ALBERT

Description: Glass separates from 115 ash layers derived from the Kamchatkan (DSDP Site 192; 34 layers), the eastern Aleutian (DSDP Site 183; 56 layers) and the Alaska Peninsula (DSDP Site 178; 25 layers) volcanic arcs have been analyzed for up to 28 elements. In addition, the abundance and diversity of associated mafic phenocrysts have been evaluated. The resulting data set has made possible an evaluation of the late Miocene to Recent changes in composition of ashes derived from North Pacific volcanic arcs and of the factors controlling the evolution of highly siliceous magmas. We find no evidence for a general transition from arc tholeiite to calc-alkalic magma parentage of ashes derived from the volcanic arcs during the last 10 m.y., but instead find 0.1- to 0.5-m.y. intervals during which particular types of volcanism are prevalent. Most convincing is the transition from arc tholeiite to calc-alkalic for ashes derived from Kamchatka during the last 0.8 m.y., a change believed to be associated with a landward shift in the site of magma generation. Considered together, ashes derived from North Pacific volcanic arcs have been becoming more siliceous during the last 1.5 m.y. and may be associated with accelerated subduction during the same time interval. Hydrous phenocrysts (e.g., biotite) are typically associated with low-silica deep-sea ashes, but not with terrestrial volcanic rocks of comparable silica contents, suggesting the important role of water in the evolution of siliceous magma. REE patterns and relative abundances of mafic phenocrysts demonstrate the importance of fractional crystallization in controlling the evolution of highly siliceous arc magmas. REE increase with increasing silica, but become less concentrated in ashes with SiO2 〉 64%. Eu anomalies increase throughout the SiO2 range. Initial fractionation is dominated by clinopyroxene and plagioclase with amphibole strongly influencing fractionation above 64% SiO2.

Description: Menaquinones (vitamin K2) were the only isoprenoid quinones found in the Actinomycetes tested. Thermomonospora strains belonging to the species T. alba, T. curvata and T. fusca contained very complex mixtures of menaquinones with nine, ten and eleven isoprene units. Hexa- and octahydrogenated menaquinones with ten isoprene units constituted the major components in T. alba, whereas, octahydrogenated menaquinones with ten isoprene units predominated in T. curvata and T. fusca. Substantial amounts of hitherto undescribed hexa-, octa-, and decahydrogenated menaquinones with eleven isoprene units were also present in the three species. The representative of the taxon Thermomonospora (Actinobifida) chromogena examined differed in possessing major amounts of tetrahydrogenated menaquinones with only nine isoprene units; a pattern also found in Saccharomonospora viridis, Actinomadura flexuosa and Micromonospora halophytica subsp. halophytica. The chemotaxonomic data and supporting results of numerical taxonomic studies suggest that Actinobifida chromogena may have been wrongly classified in the genus Thermomonospora.