ALBERT

Description: The Carboniferous Bowland Shale of northern England has drawn considerable attention because it has been estimated to have 1329 trillion cubic feet hydrocarbons in-place (gas and liquids) resource potential (Andrews 2013). Here we report on the oil and gas generation characteristics of three selected Bowland Shale whole-rock samples taken from cores and their respective kerogen concentrates. Compositional kinetics and phase properties of the primary and secondary fluids were calculated through the PhaseKinetics and GOR-Fit approaches and PVT modelling software. The three Bowland Shale samples contain immature, marine type II kerogen. Pyrolysate compositions imply primary generation of paraffinic–naphthenic–aromatic (PNA) oil with low contents of wax and sulphur. Bulk kinetic parameters have many similarities to those of productive American Palaeozoic marine shale plays. The secondary gas generation potential of Bowland Shale is greater than the primary gas potential although it requires a 10 kcal mol –1 higher activation energy to achieve peak production. Primary oil, primary gas and secondary gas reach their maximum generation at 137, 150 and 200°C respectively for a 3°C Ma –1 heating rate. Different driving forces of expulsion including the generation of hydrocarbon and overpressure caused by phase separation during sequential periods of subsidence and uplift could be inferred.

Description: The origin and age of topography along the west Greenland margin is a matter of continued debate. Evidence for tectonically driven Neogene uplift has been argued from interpretations of offshore seismic surveys, onshore fission-track data and inferred episodes of cooling. Here, analysis of seismic reflection profiles and 1D modelling of exploration wells along the Greenland margin of Davis Strait demonstrate that the data are consistent with a model of ancient continental topography affected by late Cretaceous–early Palaeocene rifting followed by thermal subsidence where offshore Neogene tectonic uplift is not required. This interpretation for the offshore evolution of the west Greenland margin has implications for the adjacent onshore evolution and for other continental margins developed throughout the Atlantic–Arctic rift system.

Description: Neoproterozoic basaltic magmatism in the Dalradian Supergroup of Scotland and Ireland was associated with the break-up of the Rodinia supercontinent. Magmas were erupted in rift-related basins along a strike length of at least 700 km and during a time period of c. 80 Ma. New major and trace element analyses of metabasalts from several formations are presented to trace the variations in magma compositions in time and space. The primary magmas resulted from variable degrees of mixing of melts derived from mantle sources similar to those of normal and enriched mid-ocean ridge basalts; some younger lavas also show evidence of contamination with continental crust. In contrast to speculations about magmatism elsewhere in Rodinia, the evidence here suggests that there was no involvement of a mantle plume in basalt generation. For example, the Scottish promontory of Laurentia drifted rapidly southwards through c. 25{degrees} over the duration of the magmatism, with no evidence of significant elevation above sea level, as might be expected from involvement of a plume. Generation of the primary magmas might have taken place predominantly through decompression melting in depleted upper mantle containing enriched streaks and blobs. Both the Dalradian lithostratigraphy and the metabasaltic compositions are consistent with extreme lithospheric stretching and possibly rupture during the earliest phase of magmatism, whereas generation of later magmatism appears to have been associated with major fault systems, possibly on a foundering continental margin. Supplementary materialChemical analyses of Dalradian metavolcanic rocks (major elements recalculated to 100%, anhydrous) are available at www.geolsoc.org.uk/SUP18468.

Description: : Neoproterozoic basaltic magmatism in the Dalradian Supergroup of Scotland and Ireland was associated with the break-up of the Rodinia supercontinent. Magmas were erupted in rift-related basins along a strike length of at least 700 km and during a time period of c . 80 Ma. New major and trace element analyses of metabasalts from several formations are presented to trace the variations in magma compositions in time and space. The primary magmas resulted from variable degrees of mixing of melts derived from mantle sources similar to those of normal and enriched mid-ocean ridge basalts; some younger lavas also show evidence of contamination with continental crust. In contrast to speculations about magmatism elsewhere in Rodinia, the evidence here suggests that there was no involvement of a mantle plume in basalt generation. For example, the Scottish promontory of Laurentia drifted rapidly southwards through c . 25° over the duration of the magmatism, with no evidence of significant elevation above sea level, as might be expected from involvement of a plume. Generation of the primary magmas might have taken place predominantly through decompression melting in depleted upper mantle containing enriched streaks and blobs. Both the Dalradian lithostratigraphy and the metabasaltic compositions are consistent with extreme lithospheric stretching and possibly rupture during the earliest phase of magmatism, whereas generation of later magmatism appears to have been associated with major fault systems, possibly on a foundering continental margin. Supplementary material: Chemical analyses of Dalradian metavolcanic rocks (major elements recalculated to 100%, anhydrous) are available at www.geolsoc.org.uk/SUP18468 .

Description: The Carboniferous Bowland Shale of northern England has drawn considerable attention because it has been estimated to have 1329 trillion cubic feet hydrocarbons in-place (gas and liquids) resource potential (Andrews 2013). Here we report on the oil and gas generation characteristics of three selected Bowland Shale whole-rock samples taken from cores and their respective kerogen concentrates. Compositional kinetics and phase properties of the primary and secondary fluids were calculated through the PhaseKinetics and GOR-Fit approaches and PVT modelling software. The three Bowland Shale samples contain immature, marine type II kerogen. Pyrolysate compositions imply primary generation of paraffinic–naphthenic–aromatic (PNA) oil with low contents of wax and sulphur. Bulk kinetic parameters have many similarities to those of productive American Palaeozoic marine shale plays. The secondary gas generation potential of Bowland Shale is greater than the primary gas potential although it requires a 10 kcal mol –1 higher activation energy to achieve peak production. Primary oil, primary gas and secondary gas reach their maximum generation at 137, 150 and 200°C respectively for a 3°C Ma –1 heating rate. Different driving forces of expulsion including the generation of hydrocarbon and overpressure caused by phase separation during sequential periods of subsidence and uplift could be inferred.

Description: New apatite fission-track data from SE Baffin Island exhibit central ages that range from just under 200 Ma to 440 Ma, and mean track lengths that vary between c . 12 and 13.3 µm. First-order analysis of the data (a plot of central age v. mean track length) reveals an approximate ‘boomerang’ trend, typical of samples that have experienced contemporaneous cooling from an array of initial temperatures. One-dimensional inverse thermal modelling of single samples suggests that cooling through the partial annealing zone ( c . 120–60 °C) occurred over discrete periods ranging from 100 to 300 Ma. Modelling the 3D exhumation of a heterogeneous crust with flat topography demonstrates that some of the variability in observed fission-track ages could be attributed to heterogeneity in crustal heat production and thermal conductivity. The remaining variability in the observed dataset is attributed here to differential erosion from a variable initial topography. However, age discontinuities over short distances require other explanations such as faulting and/or unidentified compositional effects. Collectively, these results suggest that the observed data are consistent with a simple exhumation scenario where the present-day high topography is a remnant of that created during Palaeoproterozoic orogenies. The new data do not require any recent (Cenozoic) periods of exhumation. Supplementary material: Data locations, and isotopic and petrographic results are available at www.geolsoc.org.uk/SUP18657 .

Description: 〈span〉〈div〉Abstract〈/div〉Elevated topography is evident across the continental margins of the Atlantic. The Cumberland Peninsula, Baffin Island, formed as the result of rifting along the Labrador-Baffin margins in the late Mesozoic and is dominated by low relief high elevation topography. Apatite fission track (AFT) analysis of the landscape previously concluded that the area has experienced a differential protracted cooling regime since the Devonian; however, defined periods of cooling and the direct causes of exhumation were unresolved. This work combines the original AFT data with 98 apatite new (U-Th)/He ages from 16 samples and applies the newly developed ‘broken crystals’ technique to provide a greater number of thermal constraints for thermal history modelling to better constrain the topographic evolution. The spatial distribution of AFT and AHe ages implies exhumation has been significant toward the SE (Labrador) coastline, while results of thermal modelling outline three notable periods of cooling in the pre-rift (460 Ma – 200 Ma), from syn-rift to present (120 Ma – 0 Ma) and within post-rift (30 Ma – 0 Ma) stages. Pre-rift cooling is interpreted as the result of exhumation of Laurentia, syn-rift cooling as the result of rift flank uplift to the SE and differential erosion of landscape, while the final post-rift period is likely an artefact of the modelling process. These results suggest the source of the Cumberland Peninsula's modern-day elevated topography is uplift during rifting in the Cretaceous and the isostatic compensation following continuous Mesozoic and Cenozoic differential erosion. This work highlights the how interaction of rift tectonics and isostasy can be the principal source for modern elevated continental margins, while also providing insight into the pre-rift exhumational history of central Laurentia.〈strong〉Supplementary material:〈/strong〉〈a href="https://doi.org/10.6084/m9.figshare.c.4528409"〉https://doi.org/10.6084/m9.figshare.c.4528409〈/a〉〈/span〉

Description: 〈span〉〈div〉Abstract〈/div〉Elevated topography is evident across the continental margins of the Atlantic. The Cumberland Peninsula, Baffin Island, formed as the result of rifting along the Labrador–Baffin margins in the late Mesozoic and is dominated by low-relief high-elevation topography. Apatite fission-track (AFT) analysis of the landscape previously concluded that the area has experienced a differential protracted cooling regime since the Devonian; however, defined periods of cooling and the direct causes of exhumation were unresolved. This work combines the original AFT data with 98 apatite new (U–Th)/He (AHe) ages from 16 samples and applies the newly developed ‘broken crystals’ technique to provide a greater number of thermal constraints for thermal history modelling to better constrain the topographic evolution. The spatial distribution of AFT and AHe ages implies that exhumation has been significant toward the SE (Labrador) coastline, and results of thermal modelling outline three notable periods of cooling: in the pre-rift stage (460–200 Ma), from synrift stage to present (120–0 Ma) and within the post-rift stage (30–0 Ma). Pre-rift cooling is interpreted as the result of exhumation of Laurentia and synrift cooling as the result of rift-flank uplift to the SE and differential erosion of landscape, whereas the final post-rift period is probably an artefact of the modelling process. These results suggest that the source of the Cumberland Peninsula's modern-day elevated topography is uplift during rifting in the Cretaceous and the isostatic compensation following continuous Mesozoic and Cenozoic differential erosion. This work highlights how interaction of rift tectonics and isostasy can be the principal source for modern elevated continental margins, and also provides insight into the pre-rift exhumational history of central Laurentia.〈strong〉Supplementary material:〈/strong〉 Thermal histories are available at: 〈a href="https://doi.org/10.6084/m9.figshare.c.4528409"〉https://doi.org/10.6084/m9.figshare.c.4528409〈/a〉〈/span〉