 25-8 Ma) at Site 608 in the northeastern North Atlantic. This site contains the least ambiguous magnetostratigraphic record of Miocene polarity changes available, providing direct correlations to the Geomagnetic Polarity Time Scale (GPTS). We integrate biostratigraphic, magnetostratigraphic, Sr isotope, and stable isotope data to provide a reference section for Miocene isotope fluctuations. The direct correlation of isotopes and biostratigraphy to the Geomagnetic Polarity Time Scale (GPTS) provides relatively precise age estimates. We use these age estimates to evaluate the timing of first and last occurrences of planktonic foraminifera, and conclude that many of these are synchronous within a 0.5 m.y. resolution between subtropical Site 563 (33°N) and high-latitude Site 608 (43°N). In addition, we use this chronology to estimate the ages of previously established Miocene oxygen isotope Zones Mi 1 through Mi 7 and to compare the Sr isotope record at Site 608 with previously published 87Sr/86Sr records. We approximate latest Oligocene to early late Miocene (25-8 Ma) Sr isotope changes with two linear regressions. The rate of increase of 87Sr/86Sr was high from the latest Oligocene (~25 Ma) to earliest middle Miocene (~15 Ma), with an estimated rate of 0.000059/m.y. Our ability to reproduce Sr isotope measurements is +/-0.000030 or better, yielding a stratigraphic resolution of as good as +/-0.5 m.y. for this interval. The rate of change was much lower from about 15 to 8 Ma (on average, 0.000013/m.y.), yielding Sr isotope stratigraphic resolution of worse than +/-2.3 m.y. The causes of the late Eocene to Miocene 87Sr/86Sr increases are not known. We speculate that a moderate 87Sr/86Sr increase (0.000030/m.y) which occurred during the late Eocene-latest Oligocene can be explained by intermittent glaciations and deglaciations of the Antarctic continent. These pulse-like changes in the input of glacial weathering products yield what appears to be a monotonic, linear increase. The increase in the frequency of glaciations during the latest Oligocene-early Miocene can explain the higher rate of change of 87Sr/86Sr at this time. We speculate that by the middle Miocene, the development of a permanent east Antarctica ice sheet resulted in decreased input of glacial weathering products and a lower rate of 87Sr/86Sr change.