ISSN:
0193-7197
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
Crystallinity in PVC contributes significantly to the strength and resiliency of the polymer. Two types of crystallites have been described: a primary crystallite in the virgin powder state pictured as a platelet or flat needle-like lamellar crystallite, and a secondary, fringed micellar crystallite from melts or solutions. Both crystallites create loose, crosslinking networks. The secondary crystallite forms when plastisol melts are cooled or solutions are gelled. Crystallites exert a major effect on rheological properties. The thermal destruction of the primary crystallite networks in the melt phase results in a decrease in elastic modulus. Cooling from the fused state creates secondary crystallites that affect tensile and elongation.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/vnl.730160110
Permalink
