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  • Articles  (31)
  • Wiley  (31)
  • Copernicus
  • Journal of Geophysical Research JGR - Atmospheres  (19)
  • Journal of Geophysical Research JGR - Solid Earth  (11)
  • 7527
  • 7528
  • 11
    Publication Date: 2014-05-02
    Description: A modified Ambient Ion Monitor - Ion Chromatograph was utilized to monitor the composition of water-soluble PM 2.5 and precursor gases at the Bakersfield, CA supersite during CalNex in May and June of 2010. The observations were used to investigate inorganic gas/particle partitioning, to derive an empirical relationship between ammonia emissions and temperature, and to assess the performance of the Community Multiscale Air Quality (CMAQ) model. The water-soluble PM 2.5 maximized in the morning and in the evening because of gas/particle partitioning and possibly regional transport. Among the PM 2.5 constituents, pNO 3 − was the dominant chemical species with campaign average mass loading of 0.80 µg m −3 , and the mass loadings of pNH 4 + and pSO 4 2− were 0.46 µg m −3 and 0.53 µg m −3 , respectively. The observed HNO 3(g) levels had an average of 0.14 ppb. Sub-ppb levels of SO 2(g) were measured, consistent with the absence of major emission sources in the region. Measured NH 3(g) had an average of 19.7 ppb over the campaign, and demonstrated a strong relationship with temperature. Observations of ammonia were used to derive an empirical enthalpy for volatilization of 30.8 ± 2.1 kJ mol −1 . The gas/particle partitioning of semi-volatile PM 2.5 composition was driven by meteorological factors, and limited by total nitrate (TN) in this region. CMAQ model output exhibited significant biases in the predicted concentrations of pSO 4 2− , NH 3(g), and TN. The largest model bias was in HNO 3(g) , with an overprediction of an order of magnitude, which may be due to missing HNO 3(g) sinks such as reactive uptake on dust in the CMAQ framework.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 12
    Publication Date: 2014-03-04
    Description: [1]  National Ambient Air Quality Standards (NAAQS) have been set for PM 2.5 due to its association with adverse health effects. PM 2.5 design values in the South Coast Air Basin (SoCAB) and San Joaquin Valley (SJV) of California exceed NAAQS levels, and NH 4 + and NO 3 - make up the largest fraction of total PM 2.5 mass on polluted days. Here we evaluate fine-scale simulations of PM 2.5 NH 4 + and NO 3 - with the Community Multiscale Air Quality model using measurements from routine networks and the CalNex-2010 campaign. The model correctly simulates broad spatial patterns of NH 4 + and NO 3 - including the elevated concentrations in eastern SoCAB. However, areas for model improvement have been identified. NH 3 emissions from livestock and dairy facilities appear to be too low, while those related to waste disposal in western SoCAB may be too high. Analyses using measurements from flights over SoCAB suggest that problems with NH 3 predictions can influence NO 3 - predictions there. Offline ISORROPIA II calculations suggest that over-predictions of NH x in Pasadena cause excessive partitioning of total nitrate to the particle phase overnight, while under-predictions of Na + cause too much partitioning to the gas phase during the day. Also, the model seems to under-estimate mixing during the evening boundary layer transition leading to excessive nitrate formation on some nights. Overall, the analyses demonstrate fine-scale variations in model performance within and across the air basins. Improvements in inventories and spatial allocations of NH 3 emissions and in parameterizations of sea-spray emissions, evening mixing processes, and heterogeneous ClNO 2 chemistry could improve model performance.
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  • 13
    Publication Date: 2014-04-05
    Description: We present spatial and temporal variations of methyl chloride (CH 3 Cl) in the upper troposphere (UT) observed mainly by the CARIBIC passenger aircraft for the years 2005–2011. The CH 3 Cl mixing ratio in the UT over Europe was higher than that observed at a European surface baseline station throughout the year, indicative of a persistent positive vertical gradient at NH mid latitudes. A series of flights over Africa and South Asia show that CH 3 Cl mixing ratios increase toward tropical latitudes, and the observed UT CH 3 Cl level over these two regions and the Atlantic was higher than that measured at remote surface sites. Strong emissions of CH 3 Cl in the tropics combined with meridional air transport through the UT may explain such vertical and latitudinal gradients. Comparisons with carbon monoxide (CO) data indicate that non-combustion sources in the tropics dominantly contribute to forming the latitudinal gradient of CH 3 Cl in the UT. We also observed elevated mixing ratios of CH 3 Cl and CO in air influenced by biomass burning in South America and Africa, and the enhancement ratios derived for CH 3 Cl to CO in those regions agree with previous observations. In contrast, correlations indicate a high CH 3 Cl to CO ratio of 2.9 ± 0.5 ppt ppb -1 in the Asian summer monsoon anticyclone and domestic biofuel emissions in South Asia are inferred to be responsible. We estimated the CH 3 Cl emission in South Asia to be 134 ± 23 Gg Cl yr -1 , which is higher than a previous estimate due to the higher CH 3 Cl to CO ratio observed in this study.
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  • 14
    Publication Date: 2014-11-15
    Description: The structural evolution of low-density snow under a high temperature gradient over a short period usually takes place in the surface layers on clear, cold nights. In this paper, X-ray computed microtomography (micro-CT) was combined with numerical simulations to investigate the temperature gradient metamorphism (TGM) on different types of snow. Precipitation particles (PP), small rounded particles (RGsr) and large rounded particles (RGlr) were each observed in high temperature gradients (100–500 K m −1 ) at a mean temperature of −4 °C. The specific surface area (SSA) was used to characterize the TGM, which were influenced by both the magnitude of the temperature gradient and the initial snow structures. PP samples experienced a logarithmic decrease of SSA with time, and the depth hoar structures created under high TGM (500 K m −1 ) have higher SSA compared to those under lower TGM. Unlike previous observations, for initial rounded and connected structures, like RGlr samples, the SSA increased during TGM. Simulated normal vapor flux distributions for different snow types were used to help understand the structural evolution under TGM. Understanding the SSA increase is important in order to predict the enhanced uptake of chemical species by snow or increase in snow albedo.
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  • 15
    Publication Date: 2014-08-21
    Description: Analysis of microgravity and surface displacement data collected at the summit of Kīlauea Volcano, Hawai‘i (USA), between December 2009 and November 2012, suggests a net mass accumulation at ~1.5 km depth beneath the northeast margin of Halema‘uma‘u Crater, within Kīlauea Caldera. Although residual gravity increases and decreases are accompanied by periods of uplift and subsidence of the surface, respectively, the volume change inferred from the modeling of interferometric synthetic aperture radar (InSAR) deformation data can account for only a small portion (as low as 8%) of the mass addition responsible for the gravity increase. We propose that, since the opening of a new eruptive vent at the summit of Kīlauea in 2008, magma rising to the surface of the lava lake outgasses, becomes denser, and sinks to deeper levels, replacing less-dense gas-rich magma stored in the Halema‘uma‘u magma reservoir. In fact, a relatively small density increase (〈200 kg m −3 ) of a portion of the reservoir can produce the positive residual gravity change measured during the period with the largest mass increase, between March 2011 and November 2012. Other mechanisms may also play a role in the gravity increase without producing significant uplift of the surface, including compressibility of magma, formation of olivine cumulates, and filling of void space by magma. The rate of gravity increase, higher than during previous decades, varies through time and seems to be directly correlated with the volcanic activity occurring at both the summit and the east rift zone of the volcano.
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  • 16
    Publication Date: 2019
    Description: Abstract Volcanoes are hazardous to local and global populations, but only a fraction are continuously monitored by ground‐based sensors. For example, in Latin America, more than 60% of Holocene volcanoes are unmonitored, meaning long‐term multiparameter data sets of volcanic activity are rare and sparse. We use satellite observations of degassing, thermal anomalies, and surface deformation spanning 17 years at 47 of the most active volcanoes in Latin America and compare these data sets to ground‐based observations archived by the Global Volcanism Program. This first comparison of multisatellite time series on a regional scale provides information regarding volcanic behavior during, noneruptive, pre‐eruptive, syneruptive, and posteruptive periods. For example, at Copahue volcano, deviations from background activity in all three types of satellite measurements were manifested months to years in advance of renewed eruptive activity in 2012. By quantifying the amount of degassing, thermal output, and deformation measured at each of these volcanoes, we test the classification of these volcanoes as open or closed volcanic systems. We find that ~28% of the volcanoes do not fall into either classification, and the rest show elements of both, demonstrating a dynamic range of behavior that can change over time. Finally, we recommend how volcano monitoring could be improved through better coordination of available satellite‐based capabilities and new instruments.
    Print ISSN: 2169-9313
    Electronic ISSN: 2169-9356
    Topics: Geosciences , Physics
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  • 17
    Publication Date: 2016-04-27
    Description: Bioaerosols are well-known immune-active particles that exacerbate respiratory diseases. Human exposures to bioaerosols and their resultant health impacts depend on their ambient concentrations, seasonal and spatial variation, and co-pollutants, which are not yet widely characterized. In this study, chemical and biological tracers of bioaerosols were quantified in respirable particulate matter (PM 10 ) collected at three urban and three background sites in the Midwestern United States across four seasons in 2012. Endotoxins from gram negative bacteria (and a few gram positive bacteria), water-soluble proteins, and tracers for fungal spores (fungal glucans, arabitol and mannitol) were ubiquitous and showed significant seasonal variation and dependence on temperature. Fungal spores were elevated in spring and peaked in summer, following the seasonal growing cycle, while endotoxins peaked in autumn during the row crop harvesting season. Paired comparisons of bioaerosols in urban and background sites revealed significant urban enhancements in PM 10 , fungal glucans, endotoxins and water-soluble proteins relative to background locations, such that urban populations have a greater outdoor exposure to bioaerosols. These bioaerosols contribute, in part, to the urban excesses in PM 10 . Higher bioaerosol mass fractions in urban areas relative to background sites indicate that urban areas serve as a source of bioaerosols. Similar urban enhancements in water-soluble calcium and its correlation with bioaerosol tracers point towards wind-blown soil as an important source of bioaerosols in urban areas.
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  • 18
    Publication Date: 2012-12-15
    Description: We use interferometric synthetic aperture radar (InSAR) to study deformation of the summit caldera at Kīlauea Volcano during 2000–2008, which spanned both an east rift zone eruptive event in 2007 and the start of the ongoing summit eruption in 2008. The data set consists of small baseline subset (SBAS) time series generated from 270 acquisitions on three separate beam modes from the Radarsat-1 satellite. We identify 12 time periods with distinct patterns of displacement that we attribute until late 2003 to secular tectonic-driven deformation and from 2004 to 2008 to four different sources in the summit area. We model the shallow magmatic system as a spherical reservoir at 1.9 ± 0.1 km depth below the surface to the northeast of Halemaumau (source 1) and three vertically stacked sills at greater depths in the southern caldera area (source 2 at the southern edge of the caldera at 2.9 ± 0.2 km depth, source 3 to the south-southeast of the caldera at 3.4 ± 0.5 km depth, and source 4 south of the caldera at 3.6 ± 0.4 km depth). The sequence for filling of and withdrawal from these reservoirs reveals a top-down process, with sequences of both inflation and deflation initiating in the shallowest source. Inflation of source 3 is coincident with elevated seismic activity in the upper east rift zone in February 2006 and May 2007. Source 4 is elongated toward the southwest rift zone and also shows elevated seismicity that extends toward the southwest rift zone.
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  • 19
    Publication Date: 2013-04-25
    Description: [1]  Multiple mechanisms have been suggested to explain seaward motion of the south flank of Kīlauea Volcano, Hawai'i. The consistency of flank motion during both waxing and waning magmatic activity at Kīlauea suggests that a continuously acting force, like gravity body force, plays a substantial role. Using finite element models, we test whether gravity is the principal driver of long-term motion of Kīlauea'sflank. We compare our model results to geodetic data from GPS and InSAR during a time period with few magmatic and tectonic events (2000–2003), when deformation of Kīlauea was dominated by summit subsidence and seaward motion of the south flank. We find that gravity-only models can reproduce the horizontal surface velocities if we incorporate a regional decollement fault and a deep, low viscosity magma mush zone. To obtain quasi-steady state horizontal surface velocities that explain the long-term seaward motion of the flank, we find that an additional weak zone is needed, which is an extensional rift zone above the magma mush. The spreading rate in our model is mainly controlled by the magma mush viscosity, while its gravity plays a less significant role. We find that a viscosity of 2.5 x 10 17 – 2.5 x 10 19  Pa.s for the magma mush provides an acceptable fit to the observed horizontal surface deformation, and that to first order the low viscosity of the mush, and not a higher density, drives spreading of the deep rift zone. Using high magma mush viscosities, such as 2.5 x 10 19  Pa.s, the deformation rates remain more steady state over longer timescales. These models explain a significant amount of the observed subsidence at Kīlauea's summit. Some of the remaining subsidence is probably a result of magma withdrawal from subsurface reservoirs.
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  • 20
    Publication Date: 2017-09-23
    Description: Groundwater management typically relies on water level data and spatially limited deformation measurements. While InSAR has been used to study hydrological deformation, its limited temporal sampling can lead to biases in rapidly changing systems. Here we use 2011-2017 COSMO-SkyMed data with revisit intervals as short as one day to study the response of the Santa Clara Valley (SCV) aquifer in California to the unprecedented 2012-2015 drought. Cross correlation and independent component analyses of deformation time series enable tracking water though the aquifer system. The aquifer properties are derived prior to and during the drought to assess the success of water-resource management practices. Subsidence due to groundwater withdrawal dominates during 2011-2017, limited to the confined aquifer and west of the Silver Creek Fault, similar to pre-drought summer periods. Minimum water levels and elevations were reached in mid-2014, but thanks to intensive groundwater management efforts the basin started to rebound in summer 2015, during the deepening drought. By 2017, water levels were back to their pre-drought levels, while elevations had not yet fully rebounded due to the delayed poroelastic response of aquitards and their large elastic compressibility. As water levels did not reach a new low stand, the drought led to only elastic and recoverable changes in the SCV. The SCV lost 0.09 km 3 during the drought while seasonal variations amount to 0.02 km 3 . Analysis of surface loads due to water mass changes in the aquifer system suggests that groundwater drawdowns could influence the stress on nearby faults.
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