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A model for stirring effects on transitions in bistable chemical systemsa) (1985)

Kumpinsky, Enio ; Epstein, Irving R.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 82 (1985), S. 53-57

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Experimental and model studies are reported of nucleation induced transitions between bistable states of a chemical reaction in a stirred tank reactor. In both systems studied, BrO−3–Br−–Mn2+ and ClO2−–I−, the rate of stirring has a marked effect upon the transition in one direction but not in the other. In both cases, good qualitative agreement is found between the experimental results and those of a simple, two-compartment reactor model.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.448777

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