ALBERT

Description: Nitrate contamination in rivers has raised widespread concern in the world, particularly in arid/semi-arid river basins lacking qualified water. Understanding the nitrate pollution levels and sources is critical to control the nitrogen input and promote a more sustainable water management in those basins. Water samples were collected from a typical semi-arid river basin, the Weihe River watershed, China, in October 2014. Hydrochemical assessment and nitrogen isotopic measurement were used to determine the level of nitrogen compounds and identify the sources of nitrate contamination. Approximately 32.4% of the water samples exceeded the World Health Organization (WHO) drinking water standard for NO3−-N. Nitrate pollution in the main stream of the Weihe River was obviously much more serious than in the tributaries. The δ15N-NO3− of water samples ranged from +8.3‰ to +27.0‰. No significant effect of denitrification on the shift in nitrogen isotopic values in surface water was observed by high dissolved oxygen (DO) values and linear relationship diagram between NO3−-N and δ15N-NO3−, except in the Weihe River in Huayin County and Shitou River. Analyses of hydrochemistry and isotopic compositions indicate that domestic sewage and agricultural activities are the main sources of nitrate in the river.

Description: Frequency analysis of streamflow is critical for water-resources system planning, water conservancy projects and the mitigation of hydrological extremes events. In this study, a maximum entropy-Archimedean copula-based Bayesian network (MECBN) method has been proposed for frequency analysis of monthly streamflow in the Kaidu River Basin, which integrates the maximum entropy-Archimedean copula (MEAC) and Bayesian network methods into a general framework. MECBN is effective for representing the uncertainties that exist in model representation, preserving the distributional characteristics of streamflow records and addressing the correlation structure between streamflow pairs. Application to the Kaidu River Basin shows a good performance of MECBN in describing the historical data of this basin in China. The results indicate that the interactions between two adjacent monthly streamflow pairs are non-linear. There is upper tail dependence between monthly streamflow pairs. The dependence coefficients including Spearman’s rho, Kendall’s tau, and the upper tail dependence coefficient are in inverse proportion of monthly streamflow values in the Kaidu River Basin, due to the fact that other factors (i.e., rainfall, snow melting, evapotranspiration rate and requirement of water use) provide more contributions to the streamflow in the flooding season. These findings can be used for providing vital information in the prevention and control of hydrological extremes and to further water resources planning in Kaidu River Basin.

Description: Understanding the interaction of surface water and groundwater affected by anthropogenic activities is of great importance for water resource and water quality management. The Xiong’an New Area, located in the North China Plain, has been designated a new building area by China’s government. Groundwater has been over pumped and artificial water was transferred to meet the water supply in this region. Therefore, the natural interaction of surface water and groundwater has been greatly changed and there has been a complex impact of the groundwater from anthropogenic activities. In this study, we used water chemical ions and stable isotopes of δ2H and δ18O to assess the interaction of surface water and groundwater in the Xiong’an New Area. We carried out field surveys and water sampling of the Fu River (domestic waste water discharge), Lake Baiyangdian (artificial water transfer), and the underlying groundwater along the water bodies. Results show that the artificial surface water (discharged and transferred) became the major recharge source for the local groundwater due to the decline of groundwater table. We used groundwater table observations, end-member mixing analysis of the stable isotopic composition and chloride tracers to estimate the contributions of different recharge sources to the local groundwater. Due to the over pumping of groundwater, the lateral groundwater recharge was dominant with a contribution ratio ranging from 12% to 78% in the upper reach of the river (Sections 1–3). However, the contribution of lateral groundwater recharge was estimated to be negligible with respect to the artificial water recharge from Lake Baiyangdian. Seepage from the Fu River contributed a significant amount of water to the connecting aquifer, with a contribution ranging from 14% to 75% along the river. The extent of the river influence into the aquifer ranges as far as 1400 m to the south and 400 m to the north of the Fu River. Estimations based on isotopic fractionation shows that about 25% of Lake Baiyangdian water was lost by evaporation. By using the stable isotopes of oxygen and hydrogen in the lake water, an influencing range of 16 km west of the lake was determined. The interaction of the surface water and groundwater is completely changed by anthropogenic activities, such as groundwater over pumping, waste water discharge and water transfer. The switched interaction of surface water and groundwater has a significant implication on water resources management.

Description: Great attention has been paid to the potential of wastewater irrigation as a sustainable water source, particularly due to water scarcity and water pollution issues. However, few studies have focused on its adverse effects and on the health risks it may pose. In this study, the physicochemical properties of soils and plants irrigated with rural domestic wastewater and associated microbiological risks were investigated. The results showed that sewage irrigation could increase the production of vegetables and improve soil fertility. While the nitrate content of plants increased significantly, pathogens on plants and in soils increased after irrigation with raw wastewater. In particular, there was a wide range of pathogenic bacteria in the phyllosphere, which may indicate risks if contaminated vegetables are consumed directly. Treated wastewater irrigation was not significantly different from controls, which were irrigated by tap water; consequently, it can be used as an alternative water resource for agricultural irrigation. The presence of a wide spectrum pathogens in wastewater shows the necessity of long-term monitoring and further evaluation.

Description: Conserving and enhancing freshwater biodiversity are global issues to ensure ecosystem integrity and sustainability. To meet this, it is critical to understand how the biological assemblages are determined by environmental gradients in different spatial scales. Nevertheless, information on their large-scale environmental relationships remains scarce in Korea. We aimed to understand nationwide spatial distribution patterns of benthic macroinvertebrates and important environmental factors affecting their distribution in 388 streams and rivers across Korea. A total of 340 taxa, belonging to 113 families in 23 orders of five phyla, were identified. Assemblage composition in most Korean streams included a few predominant colonizers and a majority of rare taxa. Cluster analysis based on benthic macroinvertebrates classified a total of 720 sampling sites into five clusters according to the pollution levels from fast-flowing less polluted streams with low electrical conductivity to moderately or severely polluted streams with high electrical conductivity and slow water velocity. Canonical correspondence analysis revealed that altitude, water velocity and streambed composition were the most important determinants, rather than watershed and water chemistry variables, for explaining the variation in macroinvertebrate assemblage patterns. The results provide basic information for establishing the conservation and restoration strategies of macroinvertebrate biodiversity against anthropogenic disturbances and developing more confident bio-assessment tools for diagnosing stream ecosystem integrity.

Description: In this study, an initial water-rights allocation (IWRA) model is proposed for adjusting the traditional initial water-rights empowerment model based on previous water intake permits, with the aim of improving the productivity of water resources under population growth and economic development. A stochastic scenario with Laplace criterion mixed fuzzy programming (SSLF) is developed into an IWRA model to deal with multiple uncertainties and complexities, which includes dynamic water demand, changing water policy, adjusted tradable water rights, the precise risk attitude of policymakers, development of the economy, and their interactions. SSLF not only deals with fuzziness in probability distributions with high satisfaction degrees, but also reflects the risk attitudes of policymakers with the Laplace criterion, which can handle the probability of scenario occurrence under the supposition of no data available. The developed IWRA model with the SSLF method is applied to a practical case in an alpine region of China. The results of adjusted initial water rights, optimal water-right allocation, changed industrial structure, and system benefits under various scenarios associated with risk attitudes and water productivity improvement were obtained and analyzed. It was found that the current initial water-rights allocation scheme based on previous intake water permits is not efficient, and this can be modified by the IWRA model. Based on the strategies of drinking safety and ecological security, the main tradeoff between agricultural and industrial water rights can facilitate optimization of the current initial water-rights allocation. This can assist policymakers in producing an effective plan to promote water productivity and water resource management in a robust and reliable manner.

Description: An accurate representation of the spatial distribution of stable isotopes in modern precipitation is vital for interpreting hydrological and climatic processes. Considering the dominant impact of moisture sources in controlling water isotopes and deuterium excess, we conducted a meta-analysis of precipitation isotopes using instrumental data from 68 stations around China. The entire country is divided into five regions according to the major moisture sources: Region I (the westerlies domain), Region II (the arctic domain), Region III (the northeast domain), Region IV (the Pacific domain), and Region V (the Tibetan Plateau). Each region has unique features of spatial distribution and seasonal variation for stable precipitation isotopes and deuterium excess. In particular, seasonal variation in Region IV tracks the onset of Asian summer monsoons well. The regional meteoric water lines are presented for each region. A significant temperature effect is found in Regions I and III, with δ18O-temperature gradients of 0.13–0.68‰/°C and 0.13–0.4‰/°C, respectively. However, the reasons for the temperature effects are quite different. In Region I, this effect is caused by the seasonal shift of the westerlies, whereas in Region III, it is caused by the seasonal difference in moisture sources. The precipitation amount effect is most significant in the region along the southeast coast in China, where the δ18O-precipitation amount the gradient is −0.24 to −0.13‰/mm. The findings in our paper could serve as a reference for isotopic application in hydrological and paleo-climatic research.

Description: Water, Vol. 10, Pages 1298: Denitrification-Potential Evaluation and Nitrate-Removal-Pathway Analysis of Aerobic Denitrifier Strain Marinobacter hydrocarbonoclasticus RAD-2 Water doi: 10.3390/w10101298 Authors: Dedong Kong Wenbing Li Yale Deng Yunjie Ruan Guangsuo Chen Jianhai Yu Fucheng Lin An aerobic denitrifier was isolated from a long-term poly (3-hydroxybutyrate-co-3-hydroxyvalerate) PHBV-supported denitrification reactor that operated under alternate aerobic/anoxic conditions. The strain was identified as Marinobacter hydrocarbonoclasticus RAD-2 based on 16S rRNA-sequence phylogenetic analysis. Morphology was observed by scanning electron microscopy (SEM), and phylogenetic characteristics were analyzed with the API 20NE test. Strain RAD-2 showed efficient aerobic denitrification ability when using NO3−-N or NO2−-N as its only nitrogen source, while heterotrophic nitrification was not detected. The average NO3−-N and NO2−-N removal rates were 6.47 mg/(L·h)and 6.32 mg/(L·h), respectively. Single-factor experiments indicated that a 5:10 C/N ratio, 25–40 °C temperature, and 100–150 rpm rotation speed were the optimal conditions for aerobic denitrification. Furthermore, the denitrifying gene napA had the highest expression on a transcriptional level, followed by the denitrifying genes nirS and nosZ. The norB gene was found to have significantly low expression during the experiment. Overall, great aerobic denitrification ability makes the RAD-2 strain a potential alternative in enhancing nitrate management for marine recirculating aquaculture system (RAS) practices.

Description: Water, Vol. 10, Pages 496: A Study on the Comparison of Corrosion in Water Supply Pipes Due to Tap Water (TW) and Reclaimed Water (RW) Water doi: 10.3390/w10040496 Authors: Hyundong Lee Usman Rasheed Myeongsik Kong Among a wide variety of alternative water resources, reclaimed water from waste-water has drawn much attention, as it is considered a stable water resource to be substituted for agricultural, industrial, recreational, and public water. This study aimed to compare and evaluate the effects of tap water and reclaimed water on the corrosion of the inner surface of pipes. The investigated pipes included GSP (Galvanized Steel Pipe), CIP (Cast Iron Pipe), STSP (Stainless Steel Pipe), and PVCP (Polyvinyl Chloride Pipe). Assessment of corrosion impact on the different materials of pipes was conducted by analyzing the corrosion accelerators and inhibitors related to the characteristics of reclaimed water. Reclaimed water with higher ionic content showed a faster corrosion rate than tap water because corrosion accelerators have more of an effect on pipe corrosion than do corrosion inhibitors. In terms of pipe materials, the corrosion rate was fastest in CIP, followed by GSP, and STSP; PVCP exhibited no electrochemical corrosion.

Description: Water, Vol. 10, Pages 511: Corn Straw as a Solid Carbon Source for the Treatment of Agricultural Drainage Water in Horizontal Subsurface Flow Constructed Wetlands Water doi: 10.3390/w10040511 Authors: Yuanyuan Li Sen Wang Yue Li Fanlong Kong Houye Xi Yanan Liu Agricultural drainage water with a low C/N ratio restricts the nitrogen and phosphorus removal efficiencies of constructed wetlands. Thus, there is a need to add external carbon sources to drive the nitrogen and phosphorus removal. In this study, the effects of the addition of corn straw pretreated with different methods (acid treatment, alkali treatment, and comminution) on treating agricultural drainage water with a low C/N ratio were investigated in constructed wetlands. The results showed that soaking the corn straw in an alkaline solution was the most suitable pretreatment method according to the release rule of chemical oxygen demand (COD) and the dissolution of total nitrogen (TN) and total phosphorus (TP). The average removal efficiency of TN and TP in constructed wetlands increased respectively by 37.2% and 30.5% after adding corn straw, and by 17.1% and 11.7% after adding sodium acetate when the hydraulic retention time (HRT) was 3 days. As an external carbon source, straw was cheap, renewable, and available. In contrast, the sodium acetate demanded high costs in a long-term operation. Therefore, corn straw had a great advantage in treatment effect and cost, which improved the treatment efficiency of agricultural drainage water using a byproduct of agricultural production as a slow-release carbon source.