ISSN:
0538-8066
Schlagwort(e):
Chemistry
;
Physical Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The consumption of nitric oxide in the shock-heated nitric oxide, hydrogen, and argon system had been studied and modeled as the chain-branching process containing the reaction H + NO ⇀ N + OH (k3) as a slow-branching step. Through the computer simulation method the authors clarified the role of the initiation reaction H2 + NO ⇀ HNO + H (k1) in the system and obtained the rate constants of k1 and k3 as k1 = 1013.5±0.15 exp (-55.2 kcal/RT) and k3 = 1013.7±0.15 exp (-48.7 kcal/RT) (cm3/mole·sec), respectively. k1 was one order larger than the value obtained in the flame experiment by Halstead and Jenkins.
Zusätzliches Material:
7 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/kin.550080208
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