ALBERT

Description: This study systematically investigated the influence of multi-directional forging (MDF) on the microstructural evolution, hot deformation behavior, and tensile properties of a β-solidifying TiAl alloy. The initial lamellar microstructure of an as-cast alloy was remarkably refined and homogenized by three-step MDF. High temperatures and multi-pass deformations were conducive to the decomposition of lamellae. A crack-free billet was obtained through three-step MDF, with a deformation temperature of 1250 °C and a forging speed of 0.1 mm/s, indicating that MDF can be applied to β-solidifying TiAl alloys by the proper control of the alloy composition and process parameters. Microstructural observation showed that the billet mainly consists of fine and equiaxed γ grains and a small amount of β phase. The tensile properties of the multi-directional forged alloy were also significantly improved, due to microstructure refinement. The ultimate tensile strength (UTS) and elongation (δ) at room temperature were 689.4 MPa, and 0.83%, respectively. The alloy exhibits excellent ductility at 700 °C. When the temperature was increased to 700 °C, the UTS decreased to 556 MPa and δ increased to 5.98%, indicating that the alloy exhibits excellent ductility at 700 °C. As the temperature further increased to 750 °C, δ dramatically increased to 46.65%, indicating that the ductile-brittle transition temperature of the alloy is between 700 °C and 750 °C.

Description: The effect of heat treatment on the microstructures and mechanical properties of a novel β-solidifying Ti–43Al–2Cr–2Mn–0.2Y alloy was investigated. A fully lamellar (FL) microstructure with a colony size of about 100 μm was obtained by heat treatment at 1320 °C/10 min/furnace cooling (FC). A duplex (DP) microstructure with globular γ grains and γ/α2 lamellae was obtained by heat treatment at 1250 °C/4 h/FC. The residual hard–brittle β0 phase was also eliminated after heat treatment. The mechanical properties of the β-solidifying TiAl alloy depended closely on the heat treatment. The FL alloy had better fracture toughness, and the fracture toughness (KIC) value was 24.15 MPa·m1/2. The DP alloy exhibited better ductility, and the room temperature (RT) elongation of the alloy could reach 1%. The elongation of the alloy with different microstructures sharply increased when the temperature increased from 700 to 750 °C, indicating that the microstructure had no effect on the ductile–brittle transition temperature of the β-solidifying TiAl alloy. The fracture morphologies of different tensile specimens were observed. Interlamellar and translamellar fractures were the main fracture features of the FL alloy. Intergranular, translamellar, and interlamellar fractures were the main fracture features of the DP alloy.

Description: Materials, Vol. 11, Pages 1488: Study on the Effect of Demulsification Speed of Emulsified Asphalt based on Surface Characteristics of Aggregates Materials doi: 10.3390/ma11091488 Authors: Fanlong Tang Guangji Xu Tao Ma Lingyun Kong Aggregate is an indispensable raw material for emulsified asphalt construction. For the purpose of explaining the influence of aggregate characteristics on the demulsification speed of emulsified asphalt, the surface energy and specific surface area (SSA) characteristics of aggregates were calculated based on the capillary rise method and the BET (Brunauer-Emmett-Teller) adsorption test. Afterwards, the effect of the surface energy and specific surface area of the aggregate on the emulsified asphalt demulsification speed was systematically studied by using ultraviolet spectroscopy as well as the orthogonal test. Experimental results indicate that the specific surface energy parameter of the aggregate is certainly related to the particle size of the aggregate. That is, the surface free energy of the unit system is proportional to the surface area A and the density of the interface unit. The specific surface area parameter of aggregates increases with the decrease of particle size, when the particle size is reduced to 600 mesh, the specific surface area parameters of the three aggregates selected in this paper tend to be consistent. Orthogonal experimental analysis demonstrates that the surface energy and specific surface area have an impact on the emulsion breaking speed and they are proven to be positively correlated. Meanwhile, in the case of small particle sizes, there is no statistically significant correlation between the physical properties of aggregates and the demulsification speed of emulsified asphalt, and the physical property of aggregates is not the main factor that affects the demulsification speed of the emulsified asphalt. On the contrary, the material properties of the aggregate, such as acid-base property and chargeability, are the dominant factors.

Description: Materials, Vol. 11, Pages 1805: A Study of Strain-Driven Nucleation and Extension of Deformed Grain: Phase Field Crystal and Continuum Modeling Materials doi: 10.3390/ma11101805 Authors: Kong Gao Deng Luo Lu The phase-field-crystal (PFC) method is used to investigate migration of grain boundary dislocation and dynamic of strain-driven nucleation and growth of deformed grain in two dimensions. The simulated results show that the deformed grain nucleates through forming a gap with higher strain energy between the two sub-grain boundaries (SGB) which is split from grain boundary (GB) under applied biaxial strain, and results in the formation of high-density ensembles of cooperative dislocation movement (CDM) that is capable of plastic flow localization (deformed band), which is related to the change of the crystal lattice orientation due to instability of the orientation. The deformed grain stores the strain energy through collective climbing of the dislocation, as well as changing the orientation of the original grain. The deformed grain growth (DGG) is such that the higher strain energy region extends to the lower strain energy region, and its area increase is proportional to the time square. The rule of the time square of the DGG can also be deduced by establishing the dynamic equation of the dislocation of the strain-driven SGB. The copper metal is taken as an example of the calculation, and the obtained result is a good agreement with that of the experiment.

Description: F-III fibers were treated at different pressures in supercritical carbon dioxide fluid and all samples including untreated and treated F-III fibers were characterized by a mechanical performance tester, wide-angle X-ray scattering and small-angle X-ray scattering. By studying the relationship between mechanical performance and microstructural changes of the samples, it was found that microstructural change was the main cause of variation in mechanical performance. Results revealed that the maximum tensile strength and modulus of F-III fibers were acquired at 14 MPa within the pressure range of 8 MPa to 16 MPa when the temperature, tension and time were 250 °C, 6 g·d−1 and 40 min, respectively. Correspondingly, the microstructures of the samples, including the phase fraction, crystal size, orientation factor, fibril radius, fibril length and misorientation angle, have been investigated. It was fortunate that the supercritical carbon dioxide fluid could be used as a medium during the hot-stretch process to improve the mechanical performance of F-III fibers, although the treatment temperature was lower than the glass transition temperature of the F-III fibers.

Description: When a fire takes place in a tunnel, the surface of the asphalt pavement will burn and release a large amount of smoke, which is toxic to human health. Thus, in order to prevent the combustion of the asphalt pavement under fire, it is necessary to propose some methods to retard its physical and chemical reaction under the high temperature. In this study, ten different combinations of fire retardants and a control case where no fire retardant was applied were prepared for evaluation. The thermogravimetric (TG)–mass spectrometry (MS) tests were used to evaluate their effect on the fire retardance from mass and energy perspectives and the Fire Dynamics Simulator (FDS) software was used to evaluate the fire retardance from temperature and smoke distribution perspectives. In experimental analysis, the TG (thermogravimetric) and DTG (differential thermogravimetric) curves were used to analyze the mass loss rate and residual mass of the asphalt and the activation energy was calculated and analyzed as well. In addition, decay rate of mass loss rate and increasing rate of activation energy were proposed to evaluate the ease of combustion of the asphalt with and without fire retardants. The results show that in laboratory experiments, the fire retardant combination which includes 48% aluminum hydroxide, 32% magnesium hydroxide, 5% expanded graphite, and 15% encapsulated red phosphorous would lead to an improved effect of fire retardance. In numerical modeling, the temperature and smoke height distribution over time were adopted to evaluate the fire retardance effect. The temperature distribution was found to be symmetrical on both sides of the combustion point and the same combination as proposed in experimental analysis was found to have the best effect on fire retardance due to the largest decrease in temperature. Additionally, because of the highest smoke height distribution, an improved effect on smoke suppression was also found when this combination was applied.

Description: A novel high-performance carbon foam (CF) was fabricated through the addition of phenolic resin (PR) into a coal tar pitch (CTP) based precursor. The effects of mass fraction of a PR additive on the crystalline structures, morphologies, compressive strength (σ) and thermal conductivity (λ) of resultant CF material were investigated systematically. Characterization showed a strong dependence of CF’s performance from the composition and optical texture of the precursor, which were mainly depending on the polycondensation and polymerization reactions between PR and raw CTP. Comparing with the strength of pristine CF at 6.5 MPa, the σ of mCF-9 (13.1 MPa) was remarkably enhanced by 100.1%. However, the λ of mCF-9 substantially reduced to 0.9 m−1K−1 compared with 18.2 W m−1K−1 of pristine CF. Thus, this modification strategy to produce microporous CF materials from raw CTP provides a new protocol for the fabrication of high-performance carbon based materials.

Description: In order to examine the geometric characteristics of BOF (blast oxygen furnace) slag coarse aggregate, the aggregate image measurement system (AIMS) was used to analyze the sphericity, gradient angularity and micro texture. Both volumetric and mechanical properties were studied to evaluate the influence of geometric characteristics of BOF slag coarse aggregate on asphalt concrete. The experimental results show that the BOF slag coarse aggregate has the characteristics of high sphericity, good angular performance and rough surface texture. The geometric characteristics of BOF slag has obvious influence on the volume performance of asphalt concrete. the higher sphericity of BOF slag causes an increase of the air voids of asphalt mixture. BOF slag coarse aggregate can effectively improve the road performances of asphalt concrete. BOF slag’s higher sphericity and angularity improve the moisture damage resistance and rutting resistance of asphalt concrete. Results indicate that better angularity can slightly enhance the moisture resistance property of asphalt concrete, but excessively high angularity of BOF slag coarse aggregates reduces the anti-rutting properties of asphalt mixture.

Description: Structural vibration induced by dynamic load or natural vibration is a non-negligible factor in failure analysis. Based on a vibrating boundary condition, the impact resistance of shape memory alloy (SMA)-reinforced composites was investigated. In this investigation, a modified Hashin’s failure criterion, Brinson’s model, and a visco-hyperelastic model were implemented into a numerical model to characterize the mechanical behavior of glass fiber/epoxy resin laminates, SMAs, and interphase, respectively. First, a fixed boundary condition was maintained in the simulation to verify the accuracy of the material parameters and procedures by a comparison with experimental data. Then, a series of vibrating boundaries with different frequencies and amplitudes was applied during the simulation process to reveal the effect on impact resistances. The results indicate that the impact resistance of the composite under a higher frequency or a larger amplitude is lower than that under a lower frequency or a smaller amplitude.

Description: The cement and asphalt mortar (CA mortar) used in the China Railway Track System (CRTS) I ballastless slab track may encounter a coupling fatigue effect under the high-frequency vibration, load and high-and-low temperature cycles, and the deterioration under fatigue may happen during service of the high-speed railway. In this study, the performance degradation and its mechanism of the CA mortar with and without polymer emulsion incorporated under the coupling fatigue effects of the high-frequency vibration, load and temperature were studied by using an anti-fatigue testing device specially developed for the CA mortar used in the ballastless slab track of the high-speed railway. The results showed that the deformation capacity of the CA mortar for CRTS I slab ballastless slab track decreased after fatigue test under simulated service environment, presenting a typical brittle characteristic and an obvious reduction of the ductility and toughness. The Scanning Electron Microscopy (SEM) observation and the mercury intrusion porosimetry (MIP) analysis showed that the volume of the macropore decreased whereas that of the micropore increased after the fatigue test. The asphalt in the hardened CA mortar revealed a softening and migration from the bulk paste to fill the pore and make the structure denser and even ooze out of the CA mortar under the high-frequency vibration and high temperature. Through incorporating the polymer emulsion, the anti-fatigue property of the CA mortar was obviously improved, which can prevent the CA mortar from losing its elastic adjustment function too early. Though increase of the strength and elastic modulus for the CA mortar after severe service is beneficial to the stability of train running, the comfort level and safety of the train operation may decline due to the gradual reduction of the ductility & toughness and the gradual loss of the elastic damping adjustment function of the CA mortar between the base concrete slab and the track slab.