ALBERT

Beschreibung: This study summarizes organic carbon isotope (δ13C) and total organic carbon (TOC) data from a series of tests undertaken to provide an appropriate methodology for pre-analysis treatment of mudstones from an Upper Carboniferous sedimentary succession, in order to develop a consistent preparation procedure. The main treatments involved removing both inorganic carbonate and hydrocarbons (which might be extraneous) before δ13C and TOC analysis. The results show that decarbonating using hydrochloric acid causes significant reduction in δ13C and total carbon (TC) of the bulk material due to the removal of inorganic carbonate. These changes are most pronounced where soluble calcium carbonate (rather than Ca-Mg-Fe carbonate) is present. Deoiled samples show only slightly higher mean δ13C where visible bitumen was extracted from the bulk sample. Moreover, the isotopic signatures of the extracts are closely correlated to those of their respective bulk samples, suggesting that small yields of hydrocarbons were generated in situ with no isotopic fractionation. In addition, further δ13C and TC analyses were performed on samples where mixing of oil-based drilling mud with brecciated core material had been undertaken. Brecciated mudstone material did not display distinct isotopic signals compared to the surrounding fine-grained material. Overall we show that the most accurate assessment of bulk organic carbon isotopes and concentration in these samples can be achieved through decarbonating the material prior to measurement via the ‘rinse method’. However, our results support recent findings that pre-analysis acid treatments can cause variable and unpredictable errors in δ13C and TOC values. We believe that, despite these uncertainties, the findings presented here can be applied to paleoenvironmental studies on organic matter contained within sedimentary rocks over a range of geological ages and compositions.

Beschreibung: Mixed-layer depth (MLD) is often used in a mixed-layer heat budget to relate air-sea exchange to changes in the near-surface ocean temperature. In this study, reanalysis heat flux products and profiles from a 15 year time series of high-resolution, near-repeat expendable bathythermograph/expendable conductivity-temperature-depth (XBT/XCTD) sampling in Drake Passage are used to examine the nature of MLD variations and their impact on a first-order, one-dimensional heat budget for the upper ocean in the regions north and south of the Polar Front. Results show that temperature and density criteria yield different MLD estimates, and that these estimates can be sensitive to the choice of threshold. The difficulty of defining MLD in low-stratification regions, the large amplitude of wintertime MLD (up to 700 m in Drake Passage), and the natural small-scale variability of the upper ocean result in considerable cast-to-cast variability in MLD, with changes of up to 200 m over 10 km horizontal distance. In contrast, the heat content over a fixed-depth interval of the upper ocean shows greater cast-to-cast stability and clearly measures the ocean response to surface heat fluxes. In particular, an annual cycle in upper ocean heat content is in good agreement with the annual cycle in heat flux forcing, which explains ∼24% of the variance in heat content above 400 m depth north of the Polar Front and ∼63% of the variance in heat content south of the Polar Front.