ALBERT

Description: The development of new methodologies to affect non– ortho -functionalization of arenes has emerged as a globally important arena for research, which is key to both fundamental studies and applied technologies. A range of simple arene feedstocks (namely, biphenyl, meta -terphenyl, para -terphenyl, 1,3,5-triphenylbenzene, and biphenylene) is transformed to hitherto unobtainable multi-iodoarenes via an s-block metal sodium magnesiate templated deprotonative approach. These iodoarenes have the potential to be used in a whole host of high-impact transformations, as precursors to key materials in the pharmaceutical, molecular electronic, and nanomaterials industries. To prove the concept, we transformed biphenyl to 3,5-bis( N -carbazolyl)-1,1'-biphenyl, a novel isomer of 4,4'-bis( N -carbazolyl)-1,1'-biphenyl (CPB), a compound which is currently widely used as a host material for organic light-emitting diodes.

Description: 〈p〉In organic microcavities, hybrid light-matter states can form with energies that differ from the bare molecular excitation energies by nearly 1 eV. A timely question, given the recent advances in the development of thermally activated delayed fluorescence materials, is whether strong light-matter coupling can be used to invert the ordering of singlet and triplet states and, in addition, enhance reverse intersystem crossing (RISC) rates. Here, we demonstrate a complete inversion of the singlet lower polariton and triplet excited states. We also unambiguously measure the RISC rate in strongly coupled organic microcavities and find that, regardless of the large energy level shifts, it is unchanged compared to films of the bare molecules. This observation is a consequence of slow RISC to the lower polariton due to the delocalized nature of the state across many molecules and an inability to compete with RISC to the dark exciton reservoir.〈/p〉

Description: Numerous climate change effects on biodiversity have been anticipated and documented, including extinctions, range shifts, phenological shifts, and breakdown of interactions in ecological communities, yet the relative balance of different climate drivers and their relationships to other agents of global change (for example, land use and land-use change) remains relatively poorly understood. This study integrated historical and current biodiversity data on distributions of 115 Mexican endemic bird species to document areas of concentrated gains and losses of species in local communities, and then related those changes to climate and land-use drivers. Of all drivers examined, at this relatively coarse spatial resolution, only temperature change had significant impacts on avifaunal turnover; neither precipitation change nor human impact on landscapes had detectable effects. This study, conducted across species’ geographic distributions, and covering all of Mexico, thanks to two large-scale biodiversity data sets, could discern relative importance of specific climatic drivers of biodiversity change.

Description: Interpretation of new multichannel seismic reflection profiles indicates that the Palomares margin formed by crustal-scale extension and coeval magmatic accretion during middle to late Miocene opening of the Algero-Balearic basin. The margin formed at the transition between thinned continental crust intruded by arc volcanism and back-arc oceanic crust. Deformation produced during the later positive inversion of the margin offshore and onshore is partitioned between ~N50°E striking reverse faults and associated folds like the Sierra Cabrera and Abubacer anticlines, and N10-20°E sinistral strike-slip faults like Palomares and Terreros faults. Parametric sub-bottom profiles and multibeam bathymetry offshore, structural analysis, available GPS geodetic displacement data and earthquake focal mechanisms jointly indicate that tectonic inversion of the Palomares margin is currently active. The Palomares margin shows a structural pattern comparable to the north Maghrebian margins where Africa-Eurasia plate convergence is accommodated by NE-SW reverse faults, NNW-SSE sinistral faults and WNW-ESE dextral ones. Contractive structures at this margin contribute to the general inversion of the Western Mediterranean since ~7 Ma ago, coeval to inversion at the Algerian margin. Shortening at the Alboran ridge and Al-Idrisi faults occurred later, since 5 Ma, indicating a westward propagation of the compressional inversion of the Western Mediterranean.

Description: 〈p〉Integrated antibiotic resistance (AR) surveillance is one of the objectives of the World Health Organization global action plan on antimicrobial resistance. Urban wastewater treatment plants (UWTPs) are among the most important receptors and sources of environmental AR. On the basis of the consistent observation of an increasing north-to-south clinical AR prevalence in Europe, this study compared the influent and final effluent of 12 UWTPs located in seven countries (Portugal, Spain, Ireland, Cyprus, Germany, Finland, and Norway). Using highly parallel quantitative polymerase chain reaction, we analyzed 229 resistance genes and 25 mobile genetic elements. This first trans-Europe surveillance showed that UWTP AR profiles mirror the AR gradient observed in clinics. Antibiotic use, environmental temperature, and UWTP size were important factors related with resistance persistence and spread in the environment. These results highlight the need to implement regular surveillance and control measures, which may need to be appropriate for the geographic regions.〈/p〉

Description: Liquid crystalline (LC) materials, such as actin or tubulin networks, are known to be capable of deforming the shape of cells. Here, elements of that behavior are reproduced in a synthetic system, namely, a giant vesicle suspended in a LC, which we view as a first step toward the preparation of active, anisotropic hybrid systems that mimic some of the functionality encountered in biological systems. To that end, we rely on a coupled particle-continuum representation of deformable networks in a nematic LC represented at the level of a Landau–de Gennes free energy functional. Our results indicate that, depending on its elastic properties, the LC is indeed able to deform the vesicle until it reaches an equilibrium, anisotropic shape. The magnitude of the deformation is determined by a balance of elastic and surface forces. For perpendicular anchoring at the vesicle, a Saturn ring defect forms along the equatorial plane, and the vesicle adopts a pancake-like, oblate shape. For degenerate planar anchoring at the vesicle, two boojum defects are formed at the poles of the vesicle, which adopts an elongated, spheroidal shape. During the deformation, the volume of the topological defects in the LC shrinks considerably as the curvature of the vesicle increases. These predictions are confirmed by our experimental observations of spindle-like shapes in experiments with giant unilamellar vesicles with planar anchoring. We find that the tension of the vesicle suppresses vesicle deformation, whereas anchoring strength and large elastic constants promote shape anisotropy.

Description: A P-wave seismic velocity model has been obtained for the Central Iberian Zone, the largest continental fragment of the Iberian Variscan Belt. The spatially dense, high-resolution, wide-angle seismic reflection experiment ALCUDIA-WA, was acquired in 2012 across central Iberia, aiming to constrain the lithospheric structure and resolve the physical properties of the crust and upper mantle. The seismic transect, ~310 km long crossed the Central Iberian Zone from its suture with the Ossa-Morena Zone to the southern limit of the Central System mountain range. The energy generated by 5 shots, was recorded by ~900 seismic stations. High amplitude phases were identified in every shot gather for the upper crust (Pg and PiP) and Moho (PmP and Pn). In the upper crust, the P-wave velocities increase beneath the Cenozoic Tajo Basin. The base of the upper crust varies from ~13 km to ~20 km between the southernmost Central Iberian Zone and the Tajo Basin. Lower crustal velocities are more homogeneous. From SW-NE, the travel-time of PmP arrivals varies from ~10.5 s to ~11.8 s, indicating lateral variations in the P-wave velocity and the crustal thickness, reflecting an increase towards the north related with alpine tectonics and the isostatic response of the crust to the orogenic load. The results suggest that the high velocities of the upper crust near the Central System might correspond to igneous rocks and/or high grade metamorphis rocks. The contrasting lithologies and the increase in the Moho depth to the north evidence differences in the Variscan evolution.

Description: Studies of sensory capacities in past life forms have offered new insights into their adaptations and lifeways. Audition is particularly amenable to study in fossils because it is strongly related to physical properties that can be approached through their skeletal structures. We have studied the anatomy of the outer and middle ear in the early hominin taxa Australopithecus africanus and Paranthropus robustus and estimated their auditory capacities. Compared with chimpanzees, the early hominin taxa are derived toward modern humans in their slightly shorter and wider external auditory canal, smaller tympanic membrane, and lower malleus/incus lever ratio, but they remain primitive in the small size of their stapes footplate. Compared with chimpanzees, both early hominin taxa show a heightened sensitivity to frequencies between 1.5 and 3.5 kHz and an occupied band of maximum sensitivity that is shifted toward slightly higher frequencies. The results have implications for sensory ecology and communication, and suggest that the early hominin auditory pattern may have facilitated an increased emphasis on short-range vocal communication in open habitats.

Description: We report the first observation of exciplex state electroluminescence due to carrier injection between the hybrid lead halide perovskite (MAPbI 3–x Cl x ) and quantum dots (core/shell PbS/CdS). Single layers of perovskite (PS) and quantum dots (QDs) have been produced by solution processing methods, and their photoluminescent properties are compared to those of bilayer samples in both PS/QD and QD/PS configurations. Exciplex emission at lower energies than the band gap of both PS and QD has been detected. The exciplex emission wavelength of this mixed system can be simply tuned by controlling the QD size. Light-emitting diodes (LEDs) have been fabricated using those configurations, which provide light emission with considerably low turn-on potential. The "color" of the LED can also be tuned by controlling the applied bias. The presence of the exciplex state PS and QDs opens up a broad range of possibilities with important implications not only in tunable LEDs but also in the preparation of intermediate band gap photovoltaic devices with the potentiality of surpassing the Shockley-Queisser limit.

Description: Abstract Erosion and deposition redistribute mass as a continental rift evolves, which modifies crustal loads and influences subsequent deformation. Surface processes therefore impact both the architecture and the evolution of passive margins. Here we use coupled numerical models to explore the interactions between the surface, crust, and lithosphere. This interaction is primarily sensitive to the efficiency of the surface processes in transporting mass from source to sink. If transport is efficient, there are two possible outcomes: (1) Faulting within the zone of extension is longer lived and has larger offsets. This implies a reduction of the number of faults and the width of the proximal domain. (2) Efficient transport of sediment leads to significant deposition and hence thermal blanketing. This will induce a switch from brittle to ductile deformation of the upper crust in the distal domains. The feedbacks between these two outcomes depend on the extension history, the underlying lithospheric rheology, and the influence of submarine deposition on sediment transport. High erosion/sedimentation during early faulting leads to abrupt crustal necking, while intermediate syntectonic sedimentation rates over distal deep submarine hotter crust leads to unstructured wide distal domains. In models where rheological conditions favor the formation of asymmetric conjugate margins, only subaerial transport of sediments into the distal domains can increase conjugate symmetry by plastic localization. These models suggest that passive margin architecture can be strongly shaped by the solid Earth structure, sea level, and climatic conditions during breakup.