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  • Other Sources  (2)
  • Curie temperature  (1)
  • pyroclastic deposits  (1)
  • English  (2)
  • 1
    Publication Date: 2023-06-17
    Description: Tephra layers of the Mýtina Maar, Czech Republic, contain ferrimagnetic Mg–Al-rich titanomagnetite, which is suggested to originate from a fractionated alkaline CO2-rich lithospheric mantle melt. We investigated the magnetic mineralogy and Curie temperature (TC) from tephra deposits of two drill cores (〈 9 m depth). TC calculated (208 ± 14 °C) from chemical composition (Fe2+0.8Mg0.5Fe3+1.1Al0.3Ti0.3O4) is in accordance with TC retrieved from cooling curves of temperature-dependent magnetic susceptibility measurements (195–232 °C). However, thermomagnetic curves are irreversible either with lower (type I) or higher (type II) TC in the heating curve. All curves show transition temperatures above ca. 390 °C, indicating maghemitization. We interpret the irreversibility of TC (∆TC) in terms of different degrees of cation ordering, overprinted or masked by different degrees of maghemitization, which is a low-temperature phenomenon. Negative ∆TC indicates that original deposited titanomagnetite has cooled faster and, therefore, has stored a lower degree of cation ordering compared to heating/cooling rate of 11 °C/min in the Kappabridge. Type II with positive ∆TC indicates higher degree of cation ordering, and, therefore, slower cooling rate. The central part of this deposit shows most severe maghemitization, indicating rather wet emplacement. We, therefore, suggest different eruption styles for deposition of type I pyroclastics with more phreatomagmatic and type II pyroclastics with more phreato-Strombolian eruption styles. Our study is a new approach to discriminate different cooling histories in maar deposits using the Curie temperature of titanomagnetite. We suggest that this method has the potential to discriminate different emplacement modes resulting from different eruption styles.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: CzechGeo/EPOS
    Keywords: ddc:552.2 ; Eger rift system ; Maar-diatreme volcano ; Titanomagnetite ; Curie temperature ; Cation ordering effect ; Maghemitization ; Pyroclastic emplacement mechanism
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2022-12-15
    Description: Most pyroclastic deposits of Popocatépetl volcano were emplaced at high temperatures and have similar mafic to more evolved compositions, suggesting a long‐lived, interconnected magma environment. We performed a magnetic and microscopic study on different eruptive sequences 〈14 ky in age and found that temperature and field dependence of magnetic susceptibility are suited to separate eruption phases. We observed homogeneous titanomagnetite with Curie temperatures (TC) of 50–200°C and 200–400°C, together with different amounts of oxy‐exsolved titanomagnetite with TC ∼ 570°C. Some block‐and‐ash flow deposits show remarkably irreversible TC in heating and cooling branches with a positive ΔTC (TC heating–TC cooling) of up to 130°C in the center. The central part of this sequence is characterized by decreasing magnetic susceptibility and low field dependence of magnetic susceptibility (〈10%), which is atypical for ulvöspinel‐rich titanomagnetite. The nonreversibility of heating and cooling runs measured with rates of around 10 K/min is probably related to vacancy‐enhanced nanoscale chemical clustering, which seems to occur preferentially during rapid quenching, possibly combined with subtle maghemitization. In contrast, pumice layers have the highest field dependence (∼20%) and contain Ti‐rich and intermediate titanomagnetite with TC 〈 100 and ∼300°C, which are in line with mafic and more evolved magma composition. In intermediate phases, irreversibility of TC is more common but with a relatively low ΔTC of ±20°C. We suggest that magneto‐mineralogy in pyroclastic density currents is complex but offers a complementary tool to the paleomagnetic directional analysis for emplacement temperature and contribute information on the volcanic material history and their emplacement conditions.
    Description: Plain Language Summary: Explosive eruptions of volcanoes are a dangerous threat to human settlements. In this study, we investigated pyroclastic material from the last 14 ky of Popocatépetl volcano using magnetic mineral assemblages, hysteresis properties, and temperature‐ and field‐dependent magnetic susceptibility. The data are suited to separate different eruption phases and provide information on the volcanic material history and emplacement conditions. Magnetic susceptibility analyses are suggested to be a complementary tool to the paleomagnetic directional analysis for the determination of emplacement temperatures.
    Description: Key Points: Several Curie temperatures were observed in pyroclastic deposits. Temperature and field dependence of magnetic susceptibility are suited to separate eruption phases. Irreversible Curie temperatures in heating and cooling curves observed in block‐and‐ash flows may suggest rapid quenching.
    Description: DGAPA‐UNAM
    Description: https://doi.org/10.17632/9g2tszftvr.2
    Description: https://earthref.org/MagIC/19591/206809c5-acfc-41e3-b4cb-411630a7025e
    Keywords: ddc:552.2 ; Popocatépetl volcano ; pyroclastic deposits ; magnetic rock studies ; magnetic mineralogy studies ; cooling temerature
    Language: English
    Type: doc-type:article
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